SMS_S2016_08

Structural Materials Selection Spring 2016 Session · 8 sections 14 cases · Watch on YouTube ↗ all files
Layer 3 — readable edition

§1. Power-by-the-hour: maintenance economics in aviation [00:00]

§1.p1

Honeywell makes the brakes for the airline, and so it's a great symbiotic relationship. Honeywell has an incentive to develop brakes that last longer, because Honeywell has to replace the brakes. If a mechanic comes to Honeywell and says we need to replace the brakes, Honeywell has to pay for the new brakes. But the airline has fixed costs. They know exactly how much they spend on brakes for every landing. So Honeywell has fixed costs, their accountants are happy — not Honeywell, but American Airlines, whoever the airline is — they can calculate what the profit should be. And then Honeywell has an incentive to make a longer-lasting brake. The mechanics don't care about the cost of replacing the brakes because it doesn't cost their employer anything for them to decide I need to replace the brakes. Just takes time. The cost of the brakes is borne by the manufacturer.

§1.p2

The airlines do the same thing on engines. They call it power by the hour. The airline knows that for every hour that engine is operating — and you have to keep a log of every minute the engine is operating — they have to pay so much money to the owner of the engines. And the owner of the engines could be General Electric, it could be Rolls-Royce gas turbines, it could be a number of people. They're responsible for maintaining that engine, repairing that engine, and they lease it back to the airlines. Most of the aircraft you're flying on are owned by some big investment company. American Airlines typically doesn't own that aircraft. They're leasing it. They pay a certain amount per month or per hour or whatever for the engines to one company, for the airframe to another, for the brakes to another. It actually is not a bad system. It's sort of like Zipcar — you're renting the car.

§1.p3

That wasn't what today's lecture is going to be about. I appreciate the digression. Jordan's going to give a talk on why everything I said about two dollars a pound savings is wrong for the BMW — for electric vehicles — and how they change the rules because of different constraints. I'm just glad that I talked about collateral weight savings, because his story is basically about collateral weight savings on batteries. So I stole your thunder, but it's a great presentation. I was going to tell you how to think about writing a paper on it, seriously — I thought about exactly where you publish it. It's an interesting story and you've certainly quantified it more than the Wall Street Journal would. There's nothing wrong with having assumptions as long as you state your assumptions in a paper. Many people don't bother to state their assumptions, and then you run into problems.

§2. Corrugated stainless steel gas tubing and lightning [03:18]

§2.p1

Anybody have any questions before we begin? Last time was a recitation on competition among materials for water transport and then gas transport. I showed this but it was the end of the hour and I didn't pass it around.

§2.p2

[Tom holds up a piece of corrugated stainless steel tubing.] This is corrugated stainless steel tubing. There's about six billion feet of this in the United States, through many people's homes — in the newer homes and as replacement in older homes. It's got polyethylene — this particular product has a yellow plastic jacket. It's not really supposed to be for insulation. The yellow is supposed to identify it for gas piping. There's another company that's made little connectors like this for forty or fifty years and they paint them yellow.

§2.p3

This actually has a tube of plastic around it, and the plastic has low coefficient of friction. You can pull this through the walls, and the corrugations don't get stuck on the corners as you drill a hole through a two-by-four or through a steel I-beam or something. So it does have a function other than just provide color. It does also provide electrical insulation, so hopefully it won't short out and arc to your household wiring. But if you have a small manufacturing flaw that you could never see even under a microscope, and you have a very high voltage discharge — in this particular one we actually probably put a little copper wire through here — there's a very small hole, and the electricity went through that small hole and you can't see it. I'll pass it around. It created a hole about ten times the diameter in the steel underneath. The electricity doesn't attack the coating of the plastic, but it doesn't take a very big hole for all those electrons to get through the plastic. Once it hits the steel, it melts it.

§2.p4

This also occurs on aircraft wings. If you paint an aircraft and lightning hits it, the paint can actually focus the lightning energy, and it can take one ten percent of the energy of a lightning stroke to perforate the wing on an aircraft. What's the problem of perforating the wing on an aircraft? Fuel. Your aircraft wing is actually your fuel container. It's your structural wing for support, but it also contains fuel. So they do lots of tests at Boeing and other places. I had a student do an internship at Boeing and she was working on lightning strikes to aircraft wings, although she was doing composites. I know a lot about what happens when you hit an aluminum wing that's bare, or a painted aluminum wing — the two things are different. Just putting a coat of paint on it makes a big difference in how the lightning attacks it. But Chu was working on composites because Boeing wants to use more and more composites to make lighter and lighter weight vehicles.

§3. Ashby plots and stiffness: E, E^½, E^⅓ [06:39]

§3.p1

We were talking about some of the competition among materials for different things, and I'm going to change course a little bit and get more into structural material design. I already pointed out that Ashby wrote a number of books. One is Material Selection in Mechanical Design, and I've shown you the little pamphlet. In that he has a lot of these — now known as Ashby plots, because he was the first person to do them.

§3.p2

Ashby has a whole series of these plots that plot two material properties against one another. In this case he's plotting Young's modulus versus density. It turns out E over rho — Young's modulus divided by density — shows up in a lot of mechanical property formulas. If you look at the page before this in his book: Young's modulus E versus density rho, E over rho equal to some constant will be minimum weight design for stiff ties. A stiff tie being something like — you know what the hammer throw is in sports? You have this steel ball connected to a rope, and the guy picks it up and swings it around, and centrifugal force — he lets it go and sees how far he can throw the steel ball, which is a 16-pound ball or something.

§3.p3

That tie has a certain tension in it. For stiff ties — the string that's holding the ball to the handle he's got in his hand — minimum deflection in centrifugal loading is the example. E to the one-half over rho is minimum weight for stiff beams. [Tom produces two rulers.] I have two rulers here from my briefcase. This is a very thin plastic beam. This is also a thin beam, same size ruler, but this one's got a magnetic stripe on it. It's a lot heavier and you can see this one sinks under its own weight, like a diving board. This one's stiffer even though it's thinner. It's a different plastic — this one is heavier basically.

§3.p4

So you can get stiffness from two different properties. One is Young's modulus, which is a property of the material. It's related to the Lennard-Jones potential and the bonding between the atoms and how strong that bonding is. Young's modulus is the second derivative of that energy potential minimum. The steeper that is — the highest Young's modulus for any material is carbon. Tungsten is not far behind that in steepness of the Lennard-Jones potential. This is energy of bonding versus distance, radius between two atoms, and the steeper it is, the sharper the curvature, the higher the melting point. The melting point is basically related to the depth of that energy potential well, and the stiffness, the Young's modulus, is proportional to the sharpness of the curvature. Tungsten and carbon — being diamond — are two of the stiffest materials we have. There are limits to that.

§3.p5

You can get stiffness from a material property, and there's one other way to get stiffness. What's that? Design — thickness, cross-section, geometry. It turns out for equal areas, what would be stiffer, a solid rod or a tube of equal area? A tubular section is stiffer than equal weight, equal material of a solid rod. So you can get stiffness from two things. What this Ashby plot gives you is E over rho for tensile stiffness — if you swing the ball around on a steel rope, you'll get less stretch than if it's on a rubber rope, because Young's modulus is larger. E to the one-half is minimum design for beams, like I talked about. E to the one-third over rho is for plates. A piece of paper — how stiff is that sheet compared to some other sheet of some other material? These are not the same thickness. The rubber is flimsier than the paper. The paper actually has a higher stiffness.

§3.p6

Ashby will have all of these on one plot. The advantage of an Ashby plot is you can see all kinds of properties on one plot for two properties. Here are guidelines for minimum weight design: E over rho to the first power, E over rho to the one-half, E over rho to the one-third — and they have different slopes, and you can compare those slopes. The slopes he's put in here are E over rho to the first power equal to ten to the fourth. That actually has units of meters per second. Does anyone know what E over rho being meters per second is used for in the mechanical behavior laboratory? You've heard of stress-strain curves, right? Young's modulus is the slope of the elastic region, and then you have the plastic region. How many people took a class in high school or as a sophomore in mechanical behavior, where they told you to calculate Young's modulus from the stress-strain curve? It's not the way you do it in the real world.

§3.p7

You actually put a vibrational frequency in a rod and measure the speed of sound in meters per second, and from that you get a much more accurate Young's modulus. When you just try to do a tensile test — it's easy to show students the principle of measuring Young's modulus by the slope. You try to do that on a piece of aluminum, and you have 15 students do it, you'll get numbers between seven and 15 million pounds per square inch, and the real number is 10 million. Because of slippage in the grips and things like that. So it's not that easy to measure Young's modulus unless you do it by frequency.

§3.p8

In steel mills they have little machines — you take a little strip of steel and slip it into this machine and it measures the speed of sound in that steel in a particular direction. You have a great big sheet of steel, you cut out a specimen longitudinally, a specimen transverse, and a specimen at 45 degrees, and you measure the speed of sound in each three. That modulus will be different in each three directions because of the texture of the crystals in the steel, and that steel will draw differently when you try to make a Coke can or something like that out of it. You can predict the drawability of an automobile body based on the speed of sound, which is related to Young's modulus and the stiffness. It's called a Modul-R machine, and if you take my deformation class I'll go through it.

§4. Tungsten carbide, sintered diamond, and asphalt-reclamation tools [16:29]

§4.p1

So here's a plot. The stiffest material is diamond, 60 million. Down here are the metals, and steel is one of the stiffest metals, although tungsten alloys are higher than steels. But the highest is diamond at about 60 million. Here's a composite, tungsten carbide plus cobalt. It's really the tungsten carbide. We like to use tungsten carbide as a structural material. It's stiff for lots of things. But the problem is — anybody know the problem with tungsten carbide and why we don't use it more often? Cost. Ten thousand dollars a pound. To form tungsten carbide you have to have furnaces that go well above 2,000 C — 2,600 degrees C in some cases. [Tom holds up a tool bit.] This happens to be a tool bit that we cut apart. It would have looked like this. You would have several hundreds of these on a machine.

§4.p2

You ever been driving on the interstate late at night and they're reclaiming the asphalt? They have a great big machine. This is the tool that's on the wheel that's beating up the asphalt and throwing it back into a trailer to be recycled. And you can wear out these tools in three or four hours, in which case you have to stop the machine. The mechanic has to go in — you're doing all this in the middle of the night, you're paying people double time to work in the middle of the night on the highway, because you don't want to disrupt the traffic. You'd like to have something that lasts for a good eight hour shift. Lot of wear on that.

§4.p3

If you look at the details — this one's been polished better than the other one — and pass this around — if you look at the tip of this particular one, there was a company out in Utah. There are a lot of people out in Utah who would like to work on diamond, because there was a guy at General Electric, Tracy Hall, in the 1950s, who developed the ways to make man-made diamond when he was at General Electric Research. From the tip of this thing all the way up here is tungsten carbide. It looks sort of copper colored, but I'll tell you the reason for that. This is actually sintered diamond. Ordinarily the tip of this thing would just be tungsten carbide, and it would wear out in three or four hours. If you could make sintered diamond tips on these things, they'll last more than eight hours, because you've got more wear resistance because of the stronger material. I was asked to help evaluate it because one company wanted to know if they wanted to buy this company, and they finally decided it was a great product, technologically superior, but it costs too much, so they didn't buy the company — at least that's what I heard last. They did step brazing and other things; I won't get into that.

§4.p4

Diamond is right at the top, and that's what they were able to put in there as a wear-resistant hard structural material, because tungsten carbide, which was almost as good, would have one-fifth the life of the diamond. So small differences can make big differences when you get to things.

§5. The rongeur: sapphire as a stiff structural material [19:45]

§5.p1

This is for stiff materials. Once upon a time, back in the 1980s — so this is 30 years ago — I used to do a lot of consulting for a firm south of Boston, been around since the 1830s. It's now a division of Johnson & Johnson, makes medical instruments. Does anyone know what a rongeur is? I never knew what it was. It's a French word. A rongeur is basically a pair of pliers that an orthopedic surgeon would use to chew up bone, to break up bone. So a rongeur is just a pair of pliers, and it has a little cup in it, so you can go in there and just bite away the bone. If they're going to fuse someone's spine or something, they go in and he chips away at the bone, removes the bone he wants to remove.

§5.p2

When people wanted to do arthroscopic knee surgery, which was somewhat new — I have torn cartilages in both my knees now, but I had one of them since the 1960s when I got injured in a football game. Back then, in the 1960s, to remove that torn cartilage they would have to lay open your whole knee and you'd be in a cast and on crutches for up to six months. Nowadays you can walk out of the hospital that day. You might have crutches for a week, but basically they go in with microsurgery. Rather than opening up your whole knee, they go in with microtools, they put a little slit in there, and with a little fiber optic so the surgeon can see what all the blood and guts looks like in there and try to see what he wants to cut. He can go in with a little rongeur to eat away and pull out the cartilage. Minimally invasive surgery — this is one of the first big applications.

§5.p3

The rongeur for that application looked like this. [Tom holds up a rongeur.] It's basically a pair of pliers — a sliding mechanism, and the cutting end is down here. You have a little post sticking up and a slide above, and you go in there and just eat away the bone or the cartilage. They tried to get smaller and smaller in their tools, and you can see I've got a stiffness problem here, right? They were making them out of steel. Steel's 30 million. They came to me and said, well, what can we make it out of that would be stiffer? You can go to geometry, you can go to a tubular section, except they were trying to get them smaller, and tubular sections are larger.

§5.p4

First of all, there are not a lot of choices. I didn't have an Ashby plot back in nineteen eighty-two whenever they asked me this question, but I knew the properties of materials, and I knew my choices were diamond — and I didn't know where I could get a nice long slender diamond like that, but it would be a great tool. Might be pricey, but this is a medical instrument, so you can charge a lot for it. Silicon carbide — I didn't know how I could get any reasonable cost silicon carbide. But if you look at the top there's alumina. What's another name for aluminum oxide? Sapphire. [Tom passes a sapphire boule fragment around.] This type of piece of sapphire was not single crystal. It's grown in a boule that was about the size of a great big beach ball. It took about a month to grow it in the furnace. You put the aluminum oxide powder in, take it up to the melting point which is above 2,000 degrees centigrade — somewhere between 2000, 2100 centigrade for pure alumina — and you cool it down very slowly over about three weeks before you'd open up the chamber.

§5.p5

It's a ceramic. It's aluminum oxide. Sapphire is another name for it. We grow sapphire boules like this now. A sapphire boule like that cost about a hundred thousand dollars. That was just a chunk. You can saw it into little substrates, and the reason they were making these — because every LED has an aluminum oxide sapphire substrate. Just like a silicon chip on a computer, you have an aluminum oxide sapphire substrate. Doesn't have to be single crystal because it just has to match the coefficient of thermal expansion closely of the gallium arsenide that's making the LED. So it's a big business now to make all these LEDs, and that's what this company was making all this stuff for. They were up in New Hampshire. They were selling this technology — who were they selling it to? China gave them a three hundred million dollar order for a bunch of these furnaces. And now guess who owns the LED manufacturing market, because they own the business of making the sapphire substrates? China.

§5.p6

They would slice them up on diamond saws, because what's the only thing that's going to cut that? On the old Mohs hardness scale — what material would scratch another material — diamond was number 10. What's number 9? Sapphire. Sapphire would scratch anything but diamond. Silicon carbide will actually scratch sapphire, but silicon carbide is not a natural mineral. On the Mohs scale of natural minerals, at the bottom is talc. Talc is nice and soft, then gypsum might be number four. The mineralogists for a hundred and fifty years have had this hardness scale. Diamond at the top, sapphire number nine, and I can't remember what number three was. We've come up with other things since — silicon nitride, silicon carbide, boron nitride, and Sialon — silicon aluminum oxygen nitrogen. They're fairly strong.

§5.p7

[Tom holds up a pair of surgical scissors.] This is just a pair of scissors a surgeon might use to snip some part of the body or cut suture. Back in the 80s this was a $300 pair of scissors. They're probably six or seven hundred now. It's brazed on the surface with a cobalt alloy for excellent wear resistance and strength and maintains sharpness. Once you buy this pair of scissors you can send it back whenever it's dull and they will sharpen it for free and ship it back to you. Gold-plated handles, so you know this is one of the premium grades of stainless steel scissors. I used to help make stainless steel instruments like this. Every one of them's got a hardness indentation on it because they do a hundred percent check on the heat treatment hardness. It's better than your Fiskars scissors. I don't mean to knock Fiskars, but this is a better scissor.

§5.p8

Physicians will pay a fortune for these things. Some physicians — Dr. DeBakey, the famous heart surgeon, he liked a particular color, so they would color the instruments the color he liked because it was his favorite color of instrument. If you go to a dentist's office, you'll sometimes see some of the dental tools color-coded. You can go to Sears and buy tools that are color-coded for different sized ratchets and wrenches. Color coding would have been great with sapphire. You could have added a little chromium to the melt, and if you added chromium to the melt you would have made ruby. So you could sell ruby instruments to the surgeon. You could charge a fortune for these things. "I was using ruby instruments when I cut your leg open."

§5.p9

So I wanted to make a rongeur out of sapphire. I was confident you could buy it — there's a company that started here in Cambridge and they could grow single crystal sapphire tubes or rods or sheets. They take this 2000 degree melt and they slowly pull the stuff out of the melt, and grow things of different size. I actually have some silicon like that in my office that Professor Sachs — who was one of the inventors of the name 3D printing — he started a company that has since gone bankrupt. They used carbon fiber wires, and they would lift a sheet of more polycrystalline silicon for solar cells. They're about three or four inches wide and you grow the silicon right out of the melt as a thin sheet. You didn't have to cut it with diamond or anything else. It was going to take over the solar cell market 25 years ago.

§5.p10

Problem is, if you look at it cross-eyed it will fracture. Silicon is an extremely brittle material. [Tom holds up a silicon crystal.] This is a chunk of silicon, single crystal, grown by a Czochralski process. It's completely brittle. Fractures just like that piece of sapphire. The easiest way to break it is just whack it with a hammer, and it breaks. Takes a big hammer to whack the sapphire because it's pretty hard. Silicon is pretty hard. As I pass this around — those surfaces are darker because it's grown in a vacuum system. That surface has oxidized a little bit. You actually see some fracture patterns, which if you knew anything about fracture surfaces, you might think that's a fatigue crack, because it has little what we call beach marks. In a brittle material like glass we call those hackle marks, and they're not from fatigue cyclical loading. It's just the way some very brittle materials fracture.

§5.p11

Anyway, for Young's modulus reasons I wanted to use sapphire. They never would believe me that you could buy this stuff. You can buy sapphire rod for fifteen dollars. You can buy sapphire tube probably for thirty dollars for a foot long tube, and it's twice as stiff as steel. I knew I could put a solid rod and use the diamond to make a cutting tip on one end, and do something to put a tip on the other end, and basically make a rongeur of a rod sliding through a tube. They didn't like it. What do you hire a consultant for if you don't listen? They thought sapphire would be too expensive. I thought selling sapphire and ruby instruments would have great marketing appeal, and for simple instruments, simple cutting tools, you wouldn't find a better material. It's right behind diamond on hardness, so the wear resistance of the cutting edge is fantastic. The toughness is better than a lot of the ceramic tools they use for cutting edges. They didn't like the idea, they never would try it, and they never would tell me a reason why they didn't like it. What they said is, we want something stiffer, and I said, if you've only got a handful of choices, look at the Ashby plot. We didn't have Ashby plots back then, but I said there are only a few materials.

§6. National Aerospace Plane and the Mach 17 warhead [34:07]

§6.p1

It's just like for the National Aerospace Plane in the mid-80s. They wanted to develop the surface of the airplane coming back into the atmosphere. The National Aerospace Plane was supposed to be a supersonic transport. They would actually get up into space and then come back down, and it could be two and a half hours between any two cities on the globe, because you'd be going at Mach 17 up there in space. All you had to do was make the boost into space, do your travel with no air around, come back through the air, and land. This was actually partly — they never said it — but it was also part of Reagan's Star Wars initiative, because if you could put civilians up in space, you could put hardware up in space and weapons in space.

§6.p2

It turns out if you look at that Mach 17 coming back into the atmosphere, the frictional heating will give you surface temperatures of 3,000 degrees kelvin. So they had a great idea — we'll make it out of copper, and liquid hydrogen will be our fuel, and we'll cool the inside with liquid hydrogen. I don't know where they get these people in the Air Force, or some of the aerospace companies, to come up with these ideas. So this was going to be copper skin, this was going to be 3,000 degrees centigrade air, and this was going to be liquid hydrogen. Anybody see a problem? The thickness of the copper was going to be about an eighth of an inch, three millimeters. You don't have to worry about lightning strikes because you have a better chance of just blowing yourself up. Here's the Space Shuttle Challenger all set to go. How many billions of dollars did the US government spend researching how to make this work?

§6.p3

You might think it's sort of funny — I thought it was sort of funny until in 2004, I was on another National Research Council committee on aircraft propulsion for the US Air Force. We were supposed to help advise the Air Force on what materials and designs to use for the three hundred million dollars a year the US Air Force had over the next 20 years to develop better motors. They came in and gave us a non-classified presentation — the Air Force wanted a Mach 17 warhead to fly through the air, not through space but through the air, at Mach 17. The reason was — this is before they killed Osama bin Laden, somewhere around 2004-2005 — they had actually located Osama bin Laden and they had 15 minutes to get the ordnance on site. But he was gone from that region within 15 minutes. If they had the right weapon on one of the aircraft carriers in the Persian Gulf, and it went Mach 17, they could have had it on site and blown him up.

§6.p4

What's the fastest aircraft we have right now? Mach two, Mach two and a half. The F-15, F-16. They burn all this fuel and their skin is getting hot. We had Mach six or seven with the SR-71 Blackbird, this titanium-skinned aircraft that flew at a hundred thousand feet to take pictures of Cuba and stuff, or the U-2 spy plane that Gary Powers flew in '62 — you guys wouldn't remember that. We've built special aircraft, but we've never built anything close to Mach 17. I said, this isn't going to be man-rated. No, it was going to be unmanned — sort of like a Mach 17 cruise missile. They also had another goal: they wanted to be able to fly 25,000 miles without refueling. I said, why do you need that? They said, we've determined we will not be able to have bases anywhere except in the continental United States.

§6.p5

I said, why do you need to fly 25,000 miles, why can't you just fly 13,000 miles and get halfway? They said, no, we want to be able to take off, do whatever we want to do, and come back 25,000 miles, get anywhere on earth and take off and land from the continental United States. The fuel efficiency, the lightweight requirements, and the Mach 17 temperature requirements are just as ridiculous as the National Aerospace Plane. I actually brought in some plots and showed them. They gave us plots that showed 6,000 degree temperatures from the frictional heating near the surface. I used those to calculate just the radiation heat transfer to the surface. We're not even talking boundary layers — you couldn't even leak out a little bit of nitrogen on the surface as an insulating boundary layer, because just by straight radiation, which goes through any gas boundary layer, you would be above the melting point of copper or anything else. It made no sense.

§6.p6

They hadn't even started to worry about the fact that if the top surface of the copper was at 900 degrees centigrade — it melts at 1107 centigrade — and the bottom was at liquid nitrogen, there would actually be some thermal expansion differences and distortion. Somehow they were going to just design those away. And we pay people to come up with these ideas.

§7. Strength vs. density: the Spruce Goose and baseball bats [40:00]

§7.p1

There are other parameters. This is Ashby strength — not modulus, but fracture strength or yield strength — versus density. If you have a minimum weight design for strong ties — remember before it was stiffness for ties or beams or plates — now it's minimum weight, maximum strength. Here's the plot, and it doesn't change all that much, but it is slightly different. You still got diamond at the top. You've just shifted things a little bit.

§7.p2

Over here on the side, in terms of lightweight, some of the lightest weight to strength ratio materials are something called wood. Anyone heard of the Spruce Goose? What was the Spruce Goose? World's largest airplane. Howard Hughes decided to build the world's largest airplane. He built one of them. It was on display for years in Los Angeles, but it's in Oregon now — at that aviation museum in Oregon. I've been there but it wasn't there when I was there; it must have been moved there in the last 10 years. It's called the Spruce Goose because he built it out of spruce. If you look here, ash is the strongest wood. Where does ash grow? A lot of ash grows in Kentucky. And what do we build in Louisville, Kentucky? Baseball bats. Louisville Sluggers. What are they made out of? Ash. Why? Because it's the strongest wood.

§7.p3

Student: What's the advantage of maple?

§7.p4

The answer is, I don't know. And it's not tangential, it's a key question. That would be a good topic — baseball bats. There are also metal baseball bats, which is a whole other topic. I do know something about that, but I won't talk about that right now. If you look at the plot, ash is the strongest. Then we got oak and pine. He didn't put maple on here, but I guarantee you maple's up here near the top too. So I suspect it might be an availability thing. In New England, if you were making bats, you might make them out of maple. In Kentucky there are all kinds of ash trees, which is one of the reasons Louisville Slugger is in Louisville. I have toured the Louisville Slugger plant. At the end they give you a little one-foot-long baseball bat. It's very interesting just in terms of how they rapidly machine bats and how they customize bats for certain players.

§8. Fracture toughness: Galileo, Griffith, Timoshenko [43:41]

§8.p1

Then there's fracture toughness against density. Fracture toughness is this thing that Griffith came up with in the 1920s when he was researching the fracture of glass. I talked about how brittle glass is, and this is where Griffith found out that things can be tough as well as strong. The original strength person to measure strength was a guy named Galileo. Here's a picture of Galileo's test apparatus. If you had a beam and you put a weight on it — this was out of one of his notebooks. He started studying the strength of beams. This is out of a book called The History of the Strength of Materials by Timoshenko. Anybody ever heard of Timoshenko? You've heard the name because he was a professor at Stanford University. If you look on the inside, I think he lived from 1878 to 1972 — he was almost 100, 94 years old when he passed away. Timoshenko was kind of Mr. Mechanics of Materials in the whole country. He wrote books all over the place. If your grandfather studied mechanical engineering or materials in the first half of the 20th century, he would have been studying out of the Timoshenko books. So Stephen Timoshenko wrote this book on the history of strength of materials.

§8.p2

Galileo was interested in strength of materials. We learned in the 1870s — actually even earlier, I'll give some more history Monday. Fracture toughness is the energy of fracture. Galileo was looking at the strength of fracture, and Timoshenko knew about the strength of fracture. Timoshenko lived through the era from 1925 to 1975, where we really learned about the toughness of fracture, which actually is a much more interesting story than just the strength of fracture to me, because we still continue to learn about the need for toughness in materials.

§8.p3

To give you an example — you'll see me doing this on the History Channel, I talked about the Titanic — [Tom demonstrates with a piece of paper.] you can pull on the edge of this material, paper, with pounds of force. If I put a flaw in the material, which is what Griffith was looking at — flaws in glass — I can lose eighty to ninety percent of my strength because of a flaw in a brittle material. Whereas if I have a ductile material, like rubber — [Tom demonstrates with a rubber band.] — that is toughness. I can pull on that piece of rubber and I don't have a sharp notch, I blunt the notch, and so I get lots of deformation without fracture. There's a tremendous difference in ductility of fracture versus brittle fracture, and we're going to talk about that stuff on Monday. Have a good weekend.

Cases referenced

  • Honeywell aircraft brake leasing (power-by-the-hour) §1.p1

    Symbiotic incentive structure — the brake manufacturer bears replacement cost, so it has incentive to develop longer-lasting brakes; airline pays a fixed per-landing fee.

  • Aircraft engine power-by-the-hour leasing §1.p2

    Engines leased from GE / Rolls-Royce; lessor maintains, airline pays per operating hour. Same incentive structure as brakes.

  • Corrugated stainless steel tubing — lightning perforation §2.p2

    Physical demonstration of the lightning-perforation failure. Six billion feet installed in US homes; manufacturing flaw + high-voltage discharge → perforation of the steel through the plastic jacket.

  • Boeing aircraft wing lightning strike — composites §2.p4

    Painted aluminum vs bare aluminum vs composite wing response to lightning; Tom's student internship at Boeing on composite-wing lightning strikes. Connects to the §2.p3 stainless-steel-tubing case through shared failure physics.

  • Asphalt reclamation tool — sintered diamond vs tungsten carbide §4.p2

    Highway-reclamation milling bits wear out in 3–4 hours with tungsten carbide tips; sintered diamond extends life past an 8-hour shift. Tom consulted on whether to acquire the company; verdict was technologically superior but too expensive.

  • Rongeur — sapphire as structural material §5.p1

    Tom's ~1982 consulting case for a Johnson & Johnson medical-instruments division south of Boston. They wanted a stiffer material than steel for arthroscopic rongeurs; Tom proposed single-crystal sapphire (twice the stiffness of steel, behind diamond on hardness, can be color-tinted as ruby for surgeon-preference marketing). Client rejected without explanation.

  • Sapphire boule manufacturing → LED substrates → China §5.p4

    New Hampshire company growing sapphire boules sold furnace technology to China on a ~$300M order; China now owns the LED substrate market.

  • Surgical scissors — medical liability and finish premium §5.p7

    $300 (1980s) / $600–700 (present) stainless steel scissors with cobalt-alloy brazed cutting edge, gold-plated handles, 100% hardness check. DeBakey color-preference anecdote. Used to motivate the sapphire/ruby marketing pitch in §5.p9.

  • Sachs polycrystalline silicon ribbon (1366 Technologies) §5.p9

    Emanuel Sachs (MIT, co-coiner of "3D printing") founded a company that pulled silicon ribbon directly from the melt using carbon-fiber wires for solar-cell manufacture. Was projected to take over the solar-cell market 25 years ago; company subsequently bankrupt.

  • National Aerospace Plane (NASP) — copper skin / liquid hydrogen cooling §6.p1

    Mid-1980s program — Mach 17 spaceplane with copper skin (1/8-inch thick) cooled internally by liquid hydrogen against 3,000 K external air. Tom's framing: structurally absurd; partly a cover for Reagan-era Star Wars hardware-in-space.

  • Air Force Mach 17 air-breathing aircraft program §6.p3

    2004 National Research Council committee on Air Force propulsion. Air Force requirement: Mach 17 unmanned warhead (motivated by 15-minute window to strike bin Laden) plus 25,000-mile unrefueled range from continental US bases. Tom's analysis: 6,000-degree radiation heat transfer alone exceeds copper melting point, no boundary layer can save it.

  • Spruce Goose (Howard Hughes) §7.p2

    World's largest aircraft, built of spruce by Howard Hughes. Used to motivate the "wood as a strength-to-weight material" point on the Ashby strength-density plot. Currently displayed at an aviation museum in Oregon.

  • Louisville Slugger / ash baseball bats §7.p2

    Ash chosen for bats because it's the strongest wood on the Ashby plot; Kentucky ash availability is part of why Louisville is the bat-manufacturing center. Student question on maple goes unanswered.

  • Titanic — brittle fracture §8.p3

    Referenced briefly in connection with Tom's History Channel appearance and the paper-tearing demonstration of flaw-induced strength loss in brittle materials. Not developed here. ## Figures referenced

Layer 2 — cleanup edit
p1 00:00

Okay, Lisa's the brakes to the airline, and so it's a great symbiotic relationship. Honeywell has an incentive to develop brakes that last longer because Honeywell has to replace the brakes. If a mechanic comes to Honeywell, says we need to replace the brakes, Honeywell has to pay for the new brakes on the airline. But the airline has fixed costs. They know exactly how much they spend on brakes for every landing, okay. So Honeywell has fixed costs, their accountants are happy, they can calculate what the profit should be — not Honeywell, but American Airlines, whoever the airline is. And then Honeywell has an incentive to make a longer-lasting brake. And the mechanics don't care about the cost of replacing the brakes because it doesn't cost their employer anything for them to decide I need to replace the brakes, okay. Just takes time. Okay, but the cost of the brakes is borne by the manufacturer.

p2 01:00

The airlines also do that. They do, for example — airlines now lease the engines on the aircraft. They call it power by the hour. And the airline knows that for every hour that engine is operating — and you have to keep a log of every minute the engine is operating — they have to pay so much money to the owner of the engines. And the owner of the engines could be General Electric, it could be CRO Malloy [Rolls-Royce?] gas turbines, it could be a number of people. They're responsible for maintaining that engine, repairing that engine, and they lease it back to the airlines. Well, the same thing — most of the aircraft you're flying on are owned by some big investment company. American Airlines typically doesn't own that aircraft. They're leasing it. They pay a certain amount per month or per hour or whatever for the engines to one company, for the airframe to another company, for the brakes to another company. And it actually is not a bad system. It's sort of like Zipcar, right, you're renting the car.

p3 02:11

So anyway, that wasn't what today's lecture is going to be about. I appreciate the digression. And what's your name — right, Jordan. Charles. Yeah okay, so Jordan's going to give a talk on why everything I said about two dollars a pound savings is wrong for the BMW, right, electric — for electric vehicles, and how they change the rules because of different constraints, okay. And I'm just glad that I talked about collateral weight savings, because that's — his story is basically that collateral weight savings on batteries, okay. So I just stole your thunder, okay, but it's a great presentation. I thought that — I was going to tell you how to think about writing a paper on it, seriously. You know, I thought about exactly where you publish it. But it's an interesting story and you certainly have quantified it more than the Wall Street Journal would quantify it, okay. There's nothing wrong with having assumptions as long as you state what your assumptions are in a paper. Many people don't bother to state their assumptions, and then you run into problems, okay.

p4 03:18

Anybody have any questions before we begin? So the last time — and I couldn't really think of a summary of last time, a sort of recitation on competition among materials for water transport and then gas transport. And I actually showed this but it was the end of the hour and I didn't pass it around. [Tom holds up a piece of corrugated stainless steel tubing.] This is a piece of corrugated stainless steel tubing. There's about six billion feet of this in the United States, through most people's homes — many people's homes in the newer homes and as replacement in older homes. It's got polyethylene — this particular product has polyethylene yellow plastic. It's not really — not supposed to be for insulation. The yellow is supposed to identify it for gas piping. There's another company makes little connectors like this for forty or fifty years and they paint it yellow, okay.

p5 04:10

This actually has a tube around — a tube of plastic around it, and the plastic has low coefficient of friction. You can pull this through the walls, okay, and the corrugations don't get stuck on the corners as you drill a hole through a two-by-four through a steel I-beam or something. So it does have a function other than just provide color. It does also provide electrical insulation, so you know hopefully it won't short out to it and arc to it from your household wiring. But in fact if you have a small manufacturing flaw that you could never even see even under microscope, if you have a very high voltage discharge — in this particular one we actually probably put a little copper wire through here, but there's a very small hole, and the electricity went through that small hole and you can't see it. Here, I'll pass it around. Created a hole about ten times the diameter in the steel underneath. The electricity doesn't attack the coating of the plastic, but it doesn't take a very big hole for all those electrons to get through the plastic. But once it hits the steel it melts it, okay.

p6 05:29

This also occurs on aircraft wings. If you paint an aircraft and lightning hits the aircraft, the paint can actually focus the lightning energy, and it can take one ten percent of the energy of lightning stroke to perforate the wing on an aircraft. What's the problem of perforating the wing on an aircraft? Fuel. Your aircraft wing is actually your fuel container, okay. It's your structural wing for support, but it also contains fuel. So they do lots of tests at Boeing and other places. In fact I had a student do an internship at Boeing and she was working on lightning strikes to aircraft wings, although she was doing composites there. I know a lot about what happens when you hit an aluminum wing that's bare or a painted aluminum wing — if it's painted. And the two things are different. Just putting a coat of paint on it makes a big difference in how the lightning attacks it. But Chu was working on composites because Boeing wants to use more and more composites to make lighter and lighter weight vehicles, okay.

p7 06:39

So you know, we were talking about some of the competition among materials for different things, and I'm going to change course a little bit and get more into structural material design. And I already pointed out, Ashby wrote this number of books. One is Material Selection of [in] Mechanical Design, and I've showed you the little pamphlet. And in that he has a lot of these — or now known as Ashby plots, because he was the first person to kind of do these. And what did I do? Be able to — I hit something wrong and I'll never be able to find out how to get to — now I hate to do this. I think the only way to do this — to turn this off and turn it back on to give me back to the home page that allows me to expand and contract things.

p8 07:40

In any case, Ashby has a whole series of these plots that basically plot two material properties against one another. In this case he's plotting — someday I'll read the controls on this again, figure out how it works. I did it actually twice, but nothing's very simple anymore. I like the days when I just had little mechanical switches I could figure out. Anyway, he's plotting Young's modulus versus density. And it turns out E over rho — Young's modulus divided by the density — shows up in a lot of mechanical property formulas. And in fact if you look at the page before this in his book under material selection: Young's modulus E versus density rho, E over rho equal to some constant will be minimum weight design for stiff ties — a stiff tie being something like — if I — he might know what the hammer throw is in sports, where you have this steel ball and it's connected to a rope or something, and you lace it — a hammer throw, I guess they call it, the hammer throw. And the guy picks it up and he swings it around and he sees — he lets it go and centrifugal force sees he'll throw — how far he can throw the steel ball, which is a 16-pound ball or something.

p9 09:18

In any case, that tie has a certain tension in it. And the strength of that, for stiff ties — the string that's holding the ball to the handle that he's got holding on with his hand — minimum deflection in centrifugal loading as an example. E to the one-half, which you can't quite see, E to the one-half over rho is minimum weight for stiff beams. So if I was looking at — I have two rulers here, I had in my office, actually in my briefcase. [Tom produces two rulers.] This is a very thin plastic beam. This is also a thin beam, actually same size ruler, but this one's got a magnetic stripe on it. It's a lot heavier and you can see this one sinks under its own weight, okay, like a diving board. This one's stiffer even though it's thinner. It's a different plastic. This one is heavier basically.

p10 10:17

And so you can have stiffness — you can get stiffness from two different properties of a material. One is Young's modulus, which is a property of the material. It's related to that Lennard-Jones potential and the bonding between the atoms and how strong that bonding is. The Young's modulus is the second derivative of that energy potential minimum, okay. So the steeper that is — and the highest Young's modulus for any material is carbon. Tungsten is not far behind that — steepness of the Lennard-Jones potential. This is energy of bonding versus distance, radius between the two atoms, and the steeper it is, the sharper this curvature, the higher the melting point. The melting point is basically related to the depth of that energy potential well, and the stiffness, the Young's modulus, is proportional to the curvature, sharpness of the curvature. Tungsten and carbon, being diamond, are two of the stiffest materials we have. There are limits to that.

p11 11:31

But in fact you can either get stiffness from a material property, and there's one other way to get stiffness. What's that? All right, design, thickness, design cross-section, you name it, geometry, okay. It turns out for equal areas, what would be stiffer, a solid rod or a tube of equal area? Well, this one's stiffer, okay. A tubular section is stiffer than equal weight, equal material of a solid rod. So you can get stiffness from two things, okay. And so what this plot shows you — Ashby plot will give you — is E over rho for tension, tensile stiffness, so you don't get the — if you swing the rubber band or the ball around on a steel rope, you will get less stretch than if it's on a rubber rope, okay, because Young's modulus is larger. E to the one-half is minimum design for beams, like I talked about. There. E to the one-third over rho is for plates, okay. You talked about a piece of paper — how stiff is that sheet compared to some other sheet of some other material? These are not same thickness. This one actually is flimsier. The rubber is flimsier than the paper. Actually has a higher stiffness.

p12 13:07

So if you go to this Ashby will have all of these on one plot. The advantage of an Ashby plot, as you can see all kinds of properties on one plot for two properties. Part of the — gets another Young's modulus, and you see here guidelines for minimum weight design: E over rho — either E over rho to the first power, E over rho to the one-half, E over rho to the one-third — and they have different slopes, and you can compare those slopes. And the slopes he's put in here are E over rho to the first power, and that's ten to the fourth, okay. And that actually has units of meters per second. Does anyone know what E over rho being meters per second — what type of test in the mechanical behavior laboratory that's used for? You've heard of stress-strain curves, right? And you've got a stress-strain curve and they tell you that Young's modulus is the slope of the elastic region, and then you have the plastic region. And if you took a class — how many people took a class in high school or as a sophomore in mechanical behavior or whatever, and they told you to calculate Young's modulus from the stress-strain curve, right? It's not the way you do it in the real world.

p13 14:39

You actually measure — you put a vibrational frequency in a rod and you measure the speed of sound in meters per second, and from that you get a much more accurate Young's modulus. This Young's modulus, when you just try to do a tensile test — it's easy to show the students a principle of measuring Young's modulus by the slope. You try to do that on a piece of aluminum, and you have 15 students do it, you'll get numbers between seven and 15 million pounds per square inch, and the real number is 10 million, okay. Because of slippage in the grips and things like that, okay. So it's not that easy to measure Young's modulus unless you do it by frequency, okay.

p14 15:24

In fact they — in steel mills they have little machines you take a little strip of steel if you cut out and you slip it into this machine and it measures the speed of sound in that steel in a particular direction. So you have a sheet, a great big sheet of steel, and you cut out a specimen longitudinally, you've got a specimen transverse, and you cut out a specimen at 45 degrees, and you measure the speed of sound — each three of those numbers. And that modulus will be different in each three directions because of the texture of the crystals in the steel, and that steel will draw differently when you try to make a suit can [Coke can?] or something like that out of it, okay. You can predict the drawability of an automobile body based on the speed of sound, which is related to the Young's modulus and the stiffness of that. It's called a Modul-R machine, and we — you taking my deformation, Modul-R, I'll go through it, okay.

p15 16:29

But in any case, so here's a plot. And the stiffest material is diamond, 60 million. And down here are the metals, and steel is of the stiffest metals, although tungsten alloys are higher than steels. But the highest is diamond at about 60 million. Here's a composite, tungsten carbide plus cobalt. It's really the tungsten carbide. We like to use tungsten carbide as a structural material. It's stiff for lots of things. But the problem is — anybody know the problem with tungsten carbide and why we don't use it more often? Cost. Ten thousand dollars a pound, okay. To form tungsten carbide you have to have furnaces that go to 25 — well above 2,000 C, 2,600 degrees C in some cases. So this happens to be a tool bit that we cut apart. It would have looked like this. [Tom holds up a tool bit.] And this is a tool — you would have several hundreds of these on a machine.

p16 17:36

You ever been driving on the highway late at night on an interstate highway and they're reclaiming the asphalt? They have a great big machine. This is the tool that's on that wheel that's beating up the asphalt and throwing it back into a trailer to be recycled. And you can wear out these tools in three or four hours, in which case you have to stop that machine. The mechanic has to go in — you're doing all this in the middle of the night, you're paying people double time to work in the middle of the night on the highway, cause you don't want to disrupt the traffic. You'd like to have something that lasts for a good eight hour shift, okay. Lot of wear on that.

p17 18:17

And it turns out if you look at the details — this one's been polished better than the other one — who pass this around a second — but if you look at the tip of this particular one — so there's some — it was a company, see if we — okay, there was a company out — it was out Uthoff [Utah?] anyway. There's a lot of people out in Utah who would like to work on diamond, because there was a guy, General Electric, Tracy Hall, in the 1950s, who developed the ways to make man-made diamond when he was at General Electric Research. But this actually is the tungsten carbide tip from here all the way up here is tungsten carbide. Looks sort of copper colored, but I'll tell you the reason for that. This is actually sintered diamond. Ordinarily the tip of this thing would just be tungsten carbide, and it would wear out in three or four hours. If you may, if you could make sintered diamond tips on these things, they'll last more than eight hours, okay, because you've got more wear because of the stronger material. So I'll pass around, and I won't get into — they did step brazing and other things. I was asked to help evaluate it because one company wanted to know if they wanted to buy this company, and we — I think they finally decided it was a great product, technologically superior, but it costs too much, so they didn't buy the company, at least that's what I heard the last. Anyway.

p18 19:45

But so diamond is right at the top, and that's what they were able to put in there as a wear-resistant hard structural material, because tungsten carbide, which was almost as good, would have half — or one-fifth — the life of the diamond, okay. So small differences can make big differences when you get to things. This is for stiff materials. Now, well, I had something else here for stiff materials. Oh yeah, that's Ron's yours [rongeur]. So once upon a time, back in the 1980s — so this is 30 years ago — I used to do a lot of consulting for a firm down south of Boston, been around since the 1830s. It's now a division of Johnson & Johnson, makes medical instruments. Does anyone know what a Ron's your [rongeur] is? I never knew what it was. It's a French word. A Ron's your [rongeur] is basically a pair of pliers that an orthopedic surgeon would use to chew up bone, to break up bone. So this is — a Ron's your is just a pair of pliers, and it has a little cup in, so you can go in there and just bite away the bone. So they're going to do — they're going to fuse someone's spine or something, they go in there and he chips away at the bone, removes the bone that he wants to remove.

p19 21:15

Well, when people were doing — and it's not just bone — when they want to do arthroscopic knee surgery, which was somewhat new — I have torn cartilages in both my knees now, but I had one of them since the 1960s when I got injured in a football game. And that's a — my left knee is the torn cartilage. Well, they can go in at that time, in the 1960s, to remove that torn cartilage — they would have to lay open your whole knee and you would be in a cast and on crutches for up to six months. Nowadays you can go in and you can walk out of the hospital that day. You might have crutches for a week or something, but basically they go in with microsurgery. Just put a little — rather opening up your whole knee, they can go in with microtools, they put a little slit in there, and with a little fiber optic so the surgeon can see what all blood and guts looks like in there and try to see what he wants to cut up. He can go in there and he can use a little Ron's your to eat away and pull out the cartilage and remove the cartilage that way. Minimally invasive surgery. This is one of the first big applications.

p20 22:29

The Ron's your for that application looked like this. [Tom holds up a rongeur.] And it's basically a pair of pliers by this guy. It's a sliding mechanism, and the cutting end is down here. So you have a little post sticking up and this — slide, the slides above, and you go in there and just eat away the bone or the cartilage, okay. That's a Ron's your. Well, they try to get smaller and smaller in their tools, and you can see I got a stiffness problem here, right? And they were making them out of steel. Steel's 30 million. And they came to me and said, well what can we make it out of that would be stiffer? Well, you can go to geometry, you can go to a tubular section, except they were trying to get them smaller, and tubular sections are larger.

p21 23:18

So I suggested — they never liked my suggestion. I loved my suggestion that they consider — what else? Their — first of all, there are not a lot of choices. I didn't have an Ashby plot back in nineteen eighty-two whenever they asked me this question or whatever. But I knew the properties of materials and I knew my choices were diamond, and I didn't know where I could get a nice long slender diamond like that, okay, but it would be a great tool, okay. Might be pricey, but this is medical instrument, so you can charge a lot for it. Silicon carbide — I didn't know how I could get any reasonable cost silicon carbide. But if you look in this area at the top there's alumina. What's another name for aluminum oxide? Sapphire. Here's a piece of sapphire, I'll pass it around. [Tom passes a sapphire boule fragment.] We can grow sapphire. This type of piece of sapphire was not single crystal. It's grown in a boule that was about the size of a great big beach ball. It took about a month to grow it in the furnace. You put the aluminum oxide powder, furnace, you take it up to the melting point which is above 2,000 degrees centigrade — about somewhere between 2000, 2100 centigrade for pure alumina — and you would cool it down very slowly over about three weeks to cool it back down to a low temperature like a thousand degrees centigrade before you'd open up the chamber and everything.

p22 24:48

It's a ceramic. It's aluminum oxide. Sapphire is another name for it. We grow sapphire boules like this now. A sapphire boule like that cost about a hundred thousand dollars. That was just a chunk. You can saw it into little substrates, and the reason they were making these — because every LED has an aluminum oxide sapphire substrate. Just like a silicon chip on a computer, you have an aluminum oxide sapphire substrate. Doesn't have to be single crystal because it just has to match the coefficient of thermal expansion closely of the gallium arsenide that's making the LED, okay. So it's a big business now to make all these LEDs, and that's what this company was making all this stuff for. They were up here in New Hampshire. They were selling this technology — who were they selling it to? China gave them like a I-lo — three hundred million dollar order for a bunch of these furnaces. And now guess who owns the LED manufacturing market, because they own the business of making the sapphire substrates? China.

p23 26:06

And they would slice them up on diamond saws, because what's the only thing that's going to cut that? On the hardness scale, the old Mohs scale, which is a kind of — what material would scratch another material — diamond was number 10 on the Mohs scale. What's number 9? These are empirical numbers, these are just — is sapphire, okay. Sapphire would scratch anything but diamond. Now silicon carbide will actually scratch sapphire, but silicon carbide is not a natural mineral. But on the Mohs scale — Mohs, M-O-H-S — of natural minerals, and at the bottom is talc, okay. Talc is nice and soft, a thing is number two or something like that, and gypsum might be number four or something. But the mineralogists for a hundred and fifty years have had this hardness scale. Diamond was at the top. Sapphire was number two — number nine, sorry — and I can't remember what number three was. We've come up with other things like silicon nitride and silicon carbide and boron nitride and stuff. Some of the silicon aluminum oxide we call Sialon — silicon aluminum oxygen nitrogen, okay. They're fairly strong.

p24 27:14

So in any case I wanted to make it out of single-crystal sapphire. Now you have to understand part of the business here of medical instruments. [Tom holds up a pair of surgical scissors.] This is just a pair of scissors that a surgeon might use to go in there and snip some part of the body — your soul or cut suture or something. This back in the 80s was a $300 pair of scissors, okay. They're probably six or seven hundred now. It's brazed on the surface with a cobalt alloy for excellent wear resistance and strength and maintains sharpness. This is the type of thing once you buy this pair of scissors you can send it back whenever it's dull and they will sharpen it for free and ship it back to you and clean it up. Gold-plated handles, so that you know this is one of the premium grades of stainless steel scissors, right. But I used to help make stainless steel instruments like this. Every one of them's got a hardness indentation on it because they do a hundred percent check on the heat treatment of the hardness, okay. So it's better than your Fiskars scissors. I mean to knock Fiskars, okay, we could take someone else, but this is a better scissor.

p25 28:31

But physicians will pay a fortune for these things. And it turns out some physicians like — I can't remember what the instrument was — Dr. DeBakey, the famous heart surgeon, he liked a particular color, and so they would color the instruments the color he liked because it was just his favorite color of instrument. And there are some — if you go to a dentist's office, you'll sometimes see some of the dental tools will be color-coded. Just — you can go to Sears and buy tools that are color-coded for different sized ratchets and, you know, wrenches and stuff nowadays. But color coding would have been great with sapphire. You could have added a little chromium to the melt, and if you added chromium to the melt you would have made ruby. So you could sell ruby instruments to the surgeon, and I mean you could charge a fortune for these things. I mean, well, I was using ruby instruments when I touch your leg open. Anyway.

p26 29:30

So the Ron's your, I wanted to make a Ron's your at a sapphire, and I was confident that you could buy — you can buy — either his company actually is the predecessor company — is making that stuff. But it was a company that started here in Cambridge and they could grow single crystal sapphire tubes or rods or sheets. They take this 2000 degree melt and they just slowly pull the stuff out, okay, of the melt, and grow things of different size. I actually have some silicon like that in my office that Professor [Sachs] — who did one of — the inventors of the name 3D printing and stuff — he invented a company that since went bankrupt. But they used some carbon wires, carbon fiber wires, and they would lift a sheet of silica — a more polycrystalline silicon for solar cells. I got something there, they're about three or four inches wide and you just grow the silicon right of the melt as a thin sheet. You didn't have to cut it with diamond or anything else. It's going to take over the solar cell market 25 years ago.

p27 30:47

Problem is, if you look at it cross-eyed it will fracture, okay. Silicon is extremely brittle material. To show you a brittle piece of silicon — [Tom holds up a silicon crystal.] this is a chunk of silicon, single crystal, grown by a Czochralski process. And it's completely brittle. Fracture just like that piece of sapphire. The easiest way to break it is just whack it with the hammer, okay, and it breaks. Takes a big hammer to whack the sapphire because it's pretty hard. Silicon is pretty hard. But as I pass this around, this is the — those surfaces darker, it's got some — so it's grown in a vacuum system. That steel — Parker is oxidized a little bit on this surface. You actually see some fracture patterns, which if you knew anything about fracture surfaces, or if you do already know something, you might think that's a fatigue crack, sure, because it has little what we call beach marks. In a brittle material like glass we call those hackle marks, and they're not from fatigue cyclical loading. It's just the way some material — some brittle materials, very brittle materials — fracture.

p28 31:54

Anyway, I wanted to use, for Young's modulus reasons, sapphire. And they never would believe me that you could buy this stuff. You can buy sapphire rod for fifteen dollars. You can buy sapphire tube probably for thirty dollars for a foot long tube, and it's twice as stiff as steel, okay. And I knew I could put a solid rod and use the diamond to make a cutting tip on one end, and I could do something to put a tip on the other end, and I could basically make a Ron's your of a tube slide — or a rod sliding through a tube. No, they didn't like it, okay. Hey, what do you hire a consultant for if you don't listen, okay? So there's other things that you can look at in the Ashby type plots. This is — anybody have a question about — yep, no.

p29 32:52

Then — they didn't like my idea. They thought sapphire would be too expensive. I thought selling sapphire and ruby instruments would have great marketing appeal, and for simple instruments, simple cutting tools, you wouldn't find a better material. It's right behind diamond on hardness, so the wear resistance of the cutting edge is fantastic, right. And the toughness is better than a lot of these ceramics tools that they use for cutting edges and stuff, okay. Anyway, they didn't like the idea. They never would try it, and I didn't think — I mean, I know that if you're actually machining with diamond tools, the stuff on that hard to machines, okay, sapphire with diamond — you can make some very intricate shapes. Got to be fairly simple. You can't do 3D printing, you got to do subtractive manufacturing. But no, you know, they didn't like the idea, so it never went anyway. And they never would tell me a reason why they didn't like it, okay. But what they said is, we want something that's stiffer, and I said there's only — if you've only got a handful of choices, look at the Ashby plot. We didn't have Ashby plots back then, but I said there's only a few materials.

p30 34:07

It's just like for the National Aerospace Plane in the mid-80s, they wanted to develop the surface of the airplane coming back into the atmosphere. This was a — National Aerospace Plane was supposed to be a supersonic transport. They would actually get up into space and then come back down, and it could be like two and a half hours between any two cities on the globe, okay, because you'd be going at Mach 17 up there in space, okay. So all you had to do is make the boost into space, do your travel with no air around, come back through the air, land, and it would be two and a half hours anywhere in the globe. And this was actually partly — they never said it — but it was also part of Reagan's Star Wars initiative, because if you could do that and put civilians up in space, you could put hardware up in space and weapons in space, right.

p31 35:04

But turns out if you look at that Mach 17 coming back into the atmosphere, the frictional heating will give you surface temperatures of 3,000 degrees kelvin. So they had a great idea, well we'll make it out of copper, and we'll — liquid hydrogen will be our fuel and we'll just cool the inside with liquid hydrogen. So this is a great idea, okay. I don't know where they get these people in the Air Force to come up with these ideas, but, or some of the aerospace companies. So this was going to be copper skin, this was going to be 3,000 degrees centigrade air, and this was going to be liquid hydrogen, okay. Anybody see a problem? The thickness of the copper was going to be about eighth of an inch, three millimeters. Anybody see a problem? You don't have to worry about lightning strikes because you have a better chance of just blowing yourself up. Anyway, here's the space shuttle Challenger all set to go, right? But this was — hey, you know, how many billions of dollars the US government spent researching how to make this work?

p32 36:11

Well you might think it's sort of funny — I thought it was sort of funny until in 2002 — 2004, so I was on another National Research Council committee on aircraft propulsion for the US Air Force. This is a committee, and we were supposed to help advise the Air Force on what materials to use and designs to use for their three hundred million dollars a year the US Air Force had over the next 20 years to develop better motors. And they told us — they came in and gave us a non-classified presentation — the Air Force wanted a Mach 17 warhead to fly through the air, not through space but through the air, at Mach 17. And the reason was — this is before they killed Osama bin Laden, somewhere amid, you know, 2004-2005 — they actually had located Osama bin Laden and they had 15 minutes to get the ordinance on site, okay. But he was gone from that region, you know, within 15 minutes. But if they had the right weapon on one of the aircraft carriers in the Persian Gulf, they could have — if it went Mach 17, they could have had it on site and got — blown him up if they had a Mach 17 weapon.

p33 37:39

Well, what's the fastest aircraft we have right now? It's like Mach two — Mach two and a half, you know. It's an F-15, F-16 or something like that. They, you know, burn all this fuel and their skin is getting hot, okay. We had Mach six or seven, the X — our 71 Blackbird or whatever, you know, this titanium-skinned aircraft that flew at a hundred thousand feet to take pictures of Cuba and stuff, or the U-2 spy plane that Gary Powers in '62 — you guys wouldn't remember that. Anyway, we built special aircraft, but we've never built anything close to Mach 17. So I knew, and I said, well this isn't going to be man-rated. No, it was going to be unmanned — it's sort of like a Mach 17 cruise missile. Great, okay. But they also had another goal. Their other goal is, they wanted to fly — they wanted to be able to fly 25,000 miles without refueling. I said, why do you need that? They said, we've determined we will not be able to have bases anywhere except in the continental United States.

p34 38:47

Well, I'm not sure I realized — I said, actually, I said, why do you need to fly 25,000 miles, why can't you just fly 13,000 miles and get halfway, right? And they said no, we want to be able to take off, do whatever we want to do, and come back 25,000 miles, get anywhere in the earth and take off and land from same, you know, from the continental United States. And the fuel efficiency and the lightweight requirements and the Mach 17 — the temperature requirements — they're just as ridiculous as the National Aerospace Plane, okay. And I actually brought in some plots and stuff and kind of showed them that. And then they gave us plots that showed 6,000 degree temperatures, okay, from the frictional heating near the surface. And I use those to calculate just the radiation heat transfer to the surface. So we're not even talking boundary layers. You couldn't even, you know, leak out a little bit of nitrogen or something on the surface as a bounty — as an insulating boundary layer — because just by straight radiation, which goes through any gas boundary layer, you would be above the melting point of copper or anything else. It made no sense.

p35 40:00

And then they didn't worry about — they hadn't even started to — the fact that if the top surface of the copper was at 900 degrees centigrade — it melted 1107 centigrade — and the bottom was at liquid nitrogen, there would actually be some thermal expansion differences and distortion and things like that. Somehow they were going to just design those away, okay. Mmm. Okay, and we pay people to come up with these ideas, okay. Anyway, there are other parameters. This is Ashby strength, not modulus, but fracture strength or yield strength he has here, versus density. Because if you have a minimum weight design for strong ties — remember before it was stiffness of strong ties or beams or plates — now it's minimum weight design, minimum, maximum strength from minimum weight. And here's the plot, and it doesn't change all that much, but it is slightly different if you were to compare these. Enough, you'll get these on stellar.

p36 41:11

Oops. And you still got diamond at the top. You've just shifted these things a little bit. And at the bottom, or over here on the side, interestingly, in terms of lightweight, some of the lightest weight to strength ratio materials are something called wood, okay. Anyone heard of the Spruce Goose? Okay. What was the Spruce Goose? World's largest airplane. Howard Hughes decided to build the world's largest airplane. He built one of them. It was on display for years in Los Angeles somewhere, but it's still there, okay. It's in Oregon, okay. Is it at that space — aviation museum in Oregon? I've been there but it wasn't there when I was there, but must have been moved there in the last 10 years for something. Anyway, so I've never seen the Spruce Goose, but it's called the Spruce Goose 'cause he built it out of spruce. And if you look on here, how they have screws but — ash, the strongest wood, is ash. Where does ash grow? A lot of ash grows in Kentucky. And what do we build in Louisville, Kentucky? Baseball bats. Louisville Sluggers. And what are they made out of? Ash. Why? 'Cause it's the strongest wood. Yeah, yep.

p37 42:44

What is — what's the advantage of maple? The answer is, I don't know, okay. And it's not tangential, it's a key question. That would be a good topic — of baseball bats. Now there's also metal baseball bats, which is a whole 'nother topic. I do know something about that, but I won't talk about that right now. But ash is actually — if you look, well here it is, it's the strongest. Then we got oak and pine. Then he didn't put maple on here, but I guarantee you maple's up here near the top too. So I suspect it might be an availability thing. In New England, if you were making bats, you might make them out of maple. In Kentucky there's all kinds of ash trees in Kentucky, which is one of the reasons Louisville Slugger is in Louisville, okay. I have toured Louisville Slugger plant. At the end they give you a little one footlong baseball bat, okay. It's very interesting and just in terms of how they rapidly machine bats and how they customize bats for certain players and stuff.

p38 43:41

Then there's fracture toughness against density. Fracture toughness is this thing that Griffith came up with in the 1920s when he was researching the fracture of glass. And I talked about how brittle glass is, and this is where Griffith found out that things can be tough as well as strong. The original strength person to measure strength was a guy named Galileo. And here's a picture of Galileo's test apparatus, okay. There it is. If you had a beam and you put a weight on it — this was out of one of his notebooks, okay. And so he started studying the strength of beams. And this is out of a book called The History of the Strength of Materials by Timoshenko. Anybody ever heard of Timoshenko? Well — you know about Timoshenko? Yeah. Well, you've heard the name because he was a professor at Stanford University. I think — if you look on the inside, I think he lived from eighteen seventy-eight to nineteen seventy-two, but he basically — I mean, he was almost 100, he was 94 years old when he passed away, that's down here in the bottom. But Timoshenko was kind of Mr. Mechanics of Materials in the whole country. He wrote books all over the place. If you studied — if your grandfather studied mechanical engineering or materials in the first half of the 20th century, he would have been studying out of the Timoshenko books. So Stephen Timoshenko wrote this book on history of strength of materials, and well, I'll go through some of that tomorrow or another day.

p39 45:41

But in any case, Galileo was interested in strength of materials, and I can't remember where I was — I was talking about fracture toughness. So we learned in the 1870s — actually even earlier, I'll give some more history tomorrow or — wait, no, Monday is the next day. Election Saturday — you can have off Sunday to take them both off. Anyway, I'll talk to you some more about that stuff. But fracture toughness is the energy of fracture. Galileo was looking at the strength of fracture, and Timoshenko knew about the strength of fracture. Timoshenko lived through the era from 1925 to the nineteen fifty — in 1975 — where we really learned about the toughness of fracture, which actually is a much more interesting story than just the strength of fracture to me, because we still continue to learn about the toughness — the need for toughness — in materials.

p40 46:39

But to give you an example — well yeah, I got a minute — if you take a brittle material, you'll see me doing this on the History Channel, okay, I talked about the Titanic — but you can pull on the edge of this material, paper, with pounds of force. [Tom demonstrates with a piece of paper.] If I put a flaw in the material, which is what Griffith was looking at, flaws in glass, it takes — else's — I can lose eighty to ninety percent of my strength because of a flaw in a brittle material. Whereas if I have a ductile material, like a rubber — [Tom demonstrates with a rubber band.] that is toughness. I can pull on that piece of rubber and all I do — I don't have a sharp notch, I blunt the notch, and so I get lots of deformation without fracture. And there's a tremendous difference in ductility of fracture versus brittle fracture, and we're going to talk about that stuff on Monday. Have a good weekend.