§1. Course logistics: student presentations [00:03]
You know each other from other things, so you can make switches. Just let me know who's switching with whom once the two of you negotiate. I'm not going to become the marriage broker and try to figure out these switches. If you can't do that, you're welcome to videotape your own presentation and submit it to us — please do that by March 31st, which is more than a month away, so you ought to be able to do it. Dr. Belmar and I can watch your presentation that way. If you have to be out of town — one person said they're liable to be out of town for the whole two weeks — well, if you decided you wanted to be out of town for the whole two weeks before spring break, that's probably not just a problem in this course. If you're taking any other course it's probably a problem. Note that's when other classes are giving their midterms.
Some of the people wanted to go at 8:30. I was surprised how many people said they'd like to go early, which is fine because I get here at 6:30 or seven. So I don't think any of the people that got put in at the 8:30 slot were people who couldn't do it. In fact most people wanted to do it. I was also surprised at how many people apparently didn't have problems in the 11:10 slot, which is not our regular class time. Hopefully it works out and we get 46 presentations. You're supposed to watch 20 of them, one of which can be your own — I guess you bring a mirror or a selfie or something. We will not be putting this on YouTube. We'll be putting it on another system that only MIT students can access, and really only MIT students in this course would want to access it, unless you give the information away to one of your friends.
Student: [asks about the class list and a scheduling conflict]
There is a class list — you could check with Jerry. You know my assistant Jerry Hill — she could email something out to people if there's a conflict. Did you tell me that, and I put you in the second week? Okay, that's my fault. Jerry will help you with that. I don't say I don't make mistakes, but I tried to avoid that, and maybe I just got confused. Some people at Sloan are gone off on their Asia trip, and I thought I tried to avoid that. Technically this isn't advertised as an accelerated course that finishes up in the first half of the term, so any student who complained to the dean's office, I would have to accommodate them in some way. Well, you can videotape your presentation and show it to me before April first. I've found the last couple of years that some of the students appreciate the idea that they could finish this up early. I apologize if I did put someone in the wrong slot just because I got confused. It's not the first time in my life.
There's three people per hour. What I've found is, we'll lose on average two minutes as each of you fumbles around trying to get the audio visual to work with your computer. I will have a Mac here with the dongle — this is a VGA input. We've always gotten it to work, but sometimes we waste five minutes there. I want you to do it in ten minutes, which means no more than ten PowerPoint slides. I've seen students do it with twelve or thirteen, and they usually go over. There's a very good correlation between one slide per minute, and that doesn't matter whether it's a ten-minute presentation or a thirty or forty minute presentation — one slide per minute. If you go faster than that, you're racing through it. Most students keep to eight to twelve minutes, and I will let a student go over by twelve minutes. I will time things, and it also depends on whether the person before you went under. I might be nice and let some person get a minute from them. But I will not let you go fifteen minutes, because there will be some time for questions and answers — the idea is that it should be maybe seven or eight minutes for question and answer.
Some students have said they enjoyed the student presentations more than lectures, which is sort of offensive to me. I learn a lot from the student presentations too, so I'm not really offended by that. In fact, yours, I already told you, ought to publish. He sent me a copy, and a couple people have sent me some emails, and I'm happy to comment on the topic. You can come by and see me — we've only got eight days left before we start. Any questions on the presentations? I want to be flexible, and I think you all know one of the goals of this course is to make it as stress-free as possible. That's not really completely possible in the MIT environment. The system is set up to try to create stress for students, and actually there's some good that comes out of that. There was probably more bad, but nonetheless.
§2. Energy of fracture and the Liberty ship inquiry [06:57]
So we've been talking about fracture toughness and strength of materials. There's the force of fracture, which is tensile strength and yield strength — or in composites and polymers it may be just the ultimate tensile strength, because they don't really have a yield point. But we also have energy of fracture. Griffith pointed it out in 1925. It didn't become important until World War Two and the Liberty ships kind of emphasized it. Even today we are still running into problems. The Northridge earthquake in the early '90s in California — all the codes and standards had designed to force of fracture, and they had no real criteria for energy of fracture. You come along and have these static structures that get vibrated in an earthquake, and it caused five billion dollars worth of damage. Since then we've rewritten the codes and standards, and those structures now in California have to be able to absorb a little bit of energy, a little vibration that comes around every now and then. But there's still other industries where we haven't really gotten around to helping people figure out what the energy of fracture should be.
There's also this part of the story I haven't told you. When the Navy did their study on the Liberty ships, that 1946 report found that whether they used a Charpy bar — I think I mentioned this some other time, a Charpy bar is a little one centimeter square by ten centimeter long piece of material. [Tom locates a broken Charpy bar and passes it around.] Here's a broken Charpy bar that was ductile and did not fracture all the way through, so it forms sort of a V-shape. And here's another one that's shattered — not shattered exactly, it probably absorbed five or ten foot-pounds. This one that bent like this probably stopped a hammer, a big swinging hammer that had 264 foot-pounds. You don't want to be kicked by a horse at 264 foot-pounds. It will break a few bones. If it hit you in the head it will kill you. But the other one probably fractured at ten or fifteen foot-pounds.
The US Navy found the plates that had the problems, that started the fractures in the Liberty ships, were on the average of about five foot-pounds. So one of the recommendations of that Navy inquiry was that the Navy require ten foot-pounds — they doubled the amount of fracture energy that they found empirically had caused problems. Then people decided, well, we should put a safety factor on top of the ten foot-pound, so they made it fifteen foot-pounds. By 1960, the Coast Guard had decided, well, we should put a bigger safety factor than just fifteen foot-pounds, we'll make it twenty foot-pounds. So now we're four times what the Navy found was causing problems. I remember when I was working at a steel company, and the guy in the office right next to me was in charge of what we call line pipe — the steel pipe for things like the Alaskan pipeline. They were building the Alaskan pipeline in the mid '70s, and they had plans to build other pipelines, and they wanted to have something that would really act tough, that tough steel, and they wanted sixty or seventy foot-pounds. It starts getting pricey to make steels that are that tough.
Now the US Navy does it for nuclear submarines, but nuclear submarines are sort of a different matter. It's a 22 billion dollar vessel, and you tend not to like to lose them. I try to keep track of them, find out where they last docked and things like that. It's not like losing your keys, but almost. People keep on wanting higher and higher toughnesses. Is that really necessary? Well, there are some reasons why it might be. For example, when I worked for the steel company, they were building LNG tankers — these great big steel ships that have great big aluminum spheres, five of them, like five stories tall or five stories wide, these big aluminum spheres. In order to hold that sphere you have to have a cylinder that you put the sphere on, and that was made out of steel, and that had to have toughness at minus 60 degrees Fahrenheit.
Steel has an Achilles heel — many steels, as they get colder, go through what we call ductile-brittle transition and become brittle at low temperatures. So I had to develop a steel that could be welded and maintained good toughness at minus 60 degrees. They were building these ships down at Quincy shipyard, right down here in southern Massachusetts. At the time it had just been sold by Bethlehem Steel and was owned by General Dynamics. It's now closed, and they're turning it into a parking lot for imported cars and stuff. The Coast Guard said you have to meet twenty foot-pounds. It turns out the average toughness of the steel after they had heat treated it the first time was just like 20.2 foot-pounds. Every now and then they would have to do a second normalization heat treatment to get a finer grain size to give you toughness, and sometimes they would do a third. They would scrap the plate if they couldn't get a toughness above twenty foot-pounds after three tries.
By the way, fine grain size is the only thing we know of that gives you both toughness and strength. Most things that give you higher strength give you lower toughness. We saw that in the Ratio Analysis Diagram. But fine grain size will give you both. The average that Bethlehem was shipping from Sparrows Point, Maryland, up to Quincy, Massachusetts, was like 20.5 foot-pounds. It just barely passed. But every now and then they would find one that had thirty foot-pounds of toughness. The Coast Guard required that you had to have a runoff plate to measure the toughness. If this was a plate, and you were welding the seam between these two tables, they would have a runoff plate, and they would weld that seam a little further into the runoff plate, cut off the runoff plate, send it to the lab and measure the toughness. So when they found this one plate that would come in once a month with thirty foot-pounds of toughness, what do they do? They went and cut it up into runoff tabs. So what they were measuring was not the toughness of what was going to go in the ship. They were measuring the toughness of the best plate they could find. And that was one way to get around the spec. If the ship had blown up because of that, someone probably would go to jail, but nonetheless, that was what they were doing. Maybe that's why you need more and more toughness, because people are going to find more and more ways to slim things down and try to meet the spec.
So I'm not necessarily opposed to people who are trying to increase properties beyond what we think are necessary, because other people are also very clever about beating the system.
§3. The Ashby toughness-strength plot and structural materials [15:35]
So if we start looking at fracture toughness — an Ashby plot of fracture toughness and strength. Here are the two parameters we've been talking about: strength and toughness. We want to be as far up that way as possible. This is the Griffith criterion: K squared is equal to pi sigma squared times the crack length. So if you square this equation, K squared over sigma squared must be greater than pi C, and that is these lines right here. These are the critical flaw sizes in millimeters. K squared over pi sigma squared C. 100 millimeters is a four-inch flaw size. That's a pretty big notch. Many plates aren't even that thick. So something that's crossing that line — there's not a whole lot of things that cross that line. Some steels and some fancy engineering alloys, copper alloys are very tough. But most things, critical flaw size of ten millimeters, which is one centimeter, kind of goes through not the center but the sixtieth-percentile line for most of the metals. Some of the woods are okay, and some plastics are fairly ductile.
I showed you polyethylene. [Tom flexes a polyethylene sample.] I can't break that — it doesn't snap. But if I took polystyrene, you saw what happened with polystyrene — it just shatters. Why? Because polystyrene and things might be down around 10 to the minus two millimeters — that's half a thousandth, that's one-tenth of a human hair. Doesn't take a very big flaw to make polystyrene brittle. So we know that all materials have some imperfections, and fracture mechanics has quantified that. You can look at the Ashby plot, and you can see why we use metals for structural materials, except for concrete which should be down here somewhere. Glasses, pottery, brick, cement and concrete right here. It's still pretty small, but we usually only use cement and concrete in compression. When it has to be in bending or tension, we use steel rebar, reinforcement, to give it strength.
Ice is a structural material. In the mid '50s, Professor Kingery in Ceramics had a big project to look at the strength of ice as a structural material. It didn't really become an important structural material until they started building the oil fields in Prudhoe Bay in Alaska. They built man-made islands to go out there into the ocean, 100 feet deep. They built low islands. Those islands were designed by a group of civil engineers who used to be here at MIT. They would build the islands such that as the ice started to form, the islands have nice sloping walls of rock, and the ice would just build up and be pushed up above the ocean. Ice can obviously be a structural material. Anybody who goes ice fishing knows that it can be a structural material — except for the times when it's not thick enough.
One of my favorite stories, which has nothing to do with anything — you never heard the story of the ice fishers? In Minnesota or Wisconsin or wherever — they're out on the lake, and these guys will take their dogs with them, and they drove their pickup trucks out onto the lake. They wanted to drink beer more than ice fish. So they decided they were going to break some holes in the ice with some sticks of dynamite. They had sticks of dynamite, and they threw the stick of dynamite out there to blow a hole in the ice. And the dog went running after the stick of dynamite. He was used to playing catch with sticks, right? So he comes running back with the dynamite. These guys run, and the dog doesn't know what to do, so he gets underneath the pickup truck, and he and the pickup truck go blowing up. Better not drink too much beer. Just go ahead and drill your hole in the ice, don't try to blow it with dynamite. That's supposedly a true story. Poor dog, he didn't know.
So we have structural materials, all kinds of things like cement. Wood, with the grain, is not very strong, but perpendicular to the grain it can be very strong — about two orders of magnitude greater critical flaw size. That's why we can split hardwoods with a wedge and a hammer. Ceramics are way down here. The critical flaw size 10 to the minus 3 millimeter — that's nothing. That's why we can cut glass. We talked about diamond and how strong it is. Diamond has one of the lowest fracture toughnesses. If anyone knows the way they cut the crystals on the diamond — they don't even scribe it, because you can't scribe diamond. They just whack it with something, and if they whack it at the right angle — people make a fortune who develop the skill, they can cut the diamond crystal right where they want it, because diamond is extremely brittle. Very hard but brittle.
§4. Griffith's energy criterion and the CTOD test [22:05]
Student: So for the minimum flaw size, there obviously has to be some force or energy to split it, right? So what is that number? I'm guessing it's hard to visualize for all the materials?
It turns out it's in this stress intensity or toughness number. What Griffith did is, he said, let's take something that's brittle and figure out, if I pull on it, I'm making it like a spring — I'm storing energy. One-half K X squared is the energy you store in a spring for a strain of X. There's a spring constant depending on the geometry, the strain is X, and the energy stored is one-half K X squared. He said, if it fractures when I've got it under load, I create two new surfaces — just like a piece of chalk: I fracture it, two new surfaces. There's a certain energy to form those surfaces. If that energy exceeds the spring energy, it won't fracture catastrophically. If the spring energy is greater than the fracture energy, a brittle crack will just run, and it runs close to the speed of sound, typically one-third to one-half the speed of sound in the material. So it runs really fast. The energy in here is basically the stored energy of the tension from the stress you've applied. And that's how he gets this formula.
So he starts with an edge crack that's C deep, just like my little fracture toughness specimen — an edge crack C deep, and you pull on it. He calculated the stored energy in that as a function of strain. Today, one of the ways the British like to measure fracture toughness is a crack tip opening displacement. If I have my fracture toughness specimen with holes so I can pull on it here and here, you wonder what's happening right there at the crack tip. It's sort of lima bean shaped — this is the plastic zone size right there. You can do the bending beam formula of what the crack tip opening displacement is for some crack length C. The higher the CTOD, the greater the toughness. The British will have standards where they specify, for a given geometry of test specimen of a piece of steel, you must have a CTOD greater than a quarter millimeter. Crack tip opening displacement. When you pull on it, you've got some opening; you put a little clip gauge on, just like a tensile strain gauge, the same apparatus as if you've ever done a tensile test. You put a little clip gauge on to measure the strain. They put it right there and they measure how much it opens when you pull on it.
If you look at a CTOD curve, it's just like a stress-strain curve. Maybe doesn't have a yield point, but it's just the load increasing and then decreasing as you go up, and at some point it goes snap. That's when the energy of fracture becomes less than the stored strain energy in the material. So it is an energy criterion for fracture. And it's not a constant for all materials. Some materials can store a lot more energy than others. My example of a material that's sort of bilingual — [Tom produces a piece of Silly Putty.] Silly Putty. If I want to study the force of fracture, I can just take the Silly Putty and pull it like that. Silly Putty is almost a Newtonian material — it stretches hundreds of percent strain if you pull it slow. But the interesting thing about Silly Putty, because as a polymer it has some very interesting mechanical properties — I can pull on Silly Putty slowly and it stretches. What happens if I pull it quickly? Nothing — if I pull it quickly and it's small enough in diameter for me to break it, I get a brittle fracture. No deformation. That's a brittle fracture. So Silly Putty is very strain-rate dependent. At slow strain rates it's a superplastic material. At high strain rates it's a brittle material.
Metals are not so complex. Metals are either brittle or ductile, unless you're at ballistic velocities. Metals do start behaving like that at ballistic velocities, speed of sound. But Silly Putty does it at a lot lower speed.
§5. Defining ductile vs. brittle [28:02]
Student: [asks about the boundary between ductile and brittle]
That's an interesting philosophical point among materials people. [Tom draws at the board.] Some people will look at a stress-strain curve, and they're used to being metallurgists, and they say, we'll have a yield point and then it becomes plastic at the yield point. So this is stress versus strain. At 0.2 strain, which is 0.2 percent strain, they define that as the yield point of the material. Because usually this curves over gently, and what do you call the yield point if it's curving over gently? They come back down here. So some people say two-tenths of a percent strain is the limit of brittle material, and brittle is everything where you have elastic strain, just like Griffith — what's the elastic strain energy, and then the thing snaps. Some people say it's 0.5 percent. I've seen some textbooks try to say five percent. Well, if you're way out here, you've got a lot of stored energy. The energy stored, if this is where you actually fracture, is the area under the curve.
So some people say brittle is anything below 0.2 percent, which is the yield point of a metal. Some people, and this is in the pipeline business, will say the yield point is defined at 0.5 percent, which is two and a half times as great. Some people will say you need to have five percent ductility to be ductile. Let's just say anything above one percent is ductile and means the thing has stretched. I didn't bring the sample, but I passed a sample around last time, my brittle centrifuge, and if you look very carefully, just a little bit of stretch before the thing snapped. It's a continuous spectrum of materials. Something very brittle like glass, depending on the flaw size, could fracture anywhere along that elastic limit. Things that fail out here above five percent strain are clearly ductile. They stretch like this, the Silly Putty. Things that are in between are sort of beauty in the eye of the beholder.
But most design engineers would not like to design with something with less than five percent strain capacity, because they know they're going to have holes and stress concentrations. They want something that's going to give before it snaps. Glass doesn't give before it snaps. Diamond doesn't give before it snaps. To a designer, five percent is probably the minimum ductility he would want. To a laboratory technician, he would define ductile-brittle transition as 0.2 percent, maybe 0.5 percent. Where is it? It's somewhere between 0.2 and five percent. So is that confusing enough for the answer? It depends on who you're talking to and what their purpose is. You really want something that's going to stretch a little bit. Most metals — aluminums and steels and coppers and nickels — most of them, unless they're really high strength, are going to have more than ten percent strain. Many will have twenty or thirty percent strain. You don't usually get fifty or sixty percent strain, but you sometimes do.
§6. Tensile specimens and necking geometry [32:03]
I've got some tensile tests here in copper. [Tom holds up a copper tensile bar.] Here's a copper tensile bar. This is actually material from the wire right on the Acela between New Haven and Boston. This is a piece of the material for the conductors overhead. They're carrying the current to the train. It's really ductile material. If you look at how much that has necked down, it's tremendous. This has got probably more than 75 percent reduction in area on this specimen. That's a lot. Copper is a very ductile metal, and that's a very pure copper, very fine grain size in the stuff they finally used. [Tom passes tensile bars around.]
This one's kind of interesting in that the amount of stretch you get — it's not just beauty in the eye of the beholder; beauty is the geometry of the specimen. This is just a strip tensile specimen. If you pull it, you can see these were the original length — the black lines were the gauge length — and right here you can see it has started to neck down. It's ductile. That is a 55 degree angle. If you take my course on deformation, we can prove from theory why that's true. This is a similar tensile bar — that was the original length, and the one on the right is a little bit longer; you may not be able to see it, but there's a necking down right in here. And this one is just a tensile specimen. It shows what we call a cup-cone fracture. You get a cup-cone fracture when, depending on the size of the specimen and the ductility of the specimen, you actually have plane stress on the outside and plane strain on the inside. We don't have to get into that in this course, but you'll get a different type of fracture, 45 degree fracture, on the outside surface. The size of that 45 degree fracture, the plane stress area, is another measure of the ductility — an indirect measure of the toughness of the steel. I have seen big fractures and explosions where I have shear lips that are three or four inches wide. That's some of the best material that's up here, with a four-inch wide shear lip in plane stress, is going to be really tough material. It's not a measure of fracture toughness, but there is a correlation.
§7. Fracture mode identification — ductile vs. brittle in the field [35:30]
So if you spend thirty or forty years — they say it takes 10,000 hours to become an expert at anything, 10,000 hours of practice. I have spent 10,000 hours looking at fractures. Who'd have thought I went to college to look at things that were broken, right? But I did, and put seven kids through college, helping to raise grandchildren. We'll post this on Stellar, but this is out of the Metals Handbook, and it talks about Fracture Mode Identification Chart. Instantaneous failure can be ductile or brittle, we've been talking about that. Necking or distortion — I just passed around some samples to show necking, and the necking is different in a flat specimen than in a round specimen. It's geometry dependent. The way you measure it depends on the length of the specimen and the size of the specimen.
I remember as a sophomore, Professor Backofen said the longer you think about a tensile test, the less you understand it. The tensile test is a very complex test. Brittle fractures show little or no distortion, they occur in the elastic regime. Ductile failure occurs in the plastic regime. One of the first things I do when I go look at a fracture — sometimes I only look at a photo someone sends me — I'm looking to see if there's any stretch to the metal. Out in Arizona, a year ago, some guys had some big forklift machine lifting pipes for a pipeline. The thing that was holding all these pipes — they were lifting up fifty tons of pipe — and the container on the forklift broke, did a lot of damage, millions of dollars of damage. Someone said, well, why did it fail? I looked at the photos, and the steel bent before it broke. So the steel is ductile. I knew right there it was an overload failure. I didn't even have to go see it. I sent someone else to go look at it.
If it had been brittle and there had been no distortion, if it broke like a teacup so that you could glue it back together with Krazy Glue — that's brittle, and there is no way to predict the load it failed at, unless you know the size of the flaw, in which case I have to get in there and start measuring the fracture surface to see how big the flaw is. But if it's ductile, I don't need to know the size of the flaw. It failed above the yield point. Who designs anything above the yield point? People design things typically at one-third to one-half the yield point of the material, whether it's aluminum or steel or anything else. You have safety factors. If it failed above the yield point, it got overloaded, and the question is, who put so much load on, why was there so much load on there?
A metallurgist could look at just a photo of it and often tell you whether it's ductile or brittle. Then they can go to the scanning electron microscope, from 20 to 10,000 X. Why would you ever look at the fracture 10,000 X? I don't know, it can go that high. We can start looking at features there. We can do a metallographic polishing section and look at features. These are some of the features someone would look at. You don't have to worry about all these details over here. That's instantaneous fracture. We have progressive failures by fatigue, corrosion, wear, and creep. Fatigue is bending the paperclip back and forth — doesn't break the first time, doesn't break the second time, might break the 10,000th time of the stress cycle. We can predict fatigue. We have fatigue failures all the time. Aircraft are flying fatigue machines. Corrosion — now we have environmental degradation of the material: general wastage, roughening, stress corrosion cracking. Mechanical rubbing — that's chemical wear. Fatigue is cyclical stresses, corrosion is chemical, wear is mechanical wear, and creep is high temperature degradation of the material. There are particular features we can look at, and we can tell why something fractured.
§8. Pelloux, the LNG tail shaft, and the limits of analysis [40:15]
There are entire books written about fracture analysis, and it helps to have someone who's been looking at it for ten or fifteen years show you how to do it. Professor Pelloux, who passed away, came from France, got his PhD in this department, went to work at Boeing, came back after three or four years, became a faculty member here, and taught fatigue and fracture. I remember in the mid '80s I had a tail shaft fracture on a liquid natural gas carrier, one of these same ships that was built down at Quincy, that I worked on the steel for the skirts twelve years before. They had a tail shaft fail in the middle of the Philippine Sea. They were going from Indonesia to Japan, full of LNG. When you've got a container ship full of a hundred thousand tons of LNG, that LNG is going to be boiling off, and you would like to have power so that it doesn't blow up. They had to offload it on a ship that was coming back from Japan that was empty, and they had Learjets flying halfway around the world with the right type of fittings. They did the transfer in an out-of-the-way harbor in the middle of the Philippines, and nobody got hurt. It took them a couple of days to offload the cargo. They wanted to know why the tail shaft fractured. I remember bringing in Professor Pelloux because he had a lot more experience.
It was a very interesting fatigue failure, and one of my modules actually talks about that failure and gives you the details. It's an interesting story about how the flaw was there. It was a casting flaw. It was found by the inspector. The steel company in Seattle was losing their shirt on this job. They were rejecting shafts because they shouldn't have ever been on this job — it was too big for them. And the manager threw him out of his office when the guy found the defect. So they shipped the shaft with a defect, and five years later the fatigue crack grew from the defect, and the shaft broke in two, and they lost all power in a critical application.
So we know how to analyze fatigue, we know how to analyze brittle fracture, we actually know how to analyze most of these things, but people don't always apply what they know. Metallurgists think they can go in the laboratory and look at it in the scanning electron microscope, take pictures, and understand everything about it. Mechanical engineers, on the other hand, think they can calculate the fracture strength, except they often don't do the fracture mechanics. They just say, what's the cross sectional area, what are the loads on it, were there bending loads. I would say that virtually 99.5 percent of all metallurgists refuse to do the fracture mechanics calculations, and only ten percent of most mechanical engineers do the fracture mechanics calculations to find out whether their hypothesis makes any sense. Some of the time it makes sense, sometimes it doesn't.
§9. High-entropy alloys, the J-integral, and the fracture mechanics handbook [44:01]
Just to give you an example — this was an article from the last time I taught this course, in Science magazine in 2014. Rob Ritchie, who used to be a faculty member in Mechanical Engineering here, now at Berkeley, wrote this article on fracture in a high-entropy alloy for cryogenic applications. He's at Lawrence Berkeley Lab. They used a five-component alloy: equiatomic chromium, manganese, iron, cobalt, nickel. Equiatomic, so it's not equal weight percent, it's equal atomic percent. They say this is a high-entropy alloy. This is basically using a term to make it sound like it's scientific, because many people don't know what entropy is. What do they have in Science magazine? Here's the Ashby plot of strength versus toughness, same type of thing. This one is a thousand millimeters — they're claiming that would be a 40 inch critical flaw size. Here are their high entropy alloys. Nothing comes up there. Even these things — if this pink area is non-existent materials — I mean, they just drew a big bubble around the actual metals, and most of the metals are about four inches; that's the largest critical flaw you can get.
People are always trying for tougher and tougher steels or other materials. This is a complex one — an alloyed steel. There's your compact tension specimen. Here's the energy versus crack extension. You could measure a CTOD at the opening right there. You pull on it and it starts to open up. Eventually this one will not shatter. This is one of the toughest materials ever measured. This is called the J-integral. The J-integral is what you do when you can't do a fracture toughness specimen. We actually use things called K-one for a tensile fracture — K Roman numeral one. We have K Roman numeral two, K Roman numeral three, depending on whether you're doing tensile loading or shear loading. There's two types of shear, in and out of the plane. The J-integral was developed by a guy named Jim Rice at Lehigh University as part of his doctoral thesis back in the early '70s, late '60s. Rice went on to Brown University, and he's been at Harvard for the last thirty or so years in the area of fracture of materials. Jim Rice is up here, and the next best person in the world is several steps down. Jim Rice is the god of fracture. He's about seventy or seventy-five now, but he's still at Harvard. He's looked at a lot of the fracking that's done. Jim Rice was looking at earthquakes and fracture of rock twenty-five years ago, and a lot of the fracking that's done to make oil today is because Jim Rice basically decided to start thinking about the problem and coming up with ways to fracture rock, which were then applied in situ.
In case you're really interested in fracture mechanics, here's a little book you might want to buy. [Tom holds up a reference book.] The Stress Analysis of Cracks Handbook. I'm sure you all want this on your bookshelf. It's on mine. Third edition, published by ASME Press. Mechanical engineers and materials engineers got together. It's written by the guy who did the work, Paul Paris, who is a professor at Ohio State, and came up with the Paris equation of fatigue. He is also one of the most arrogant people you will ever meet. And then George Irwin. George Irwin was at the Naval Research Lab, worked with Pellini on some of the fracture toughness stuff. He's known as the father of fracture mechanics — Griffith was the grandfather. Irwin basically came up with a lot of the math. It's just pages and pages of formula for looking at different geometries of cracks and different shaped specimens. Just an encyclopedia of analysis of the stress-strain relationships when you're pulling on that Griffith specimen.
You're not always using a simple little specimen. You've got a pressure vessel, or some spherical vessel or cylindrical vessel; you've got edge cracks, you've got embedded cracks. Every solution that anyone's ever come up with is in here. The solutions look something like crack opening profile — this is the crack tip opening displacement formula. People have spent careers working these out. How exciting — just think what you could do. Well, you can't do this, someone's already done it. Think of something else that is utterly boring that you can do for your career. But it's important. I pull that off the shelf about once every three years and use it when I have to.