§1. Why the Liberty ships failed [00:09]
So I did find the part in the report. 4,694 [Liberty ships] floated — literally ships born to join the war effort. 970 of these vessels suffered casualties involving fractures, 24 sustained complete fracture of the hull, one sustained complete fracture at the bottom, eight were lost or broken due to brittle fracture, 26 lives were lost. The fractures came from a combination of low temperatures and stress.
Student: Was it because they were making more vessels, because they were making them in different ways, because they were in the North Atlantic which wasn't a normal travel route? Why did they have problems?
Well, there are a couple of reasons. One is they had never really welded ships before. The first metal ship was around 1860 — a battleship, a portal liner for going across the ocean. We had the Monitor and Merrimack that were just bolted, riveted sheets of steel on wood. And they built the Great Eastern, all metal, and ships like it in the 1870s. Then warships in the Spanish-American War — they didn't have welding technology.
§2. The invention of arc welding and stick electrodes [01:53]
Welding did not come about until we had a voltage source. And when was that? The 1880s, with guys named George Westinghouse and so on. Arc welding was invented by Sir Humphry Davy in the early eighteen hundreds — 1805, 1806 — when he discovered the electric arc. The reason it's called an electric arc: he had two copper electrodes that were horizontal, he was using electricity from Leyden jars and a battery, he pulled them apart and he struck an arc. It was a little bit of flame, but it had an arch because the rising gases created an arch. That's where the word "arc" comes from. And one of the first things he did with this new source was he welded. But no one could do it commercially until the 1880s. A lot of welding books on the history of welding show a French woodcut from the 1850s or 1860s with a battery of Leyden jars in the background and people welding by electric arc. But really electric arc welding didn't exist in a big way until the early 1900s.
There's a lot of work done by companies developing arc welding power supplies, and then developing what we call stick electrodes. [Tom produces a stick electrode.] So this is a stick electrode. Originally people had been welding with bare steel wire. The problem with the bare steel wire is it picks up nitrogen from the air, and when it solidifies the nitrogen gets rejected, and the rejected nitrogen comes out and makes the weld porous. Looks like Swiss cheese. Not small pores — pores the size of a millimeter or so. It's a terrible weld. It has some strength, but it's not as strong as it should be, and it looks terrible in service.
Two things happened. There are two types of electrodes. One guy, Gudov in Sweden, working for a company that's now part of what's called ESAB Corporation — this is the early 1900s — stuck his steel electrode in the mud and welded with a muddy electrode, and the porosity went away. That's the basis of what we call mineral-coated electrodes. This is a 7018 electrode, a common high-quality welding electrode — low hydrogen. Kind of a cement-white coating, flux on the surface. If you bend it, it'll break.
Another guy in the United States — I don't know who this was — found if he wrapped it like a rolled-up piece of paper, he could weld and he no longer got the nitrogen porosity. Didn't even know it was nitrogen porosity back then, but that's the basis of what we call the cellulosic electrode. That one's heated up to about 350 degrees Fahrenheit; the 7018 was heated up to about 800 degrees Fahrenheit to drive the moisture off. This one's full of moisture. They make it out of paper — actually they don't make it out of paper. Lincoln Electric uses old tobacco stocks as their form of cellulose. This is proprietary information. I didn't get it from Lincoln, but I'm told they use old tobacco stocks. I got it from one of Lincoln's competitors, who was telling a story once. Because tobacco concentrates rubidium from the soil. And rubidium, being in the first column of the periodic table, gives up electrons much easier than sodium and potassium. So what could be cheaper than old tobacco stocks, which have no other use, and you get a cheap source of rubidium too, which helps the arc stability. So there is some science to it.
§3. World War I, the Big Inch pipeline, and welded ships [06:43]
In 1900, people learned to make stick electrodes, but they still didn't have really good quality welds. In World War I, there was a professor at Harvard named Comfort Avery Adams. He was known as the dean of American engineers, and as we entered the war he was put in charge of the American Emergency Fleet Corporation, a new part of the federal government to build the ships to get the boys over there. We couldn't fly them, we had to float them. Comfort Adams was an electrical engineer, and he worked on building welding power supplies first in his career. He realized after the war they had never been able to weld the ships because they didn't really have the technology. So he decided in 1921 to form the American Welding Society. He was the first president. The Adams Lecture is the AWS lecture named after him — he was the leader of American welding at the time.
They didn't build a critical structure by welding until the early 1930s. They built the Big Inch pipeline — Louisiana up to New Jersey, 30-inch diameter. They had pipelines before, but they were lap-seam overlap and very labor-intensive. They didn't have riveting guns; they had people with hammers and arms. They would lead pipe joints. And they built the Big Inch pipeline, 30 inch. And then in World War II they welded the ships. They could build five thousand ships with such people. There may have been Rosie the Riveter, but she built aircraft, because they were made out of aluminum, which is even more difficult. So they welded the ships.
So Tom Schultz's question — your question was, why did we run into all these problems? It was the first really massive use of welding of steel, and they didn't know how to do it. And since we're talking about that, I can tell you another thing we don't know how to do, in general. [Tom passes around a sample.] This is a weld in a 17-inch-thick piece of steel. It was part of a forging press they were trying to repair in Pennsylvania some time ago. I didn't count exactly, but there'd be 400, a hundred-and-something passes in here. Weld passes laid by stick electrodes.
§4. Slugging welds and a sailboat on Route 24 [09:52]
That's how they welded ships in World War II. The stick electrode of the time — four to six pounds an hour is what the welder can put down. And what did they do sometimes? They were tired and they would slug the welds. What's slugging a weld? You've got a big thing like this on a cruiser, a battleship — they take a bunch of electrodes, drop them in the groove, and weld over. Talk about a critical flaw size. It's not a good thing. I've only seen one slug weld in my life. We tend not to slug weld.
That one was on Route 24 [coming into] Boston. The guy was from Nova Scotia, and he had a 40-foot sailboat. He'd gone down to Newport sailing races, and he was driving back over to Nova Scotia. He's got this home-built trailer with the boat, and as he's cruising down the highway, there's a big bang, of course he puts his brakes on, and he sees this boat go by. It was his. The trailer broke, and his boat is cruising down the highway with no brakes. And it turns out, someone in the weld — someone took a bolt between two of the angle irons and stuck it in there and welded over the bolt. You wouldn't do that to a product.
§5. Building submarine hulls: Quonset Point fit-up [11:40]
Student: Even though welding by hand causes a lot of imperfections, the boys' ones — like this they push the heavy heads of a submarine, and can you tell us how thick it is? I was surprised. This is technical. They have a frame stand especially for the caps, and now they pre-triangulate them together and make them in a perfect angle so they don't have gaps. And what they do is they run a barrel track across the seam, and they put an automated mechanized welding machine, and they have a geyser strain walk along with it. So they just relax it, and it walks back and forth across the welding every time. And the welds consistently lay down — there's some hundred passes that go into this. And then of course they flip it upside down, gouge out the back of the weld, just to make sure there's a clean surface to weld through. And they're flooding it with inert gas to make sure the accumulation of inert gases passes out down there. And then they do this exact same thing for the reverse side. And of course they buff it out, and then it rolls down the line, and you can't have a defect bigger than three millimeters in there. They crank them out, they're always working on one way or the other.
Thank you. Let me tell about some other submarine stories. Are you familiar with the torpedo tubes? They have to be very straight. They're pretty long — longer than the torpedo. The tolerances are something like a millimeter. They used to weld them up, and of course you get distortion from welding, and then they would machine them with a great big boring machine that would go the length of one of these things. I'm not sure how long they are, but probably 40, 50 feet long. My first student, who went to work for Electric Boat — he's now retired, I'm still working — he figured out how to do it so they would not have to straighten them. When they put the welds in, going around the circumference, they actually had something automated. He put some feeler gauges on the end, measuring distance a couple of feet away, and he could see the angular distortion. What he would do is compensate with the weld. He would stop the continuous weld and go on the other side to pull it back the other way. Or he would actually grind out the weld and put another weld in to cause more distortion in that direction. So he monitored in-process the distortion and corrected for it in this cylindrical joint. And all of a sudden, all they had to do was just a skin pass down the bore, as opposed to taking a quarter inch off.
§6. Jacking pipes into alignment and Navy repair [15:30]
Student: In the shipyard, all the welding is on metal that's like paper and sugar — you hold it, and it warps and bends as you do things to it. So the hole itself will distort. They have these very heavy planks where they basically spot-weld a bolt like a plank-heading on there, and you can attach a C-clamp to it. And the clamping screws onto this tack-welded bolt, and then you can screw it up or down on that bolt. It has a curved portion. So if you imagine here's a seam of two pieces of metal like this, and you have this thing bolted here, and you press it against this piece of metal, and it goes all the way around the circumference. So you have orange clamps all the way around the whole circumference of this weld joint. And then you use an air-powered jack, and you work this whole cylindrical thing within tolerance, then you weld it all and it can take it all. And so this whole thing is under stress. Like the rest of the submarine's life, there's some degree of inherent stress in the metallic structure because you had to line this up with an exact tolerance.
Student: I was on the repair side of it. We have a lot of corrosion issues with carrier nuclear piping that we're dealing with right now. Back in the shipyard, when they built the thing, they would jack a pipe — if it didn't line up, you jack it on tight and weld it. And now we go in years later, and we cut that pipe out and realize you can't just rebuild it and have your piping line up with no stress. So now you refabricate entire piping systems with pretty complicated processes that hold it back together because it was easy to just crank it over a few inches and weld it. There's a lot of resources that go onto a ship.
If you look at manufacturing tolerances, a typical manufacturing tolerance — it doesn't matter whether you are doing semiconductors, chips, or ships — a typical tolerance is 1 part in 2,000. So if you're a machinist, and you ever work on a lathe and you're trying to machine something to one inch diameter precisely, you can get about five ten-thousandths of an inch without too much difficulty using a micrometer. You can machine it to that tolerance. That's a typical tolerance, and it doesn't matter. But if you talk about a ship that's a thousand feet long, that's a one-inch distance. If you're off by an inch, the hulls don't come together. So shipbuilding — Alan Brown from the Ocean Engineering Department pointed this whole tolerance thing out to me once — shipbuilding was the most precise manufacturing that we did in terms of parts per thousand. About one part in 20,000 in terms of the tolerances you have to put. And when the sun comes out, or a cloud goes in front of the sun, the whole ship changes shape from solar heating. And you have to weld these things so that there's not a bunch of mismatch.
Student: Yeah, I was the docking officer at the shipyard before I came here, and we dealt with that a lot. You build a carrier — it has to be long, and you've got to dock it on wooden blocks. The sun comes out, the front end of the ship lifts up because of the temperature. Down in Pascagoula, we actually have some sun shades, basically when you're welding out there in the hot sun — they have to control the solar heating.
§7. The come-along, the safety chain, and Boeing's five-pound rule [20:23]
There are a lot of little different things in welding that they have to worry about. The jack clamp also has some chain attached to it. Why is the chain there? The idea is, if you have welded that spot-welded bolt on the side of the hull, that's under pressure because you've lined the holes — it could explode across the hole during the maintenance build of the facility, and you could blow someone with that kind of force. So the chain is there to catch that case. Of course the only reason they do that is because it happened.
Student: I'm sure everyone who's worked in a shipyard has seen that guys put in a lot of effort that you don't feel you design. You know, the guys who can pick up job instructions for a brilliantly detailed job, then go down there, and the guy picking it up on board goes, "Ah, use a come-along to pull this against another piece." We've got stories about that, something that was done that one game. I don't have a story of a come-along thing that I did.
A Boeing story about fit-ups. Now there I'm dealing with plate two or three inches thick. By the way, at Quonset Point, when they have their welding for the whole sections in the vertical — the reason is, if you make four welds at a time when you're horizontal, you can only make one weld when you're vertical [correction: vertical orientation allows four welds at once]. Even though each weld goes slower, making four at a time is faster than making one. And you get better residual stresses and less distortion. When they do that, they have to cover the top so the Soviet satellites can't measure the thickness of that hull. Well, I heard that 25 years ago. I thought, "They're pretty accurate from a hundred miles up to be able to measure the thickness?" Because they want to know that thickness within a quarter of an inch — any structural engineer can figure out how this stands up if they know the thickness of the outer shell.
An important news source — Hudson, Yours Whitney — like a year ago, or maybe it was awesome [auspicious?]. They had pictures of some Russian submarine, a post on the blog: here's the commissioning of the submarine, attached to this awesome [stage]. It had some bunting and like shark tank over it — it was like a video from Fox News from a submarine, unfurled a big curtain coming out of it. But like one flap of the curtain was hopping open, and you could see they have a double construction on Russian submarines, you could see both the hulls there. And so the brief from the camera was, this is what we perceive what kind of damage our weapons would do to their submarines based on the hull thickness and assumed devil [shell?] operation. Some kind of bubble formation and collapse against the hull from a computer simulation. So sometimes you think, "Well, why is such and such classified?" — it turns out you can figure out why.
Let me tell the Boeing story. So Boeing has a spec about fit-ups. This is not a come-along, this is sort of a Boeing spec. Boeing has a spec that when you're building an aircraft, you're going to rivet the hull to the inside ring stiffeners — submarines aren't quite this way; it's made out of a lighter material. The amount of force you can apply to bring those two into registry before you make your rivet has to be five pounds or less. That's the general spec. And this is one of the problems Boeing has — they have general specs. They like to write general specs, and sometimes a general spec doesn't fit a particular application, but nonetheless they are. So worried about the residual stresses on the skin of that aircraft, the structural engineers sitting in manufacturing say: you have to form it so that it fits together within a few thousandths, and you cannot apply more than five pounds of force to bring it into line. They can apply 15 pounds. You're applying more than five pounds on the ships here.
So there are different specs for different applications. In the Boeing case, they're worried about fatigue and the residual stresses around the little rivet holes. In the Navy's case, you just want to make the thing fit together right. And then when you come to repair it, you're lucky. I've seen situations where someone cut something and the whole thing goes flying, because of the residual stresses that are locked in. So come-alongs are great, but there's a spring tension that not everybody is going to be worried about.
§8. What is steel? The iron-carbon diagram and John Chipman [26:20]
So let's actually start talking, after two hours of lecture about welding, about metallurgy in general first. One of the students last year asked me the question, "Why are there so many steels?" We're going to get to that. First we have to answer the question: what is steel? You might know the technical definition of steel: it's an alloy of iron and carbon. And if you go to the metallurgical literature, you'll find a phase diagram for iron-carbon. This was the aluminum-copper phase diagram I showed you a while ago. This is the iron-carbon phase diagram. If you look down at the bottom, which you can't read, in pencil — John Chipman. John Chipman was the guy who developed this diagram in 1973 or so. He was actually retired when I came as a student, but he developed this diagram. We talked about steels, and they didn't have the same quality steels back in the old days as we have today.
John Chipman came to MIT in the 1930s. He was a physical chemist from Georgia Tech, a wonderful gentleman, a southern gentleman. John basically used the principles of physical chemistry on high-temperature melts of steel. Rather than aqueous solutions, which is what physical chemists like to study, he applied physical chemistry to 1500 degrees centigrade steel melts. A lot of this was done in the basement of Building 8 over here. John Chipman worked on the Manhattan Project. He was developing ceramic materials that they could melt uranium and other reactive metals in, because the uranium and plutonium would react with any oxide. He was actually working on sulfides. John Chipman developed the technology to make steel reliable, and there are stories I won't go into. But some of his books or treatises will be found in Chinese libraries enshrined in Plexiglas, because this is the seminal volume that taught the world how to make steel.
Steel is usually carbon steel, by the American Iron and Steel Institute standard. It's an alloy of carbon, iron, manganese, sulfur, phosphorus, and they also have — okay. This is the iron, and iron is a high-toughness high-strength material. Carbon is there because carbon can give iron exceptional strength. The iron-carbon phase diagram — this is iron going up here. This is temperature, this is 1500 degrees, this is the vaporization, the vapor pressure line, curves as function of the carbon. This is graphite, melting at 50, 300 degrees, or subliming at 50, 300 degrees. Steels are right down here in this corner, cast irons are over here. This is the low-melting, just like the aluminum-copper eutectic. A cast iron has three or four percent carbon in the iron, and it melts not at 1500 centigrade but around 1200 centigrade. A lot easier to melt cast iron.
§9. From Bessemer to basic open hearth [30:27]
We've been making cast iron for thousands of years, but it wasn't until 1856 that Henry Bessemer style-melted steel. Where does steel come from before the 1850s? It either came from meteorites — which made it very valuable, fairly rare — they would take meteorites, which are iron-nickel alloys, and they'd beat them down into swords. Or they would take iron ore and reduce it in a rarefied atmosphere with a lot of carbon, and they would get carbon monoxide, taking the oxygen out of the steel as carbon dioxide, and you get sponge iron. Basically solid-state reduction, and you get this porous spongy iron. The Japanese were doing it a thousand years ago, the people in the Basques were doing it 2,000 years ago. India used to make steel, and that's where the steel sword blades came from. But it was a very laborious process — spongy iron, you ever seen pumice from lava, fifty percent air — a guy would forge it until he knocked all the air bubbles out and forged it together. To be able to make steel really didn't happen until the application of fossil fuels.
To make steel with fossil fuels, you have to preheat your steel. The Bessemer converter looks something like this. [Tom sketches.] You turn it halfway outside. You have the molten iron-carbon down here. You put cast iron in here, which is three or four percent carbon, and to make it into steel you've got to be less than one percent carbon — you've got to burn the carbon out. They knew they could do that, because they had made wrought iron for years by blowing oxygen in. But as you blow the oxygen in, the wrought iron's melting temperature increases, you get rid of your carbon, and it solidified on you. They made wrought iron up at Saugus Iron Works in the 1630s. But it was a very inefficient process of heating, reheating, getting the carbon out by oxidizing it away.
What Bessemer learned is, if you blow the air in such a way that the exiting gases preheat the incoming gases, you can now get temperatures — hydrocarbons burning in air will get you about 2,000 degrees Fahrenheit, 1200 centigrade. That won't melt low-carbon steel — at 1200 you're still in the solid range. To get that extra three or four hundred degrees, you have to preheat the incoming air. That's what the Bessemer converter did, by bringing the incoming air in one way and the outgoing air the other way. There was a counterflow, very inefficient counterflow, but you basically preheated the air on the end, so the air that got down here to burn with the carbon was preheated to about 1200 degrees centigrade. Now I could get 1500 degrees centigrade in the back.
After that, Andrew Carnegie came up with the basic open hearth, which is what you'll learn if you read George Linnert's 1960s welding manuals. We don't have basic open hearth steel today — everything's basic oxygen [furnace]. But I might as well spend the last little while talking about how to make steel. Carnegie in the 1880s — Andrew Carnegie was the richest man in the world. He was richer than Bill Gates in adjusted dollars. He got rich on steel — the railroads, making steel for them. Evidently he was worth a hundred million dollars then, which is more than a hundred billion dollars today.
What they had was an open-hearth furnace. An open-hearth furnace is nothing more than a big ceramic-lined pot. This thing would be half the size of a football field. You put in a thin layer of cast iron carbon alloy from your blast furnace, and you put a top on this and you blow the air in to burn the carbon off, to take the three or four percent carbon cast iron down to the tenth-of-a-percent carbon steel. The carbon goes off as carbon dioxide. So you get a lot of carbon dioxide. But basic open hearth would have something just as large, actually two of them just as large on either side, which were nothing more than a bunch of ceramic bricks with holes in them, stacked in a lattice arrangement. There'd be one on this side, another on the other side, a stack of ceramic refractory brick. To fire this thing up, you would take some natural gas or whatever and you heat up the brick. The whole thing's about half a football field and stacked up several stories tall. You heat up the brick, you then blow the air through here and into the furnace, so it comes in preheated by the brickwork. The exit gases would go out through the other end, and you run it that way for six hours. After six hours, when that bank was hot, you flip the air, and you do that three times. After one day you tap off three hundred tons of steel. You had to preheat the air. That's how we made steel for the first hundred years.
§10. The basic oxygen furnace and AOD for stainless [37:03]
Then some guys in Europe, in Austria, decided to go back to something similar to the Bessemer converter. They would have a huge vessel four or five stories tall, steel lined with ceramic so you can melt steel in it without melting the steel shell. You have a massive steel pot maybe three or four feet deep. You pour the hot cast iron in here, and then you bring in a lance, a water-cooled copper lance, maybe about three-quarters of a foot in diameter, and you blow at supersonic velocity pure liquid oxygen down. That creates a froth of steel. They will fill up a 700-ton vessel — and in 20 minutes you can do what took 24 hours in a basic open hearth. The basic open hearth was surface diffusion. It was air going across the surface. You had to transport that carbon to oxygen one way, the carbon dioxide the other way — slow process, low area of contact, a surface reaction. Over here it's like shaving cream. You've got lots of surface area. And it's pure oxygen — you don't have to add any heat, you're burning carbon in there. In 20 minutes, 300 tons of cast iron becomes 300 tons of steel.
Oxygen-blown steel — if you get down low enough in carbon, when you get down to less than a tenth of a percent carbon, the carbon will keep the oxygen low until you get very low carbon. But then if you get very low carbon, it gets really expensive to get the last part of carbon out. And for stainless steels we have to get the last part of carbon out. If you went down to where the glass slab is — the basement of Building 8 — that's the room where the original research was done by a guy named Christy in the 1950s, in his doctoral thesis with John Chipman, where he was studying just the carbon monoxide reaction. He had a melt of steel and they could bubble oxygen up through it to understand the carbon monoxide reaction, and measure the off-gases. He wanted to get to even lower pressures of oxygen, so he started bubbling argon with a little bit of oxygen — he wanted to have less than one atmosphere of oxygen, so he diluted with argon, and he was able to do his research from low carbon concentrations.
Then he went to a company called Crucible Steel to work, and they got together with Union Carbide. They couldn't get any big steel company to listen to him. They found a team at Crucible Steel — a small steel company that was willing to take a vessel, modify it into a real production vessel, and blow a mixture of argon and oxygen through the bottom of the steel bath. It's now called argon-oxygen decarburization, AOD. All five million tons of stainless steel made in the world today is made by this process. Stainless steel is one-third the price it would have had in the 1950s before Christy took his doctoral thesis from MIT. AOD was not invented at MIT, but the scientific principles were done by Chipman.
§11. The strength of steel and the hardening of iron [41:37]
So carbon makes iron very strong, but is it steel? How does taking as much possible carbon out of steel make it steel? We're going to talk about that. Steel is needed and has a lot going for it. Titanium has the same advantage. It has a different crystal structure at low temperature — body-centered cubic — that turns to high-temperature face-centered cubic. I can demonstrate that later. Because of this it goes through a transformation, a solid-state transformation at 723 degrees centigrade if it's a ten percent carbon. If it's zero carbon it would be 910 degrees centigrade. The strength of steel is a very strong function of the carbon content. This is out of the book called Steels by George Krauss, who was one of Morris Cohen's doctoral students here, retired from University of Colorado, and then at Lehigh University. He's Mr. Steel today.
The guy who was Mr. Steel before that was Morris Cohen. He was an assistant professor here after World War II, when they had all the welded ships cracked. There were three places that did the study based on this stay-dry report on Show HBU. One was MIT and Morris Cohen on brittle fracture of steels. Another was the Naval Research Laboratory, a guy named Pellini at the Naval Research Laboratory. We'll talk about Pellini — when he retired from NRL back in the 80s, he came and spent the last couple years as a lecturer here on course 13, which has ended now, and retired on Cape Cod. The third place was started in 1947 or so by a guy Richard Weck, who was a young engineer in England, pedaling through Cambridge. He was riding his bicycle into this little town called Abington — he decided this is where the British welding researchers should go. So the three places in the world that really studied the fracture of steel in the late 1940s, which is one of the things that caused all these ships [to fail], along with poor quality steel.
The poor quality steel: if you have too much oxygen, you don't get the oxygen down. One of the ways to get the oxygen down is you throw some silicon or some manganese in to get out that last oxygen. So first you take cast iron, which is iron-too-much-carbon, and then you've got to get rid of the carbon by blowing oxygen through, and then you've got to get the oxygen down to get the toughness up. There's a whole series of processes, and we'll go through some of those.
Morris Cohen was here, Krauss was one of the students, and this comes out of this book. This is the carbon content versus the hardness of the steel. You can see, up to about six-tenths of a percent carbon you have a tremendous change in hardness of the steel, and then a law of diminishing returns over there. So what we're going to learn tomorrow is the difference between hardness, hardening, and hardenability. They're very different terms. Hardness is how hard it is, how much it resists indentation. Hardenability is how deep you can do that, and how we change that. Question?
Student: What does the cross-hatched area show?
That's retained austenite. Austenite is the FCC structure that didn't transform. Only George Krauss would get into those details.
One of the most important things about steel, and something man's done that's unique — something that I did my junior year humanities term paper on, in my crosshair — was the hardening of steel. You can take the same steel, just cut as it comes off the mill, and it's relatively soft. Or you can take it and heat it up, quench and temper it, and you can make it into something like a file. I can file down or order this thing with another piece of steel — this one's been hardened, this one is soft. The ability to take something when it's soft, shape it, and turn it into something that's hard, is the ability to make a tool. We do the same thing with pottery: we take clay, which is soft, we heat it up and we turn it into a ceramic, which is hard and brittle. This is a fundamental ability of making tools that humans have, that even apes who might use tools don't have — they just take something hard, they don't know how to transform the material into something that is hard.
I actually wrote my junior year paper, in the history department, on steel. And there are interesting ways over the years. The Muslims during the Middle Ages thought that the best way to quench the steel — you heat it up, it goes red-hot, and ordinarily you'd quench in water or oil — they liked to take a Nubian slave, a living person, and run the hot sword right up through, push it up. They felt it gave a better edge to the sword. So if you wanted a short-term profession, you'd be the quenching medium for Mr. Steel by the sword. Or sometimes they take the hot steel and quench it in blood rather than in water.