SMS_F2014_10

Structural Materials Selection Fall 2014 Session · 8 sections 20 cases · Watch on YouTube ↗ all files
Layer 3 — readable edition

§1. Ashby's plot revisited [00:43]

§1.p1

Good old Ashby. Michael Ashby is a real leader in materials selection and design, and he's a great material scientist. I'm not going to try to knock him for that — I'm going for something else.

§1.p2

I showed you on the first or second day of class this Ashby plot — materials used through the ages. It turns out I was wrong about the date. I went back to his books. I thought it was from one of his 1980 books; it was actually from Material Selection and Mechanical Design, and the first time I could find that plot was 1992. He has books going back to 1980, but they don't have that plot. So here's the plot, and that's where my slide came from.

§1.p3

[Tom struggles with the projector for several minutes.]

§1.p4

So Ashby came up with this plot in 1992. The first edition of Material Selection of Mechanical Design was 1992; the fourth edition is 2011 or 2012. When I presented this I said he was extrapolating around 1980 or 1990 and saying the amount of metals is decreasing and is going to continue to decrease, and the amount of other structural materials is going to increase over time. I happened to buy the fourth edition a week ago, and flipping through it, what he says in the fourth edition is he sort of corrects that.

§1.p5

In the caption he says, "The evolution of engineering materials with time, relative importance" — which he's plotting on the vertical axis — "is based on information contained in the references from 1960 onward, data for teaching hours allocated to each material family at the United Kingdom and US universities." So this is basically — and it's true — when I was a student in 1970, the curriculum was metallurgy. It was metallurgy and material science, and it didn't become material science and engineering in this department until 1973 or 1974. So it was primarily metallurgy, and that's correct. Except that's not what he said in 1992.

§1.p6

In 1992 he said: "The evolution of engineering materials, this evolution increasing pace, are illustrated in Figure 1-1, the materials of pre-history." He's talking about the fact that everybody taught metallurgy back in the 1960s. "There had of course been developments in other classes of material, Portland cement, refractories. The rate of development of new metallic alloys is now slow, demand for steel and cast iron has actually fallen." That's wrong. It has never fallen. Maybe in one year, but if you draw a trend line over a decade it's been increasing, and it continues to increase.

§1.p7

"The polymer and composite industries on the other hand are growing rapidly." Yeah, because they were so small. It's not hard to grow rapidly when you're small; it's very difficult to grow rapidly when you're big. It's what your baseline is. "And projections of growth, production of new high performance ceramics suggest rapid expansion here also." Well, this is right after the ceramics fever — they're going to make jet engines out of ceramics and all this other stuff. You're supposed to be the material property guy, you're supposed to know about strength and toughness — you've got the plots in your book. In fact, he was on the same bandwagon as everyone else in 1990, saying metallurgy is dead. The last department head in this department was a polymer guy, and he actually said metallurgy was dead, which I didn't particularly appreciate. Other materials are important and I'm going to talk about some of those.


§2. Selection criteria and the Spruce Goose [09:06]

§2.p1

A long time ago I gave a talk on material selection at a conference. If you look at different materials — strength to density ratio — aluminum is better than steel for typical strengths and densities. Composites are right in there, equal to steel. Very fancy composites can be significantly above, but they're materials that cost ten thousand dollars a pound. Plastics are relatively low even though they're the lightest weight of all these, as is wood.

§2.p2

But if I'm going to build something like an aircraft, you look at the strength to density — the specific weight of the material — we make aircraft out of all these things. One of the biggest aircraft ever built, Howard Hughes's Spruce Goose, was made out of wood. In the 1940s when you wanted to make the biggest aircraft in the world, you didn't make it out of aluminum, you made it out of spruce. They only built one of them, but it worked.

§2.p3

So there's competition for materials. From that same talk, on selection of structural materials: the number one thing I've been telling you is cost. Strength and fracture resistance — there's your strength and toughness — and that's what I've been saying is after cost what we're worried about. We really didn't worry about fracture resistance until the last 25 to 50 years, and some industries haven't even caught up yet. Availability. One of the strengths of steel is there's a lot of iron out there, and it's not hard to come by. That's the strength of aluminum too — aluminum takes a lot of energy, but they're both available, and that's why they're the two most common metals.

§2.p4

Wood — really good quality wood, we're running into the same kind of problem they had back in the 1500s in England. The really good big trees, the high quality trees, have sort of been deforested, and we don't have them like we used to. So people are using composites and making things look like fake wood. Fabricability — if you can't machine it, you can't cut it, you can't weld it very easily, that's one of the problems with ceramics. I showed you the ad for the watch, the little bezel. Ceramic is very difficult to machine. That's why you've got to buy a forty-thousand-dollar watch to have them make it out of ceramic.

§2.p5

Recyclability. The most used metal is steel — a billion tons a year — and steel is about 80 to 90 percent recycled. Everybody thinks of recycling of aluminum, people picking up beer cans and soda cans, but aluminum is only 50, 60 percent recycled. It's not recycled as much as steel. There are a number of reasons. The aluminum alloys are so different in their classes that if you try to mix them all together you end up with a mishmash that you can't use for much of anything. People are working on new ways to separate the alloy content out of the aluminum alloys.

§2.p6

But there are two materials that are higher than steel in usage. They're not metals. Stone, and cement — and wood is there too. You go to the hobby shop — Ken Stone recycles wood. He made some things for me, all from recycled wood. He used to use the old MIT desks. The legs were solid cast iron, and the tops were bird's eye maple, beautiful maple, two inches thick solid. We got rid of them rather than refinish them. Beautiful wood. So Ken recycles that. But mostly wood is consumed. It's a renewable resource.

§2.p7

The one we make one and a half billion tons a year of that we don't recycle is cement. You can't keep putting one and a half billion tons a year of big old rocks — once you break it up, you have an earthquake, you destroy the building and send it to a landfill — you can't keep landfilling one and a half billion tons a year. You want a problem to work on, figure out how to recycle cement. At some point in the next 10 or 15 years people are going to realize you can't keep landfilling all the cement. We've had tremendous growth in the use of cement — it used to be half a billion tons, now it's one and a half billion tons and continuing to grow, particularly in the third world.

§2.p8

Repairability. This is one of the Achilles heels of all your fancy composites. How do you repair them? You went to all this trouble and processing and extra expense to make this fancy material, and then you have a hard time. There are other criteria too — I actually have a list of 10 or 12 different things.

§2.p9

However, even Rudyard Kipling knew that — "Gold is for the mistress, silver for the maid, copper for the craftsman cutting at his trade. Good, said the baron sitting in his hall, but iron, cold iron, is master of them all." So what I've been telling you is not new. It's been known for a long time.


§3. Productivity and the MIT Commission [17:11]

§3.p1

I want to switch into a topic that's not necessarily material selection, but I lecture as I feel like — productivity. I'll tell you a little bit about Made in America: Regaining the Productive Edge. Michael Dertouzos was a professor running the computer science lab at MIT. Richard Lester has been an administrator around here for 20 years. And Bob Solow is an economics Nobel Prize winner. This is the MIT Commission on Industrial Productivity. As a younger faculty member I got involved in this. It started about 1985 at a meeting in the School of Engineering conference room. It was published in 1989.

§3.p2

In the mid-80s the Japanese were knocking our socks off in manufacturing, and everybody thought the problem was regaining the productive edge. In 1984 and 85 I went to Japan for a year on sabbatical working for the U.S. Office of Naval Research. I was visiting research labs and manufacturing facilities all over Japan for a whole year, and I said, this is not better than what we have in the United States. It might have been making better quality, but at the time there was a significant competitiveness issue. It was 250 yen to the dollar after World War 2 — it had been like 350 yen to the dollar. Today the exchange rate is about 100 yen or 90 yen to the dollar.

§3.p3

Back in 1985, 250 yen to the dollar, a 10,000 yen note was a $40 bill. My housing was pretty expensive — the U.S. government paid $36,000 for me to rent a house in Tokyo for my family. Food was expensive, particularly if you wanted to eat like an American. Back then a box of Cheerios could cost you $15. That'd be like $35 or $40 today. Because they had to import it from the United States. If you wanted to eat like a Japanese you could eat pretty cheap, and if you wanted to eat like Chinese you could eat really cheap in Japan.

§3.p4

I had a certain advantage — I was a U.S. government employee for that year, and I could buy things at the military exchange. C-5As would come over from Seattle on the weekend. You'd go out to Yokota Air Force Base and there'd be 10 of them, and this is the National Guard basically taking a quarter-million-dollar flight from Seattle to Tokyo to get their training time in. What were they offloading? Big pallets of Coca-Cola. So I could buy a case of Coke in Tokyo cheaper than I could in Boston, and they'd been flown across by the military.

§3.p5

I remember the first week I was there, I showed up at church and they said — I was the only person who was a government employee at the time — can you go down to the embassy and buy us hot dogs, because they were going to have a social and they wanted 300 hot dogs. A hot dog in Japan would cost you like two bucks apiece, just for the hot dog without the bun. I could get them at the commissary for 50 cents a pound. So I had to go down to the commissary and buy all these frozen hot dogs. One thing I learned: if you're ever going to live abroad, live under the U.S. State Department rules. Those people know how to live abroad.

§3.p6

So we thought that the Japanese were these master manufacturers, and it never quite made sense to me in the mid-80s from what I'd seen over there. They had lots of inefficiencies built into their system. Finally in the early 90s I read something in The Economist that pointed out the United States was the most productive nation in the world in terms of person-hours per whatever metric — tons of steel, pounds of aluminum, computer chips. We actually had the competitive advantage in almost everything, including agriculture at that time. Now Thailand is the most productive rice grower because they've got the right climate and soil. But we are the most productive nation in the world, and have been for the last century. We passed the British.

§3.p7

The important thing is to read the very beginning of this book: "To live well, a nation must produce well." It was written by a committee led by these three people, and I served on one of the committees that looked at the steel industry. There's a section in there on the steel industry. Paul Krugman — does anybody know who Paul Krugman is? He's an economist. He did all his really good work here at MIT. He wrote some very good books that were understandable and used correct principles. He then went to Stanford, which is when he won the Nobel Prize, and now I think he's back at Columbia. He's an MIT product.

§3.p8

So here's Made in America: "To live well, a nation must produce well." Paul Krugman used to say, "productivity isn't everything but in the long run it's nearly everything." That's where I talked about nails. I have a plot here on productivity of steel — hours per ton on a log scale versus time on a linear scale.


§4. From Bessemer to the basic oxygen furnace [24:26]

§4.p1

Steel was very labor-intensive back in the old days, and then the Bessemer process came along — we learned to melt steel. Before, we basically either started with cast iron, or if we made wrought iron we basically diffusion-reduced it from the ore and ended up with a sponge which we then had to forge by hand into wrought iron — which was steel basically, a lower-carbon cast iron. Then Carnegie came along with economies of scale and built huge steel plants, based initially on the Bessemer process but later others — the open hearth. Then in the 60s came the basic oxygen furnace, continuous casting, mini mills which were smaller, a way to use a lot of scrap.

§4.p2

We went from labor-intensive in 1975, when I worked for Bethlehem Steel — labor was 45 percent, materials 45, and they actually made a 10 percent profit. In the 1980s it was 55 percent and they made a 10 percent loss. That's another story. Raw materials and energy intensive today. That's what it takes to make steel. Doesn't take much labor — we're down to 20 minutes per person-ton.

§4.p3

Why? Let's talk about what happened in the steel industry. People asked me about that before, and I went through a little bit of it but didn't give the whole story. I told you the story of Saugus Ironworks and the problem they were running out of wood in England, so in the 1620s they started an ironworks here, the first one in the United States because we had a lot of forest. They needed the energy, which came from wood.

§4.p4

This is something out of the Metals Handbook on casting — development of foundry technology in the United States. Here's a plot of the Chesapeake Bay in the 1700s. Northeast Forge in 1735, principal forge and furnace in 1724. In the 1700s there were all kinds of forges around the Chesapeake Bay. This became the center of the iron industry in the 1700s, which was the beginning of the metals industry in the United States. Saugus failed in the first 10 or 20 years and went out of business, eventually because of the wood. In Virginia they had all the water power down on the Rappahannock and the other rivers — and you could eat oysters for lunch. They used to feed oysters to the slaves and to the lower-paid laborers because they were so plentiful. Rich people didn't eat oysters — that was poor people's food. Nowadays I had an oyster yesterday in San Francisco that cost me three bucks apiece.

§4.p5

Let's talk about some of these processes. The Bessemer converter came along. You couldn't melt steel with a regular fire. You can stick a poker of steel or even cast iron in a hydrocarbon fire burning in air — we make furnace tools, the hearth and stuff, out of cast iron, and it doesn't melt. But Bessemer built a converter where you had the liquid iron, and you'd blow the air in, and the exhausting air would come out and sort of preheat the air coming in. It was a very crude way to preheat the incoming oxygen. If you preheat your oxygen or your fuel, you get a higher temperature flame. With this particular furnace design he was able to blow air in, get this kind of forced heat exchange, and melt steel.

§4.p6

That wasn't very efficient. Then came the basic open hearth — what Andrew Carnegie used — where you just had a big furnace with a layer of liquid iron about three feet thick. You start figuring out the density of that iron. We used open hearths from the 1880s to the 1970s. When everyone else was going to the basic oxygen furnace, U.S. Steel — being the conservative people they were — in the 1970s put in the world's last open hearth furnace at 450 tons, probably the world's largest steel furnace ever made. They were going bigger and bigger in scale.

§4.p7

To do this and preheat the air in a big furnace, first it has to be a fairly shallow bath because you're getting the reaction of burning the carbon out of the cast iron which comes from your blast furnace. You blow the air in and the oxygen burns away the carbon, leaves behind an iron liquid with less carbon. You control the time of burning to get the carbon down to what you want, and then you can lift up this whole — it's about a thousand-ton furnace if it's 450 tons of iron with refractory and walls. Some of these would actually tip up — pretty massive things. Some you would just tap out of a little hole. You build ceramic, put a little piece of dynamite in there, blow out the hole, and all this liquid iron comes rushing out — pretty hard to stop. You have to have something to catch it, and if you don't, you have a mess.


§5. The Copperweld disaster [30:37]

§5.p1

I remember one of my classmates one summer worked for Copperweld Steel. Harvey came back and told the story that the foreman in the melt shop was an hourly employee — the kind of guy who maybe graduated from high school but he was making a lot of money. When I worked at Bethlehem Steel, the foreman in the melt shop was an hourly worker probably making forty, fifty thousand dollars a year. I was making about twenty thousand dollars a year as an engineer. The foreman had to turn out about 300 tons of steel every hour, he was responsible for it, he had about 30 years working in the steel industry, and he made more than almost all the college professionals — not as much as the plant manager.

§5.p2

So the guy's sitting there in the control room, and the engineer comes in, looks up at the gauges and says, you haven't tapped the heat, I want you to go ahead and tap the heat. Now this whole thing is about a 500-ton vessel with a couple hundred tons of steel, on a trunnion with great big bearings — you basically tip it over and pour it into a big ingot on a big railroad track, then carry it away to cast it in the molds. The engineer says, you haven't cast the heat, I want you to go ahead and cast it. The guy says "but —" and the engineer says I don't care, I told you to cast it, do it, and walks out. The foreman's an hourly employee, the engineer makes more than him. So he does what he's told, he taps it. Problem was, there was no railroad car there yet — that's why he hadn't tapped it. So he taps it right on the floor of the casting shop. The floor of the casting shop is usually just dirt, but it takes about a week to clean that up, and five or ten million dollars, because you've now welded all your steel parts in your cast shop with this big puddle of 200 tons of molten steel which solidifies. You have to wait for it to solidify and then go in there with oxygen lances and cut it up. Both of them lost their jobs. The moral of the story is, have enough respect for that hourly employee and listen to what he means when he says "but." He may not be completely stupid.

§5.p3

The problem with the old open hearths is you had to preheat the air. You had a basic open hearth which could be a quarter the size of a football field, and then two big buildings of two or three stories of brickwork — a big lattice. Initially you'd fire it up once every two or three years and run it for two or three years before shutting down to replace the refractory. The exhaust gases would go through this brickwork, preheating the bricks. The brickwork might be half the size of a football field, all inside a chamber, and then the gases would go up the stack. From about 12 hours before, you had preheated these bricks, and the air comes in — that's how you preheat the air going in — and then you switch over every 12 hours. You're just using the thermal mass of these bricks to contain the heat. You're taking your waste heat going out to heat up bricks, then you switch over and your air coming in is heated by those hot bricks. Fairly inefficient process — took about a day to produce 300 tons of steel.

§5.p4

In the early 70s — though in the late 1950s some Austrians had developed a process where they took pure oxygen and blew it through a lance onto the steel, and in 30 minutes they could burn all the carbon out, where the old process took a full day. There's about a factor of 50 in productivity. The BOF shop has a footprint one quarter that of the open hearth shop. Everybody in the world — the Japanese and others — except U.S. Steel and Bethlehem Steel, went to the BOF. The American companies were 10 or 15 years behind because they were used to doing things the traditional way. The BOF is only filled about ten feet deep and it's about three stories tall.

§5.p5

When you actually blow the oxygen in there at sonic velocity — it's liquid oxygen, and an oxygen company will build a refrigeration plant right next to the steel mill to supply it, whether it's Linde or Air Products. The whole thing turns into a froth two or three stories tall of molten steel and oxygen reacting and burning rapidly. Pretty dramatic to see from a distance.

§5.p6

When I was at Bethlehem Steel, one guy retired and decided to commit suicide, so he came back and jumped into the bath. You float very well on steel, by the way. They could see the body spreading gold on top of the bath. In a case like that, what they do is bury one ingot in the cemetery. The only problem with the steel is the phosphorus increases, because we have a lot of phosphorus in us. Phosphorus is an impurity in steel — so that had to degrade the steel a little bit.

§5.p7

After the BOF converter, you may do argon bubbling to get even lower carbon. You can do degassing — actually pulling a vacuum using this venturi technique that was developed at MIT mechanical engineering in the 1940s. You can degas the steel, pour it into a ladle, transport it by the cranes into a tundish, which is stationary, a holding vessel, and they control the rate of casting into this little vibrating copper mold which might be about 10 feet high, water-cooled copper. The steel comes out red hot and you actually can bend it with rolls, turn it horizontal and cut it off into big slabs about 10 inches thick.


§6. BOF chemistry and the Chipman legacy [37:23]

§6.p1

Student: [Question about the oxygen reaction.]

§6.p2

You're shooting the oxygen in there and there's so much surface area between the gas and the liquid that you get a very rapid reaction. First, there's no nitrogen around to mess things up. The oxygen combines with carbon to form carbon monoxide. One of the reasons it's nice and dramatic is you get a carbon monoxide gas jet coming out that's about 10 or 20 feet tall. You don't stand right next to it, you stand about 30 or 40 feet away. You can feel the radiant heat at 3000 degrees Fahrenheit. You're getting huge amounts of surface area between liquid and solid, burning that carbon out — a little controlled explosion, a huge deflagration.

§6.p3

Student: [Question about whether you also burn the iron.]

§6.p4

No, it doesn't, until you get down to very low carbon. The thermodynamics are such that you can get down to about 0.05 percent — about 500 parts per million carbon — before you start to oxidize the iron. The people who worked all that out: John Chipman here at MIT, who was head of the materials department, and after him John Elliott who was one of his students, and Tom King who was department head when I was an undergraduate. All the world's steel-making technology, the chemistry of it, was developed here at MIT by John Chipman.

§6.p5

John Elliott told me that when Nixon opened up China, Elliott in the late 70s was one of the first scientists to go from the United States. He visited one of the universities there and they had a book called Elliott and Gleiser. John Elliott and Molly Gleiser had written it on thermochemistry for steel making. They had it enshrined in a glass case at the library, because Mao Tse-tung didn't allow them to purchase European things. Harold Larson's got a case of those volumes down in the basement. He was a student with John Elliott at the time.

§6.p6

We have a Chipman room, and over half the chaired professorships in this department come out of the steel industry, in part because of John Chipman. Back in the 1920s, 1930s, 1940s, it was sort of a crapshoot to get the right chemistry for the steel. You'd melt it in the basic open hearth furnace and hope through trial-and-error experiments you got the right chemistry. You could end up with 300 tons of the wrong chemistry steel, which you'd have to downgrade or re-melt. John Chipman came along — he was a physical chemist from Georgia Tech — and applied the same principles of physical chemistry to high-temperature physical chemistry, not aqueous chemistry which is what the chemists were doing in water baths. He applied those principles to high-temperature slag baths and steel, figuring out how the elements partition between the slag phase and the metal phase. Now we can hit those chemistries right on. You get one bad chemistry out of a hundred heats today, whereas in the old days you'd get 10, 20, 30 bad heats.

§6.p7

That's one of the things about productivity. If you go in the Chipman room you'll see the Benjamin Fairless Works award. The world's largest steel mill at the time was the Fairless Works of U.S. Steel. There's lots of metallurgy that goes into the continuous caster — the tundish where the stuff is flowing around, the water-cooled copper molds, solid flux and liquid, a vibrating copper wall that's contracting. You actually have the molten zone supported by rolls, and sometimes you'll have a breakout. This little continuous caster you see here is about 10 or 12 stories tall — a pretty good size building. You want to build a continuous caster like this today, probably about 2 billion dollars.

§6.p8

If you have a breakout you're going to drop your whole tundish right onto the floor, just like they did at Copperweld — but that guy did it sort of intentionally because he was irritated with the jerk engineer. There's all kinds of microchemistry going on — solidification, dendrites, pushing of inclusions. Tremendous technology has been developed in the last 50, 60 years, but most of it was developed between the 1940s and 1980s. Once the steel industry lost its productivity, they closed the research labs. Steel research went down, there weren't any jobs. Now they're coming back and they want to hire students, but there are no students — everybody's working on semiconductors.

§6.p9

Student: [Question about the vibrating copper mold.]

§6.p10

Because you don't want it to stick to the walls — you're trying to get it to move through there, so you vibrate it. You don't want to weld to the copper wall, and you want to reduce the wear on the copper. That copper's got to last for about three or four years before shutdown. The Japanese have run continuous casters for over a year without shutting them down — running 24/7 for over a year. These things have to be fairly robust, and vibration is one of the things —

§6.p11

Student: [Follow-up about space inside the caster.]

§6.p12

Well, you've got these water-cooled copper molds, 10 or 20 feet high, and you've built up a skin half an inch or two inches thick depending on your casting speed. The actual contact is just up in the top. It's cooling away, and you've got radiational cooling from the cold water-cooled copper that's helping grow that skin. One reason you can bend it so easily is that the first part has a liquid core. If you're not careful about the radius of curvature and the casting speed, you can have a breakout — all that liquid steel falls down through everything else — probably a hundred-million-dollar loss. They've got control algorithms and everything else. A lot of incentive to run it as fast as possible but not too fast. Breakouts are not very common — probably not more than one breakout in the world every year or two today.


§7. Mini mills, dumping, and government subsidy [44:51]

§7.p1

When they first started continuous casting in the 1960s, a lot of people said that process will never work. Some people said going from 65 percent yield — pounds of steel produced per hundred pounds cast — to 97 percent is a big enough increase in profitability that they were willing to bite the bullet and do it. American steel companies were too conservative. Boards of directors were not willing to take a risk. It was people who were willing to take a risk, but some of those people were in foreign countries where the government was backing up their risk. It's sort of like the Airbus-Boeing controversy today — how much is the government supporting both of them.

§7.p2

In the United States, well, we don't support Boeing. How much money does Boeing get in defense contracts every year? You don't think that's a way to support things? What about the new Air Force tanker program, which went to a consortium that included Airbus on the first bid? All the Boeing people went to their congressmen and forced the Air Force to reopen the bid. And guess who won that time? Boeing. Now Airbus is pretty much directly subsidized, and they're always fighting about how you're illegally subsidizing your aircraft industry. It's a tremendous export industry. What's Boeing today — 40, 50 billion dollars a year worth of exports, and fairly profitable in general.

§7.p3

Student: [Question about whether Boeing is always subsidized.]

§7.p4

All the time. Half of Boeing is government contracts. We don't subsidize in the same way — we subsidize in a different way. But our subsidy is okay, we say. The Europeans say no it's not. These are some of the externalities. It was a real problem for the American steel industry in the 1980s, because everyone had convinced Congress that the Japanese were not dumping steel — and then the Romanians, and then the Koreans, and now the Chinese. They've been fighting this for 40 years.

§7.p5

Yes, the American steel industry was losing a tremendous amount of money in the 1980s, but the reason — I showed you these plots before — productivity had doubled, consumption was constant, employment went down. That was because they went to BOFs from open hearths, they went to continuous casting, they built mini mills, and mini mills could use 100 percent scrap.

§7.p6

Before the mini mills, they had to use 70 percent virgin iron ore to make the steel from cast iron, and only 30 percent scrap in the BOF. An electric furnace can make steel out of 100 percent scrap. You can use John Chipman's principles to purify the scrap to get the chemistry you want. It's a lot harder in aluminum, because — this goes to your question about burning out the carbon before you burn the iron — if you start burning away iron, you're going all the way back to iron ore, which is a lot of wasted energy. In aluminum, you'll burn up the aluminum before you burn out the copper and other things. In steel, you can burn out a lot of these. Certain things you can't burn out — bismuth in steel goes to the grain boundaries and produces a brittle product.

§7.p7

Fifteen years ago people were trying to get lead out of solder, and they're still trying to get lead out of solder. I'd go to these conferences and they'd say, we've developed this bismuth alloy. I said that's great — so you're going to start putting pounds of bismuth in every automobile, which means we will no longer be able to recycle steel automobiles. That was dead on arrival, but these metallurgists working on solder didn't know anything about steel making. They didn't realize nobody was going to put bismuth alloys into the soldering on an automobile, because you can't — you'd have to separate the scrap. You can't just shred up the automobile and dump it into the furnace, you'd have to separate it out. We do separate some things — we take out the airbag explosive, because that has killed people in the steel mills when they're shredding and all of a sudden a piece of shrapnel goes through someone's arm. They do some things, but you can't start ripping all the wires out — you couldn't afford to recycle the steel.


§8. Chaparral Steel and the 3/8 inch rebar [50:10]

§8.p1

What happened in the 1970s is people like Gordon Forward and Ken Iverson realized you could buy scrap steel at $100 a ton on the open market. There are millions of tons out there. Cast iron cost $200 a ton. You had a $100-a-ton advantage on something that sold for $400 a ton — a 25 percent cost advantage to use 100 percent scrap. Except the quality of the scrap was not very good because it had all these alloying elements, and about the only thing they could make was reinforcing bar for concrete. It just has to have 60,000 strength and be the right diameter. You don't have to have toughness requirements — let's face it, the concrete has no toughness, so you put the steel in, it's tougher than it was.

§8.p2

You could make rebar, but rebar was garden-variety low-quality stuff. And the Bethlehem Steel manager said, "we don't care about mini mills." This is what Clayton Christensen made his name for at Harvard Business School — the innovator's dilemma. Here you have these little mini mills, and one of his three examples is steel technology. My daughter worked researching things for him one summer, and I'm a reference in there on what it cost to build a steel mill. Rebecca came home and said, "Dad, Clayton wants me to find out what it cost to build a steel mill and I can't find it anywhere." This was 1995, and no one had built a steel mill since Bethlehem Steel in 1965. It had only been countries that built them, all mixed in with the government finance.

§8.p3

About a year before, I'd been sitting in the Saginaw, Michigan airport with one of my graduate students, and I'd sketched out on a piece of paper the approximate cost of an integrated steel mill, a mini mill, and a micro mill. A mini mill you could build for like 100 million dollars. An integrated steel mill was 15 billion, by my estimate. It cost Bethlehem Steel in 1965 5 billion dollars. That was their whole year's gross product, and they almost went bankrupt. By the time they hired me, it was the most profitable year ever — that's why they could afford to hire me. But they almost went bankrupt in the previous six or seven years.

§8.p4

No one could take on a 5 billion dollar investment back in the 1960s. That's like Intel taking on a 15 billion dollar investment today, or Boeing a 15 or 20 billion dollar investment. These companies are betting the farm on building a new 787 Dreamliner or a new computer fab. Other countries — it's the whole country. There's never been an integrated steel mill built since Bethlehem Steel Burns Harbor by a company. Plenty of integrated steel plants built, but by countries doing the financial backing. No private investment taking on a 20 or 30 billion dollar investment for an integrated steel plant.

§8.p5

What they did at Chaparral Steel — Gordon Forward is a graduate of this department, a Canadian, retired in British Columbia now. Every now and then, if you were an employee at Chaparral, you had to go spend one week a year with the salesman in the field to find out what the customer wanted. What a unique thing. They found out that the smallest diameter rebar, three-eighths of an inch, got like a 20 or 30 percent premium, because you could only go so fast through the rolling mill. So first they came back and said we're going to roll faster — we're going to take over the 3/8 inch rebar market because there's more profit there. So they tried to go faster.

§8.p6

This stuff is going through there 60 miles an hour, and if you go faster you get instabilities, and all of a sudden you've got hot band steel that breaks and goes whipping around. If someone's there, cuts your arm right off. My oldest daughter Rebecca was born in the hospital in Bethlehem, Pennsylvania — beautiful hospital, because they sent maimed steel workers down there every day. Cut your arms right off.

§8.p7

So they tried to speed it up for a while, and finally they said no, we're doing it the wrong way. We shouldn't try to speed it up, we should try to slow it down. They slowed it down — here it's coming into the rolling stand as one bar and coming out as two bars. They split it in two. They had to go slower to do it, but they got twice the productivity out at a slower rate. They did that once, and decided they could do that again. Here you see two bars coming in, and four bars coming out. They did it twice. So they're running this mill slower, but they're getting four times as much product through. They took over the 3/8 inch rebar market.

§8.p8

I'll tell you about that tomorrow. The quality actually went up — that was another benefit. They proved that with I-beams in less than a year, and that's the rest of that story. You can read about it — not in this book, but there's another book I was involved in reviewing on Chaparral Steel's product development with Steve Wheelwright at Harvard Business School. You can read about it if you're really interested.

Cases referenced

  • Copperweld continuous caster breakout §5.p1

    Hourly foreman vs. engineer dispute. Engineer overrides foreman's "but —" and forces a tap when no railroad car is in position. 200 tons of molten steel poured on the casting shop floor. Both lose jobs. Moral: respect the hourly employee's tacit knowledge.

  • Chaparral Steel 3/8 inch rebar productivity case §8.p1

    Gordon Forward (MIT graduate, Canadian) at Chaparral. Mandatory week-per-year with the salesman discovers 20-30% premium on 3/8 inch rebar. First attempt: roll faster — instabilities, maimed workers. Second attempt: slow down and split the bar — one in, two out, then one in, four out. Took over the 3/8 inch market with quality gains as a bonus.

  • Bethlehem Steel labor and worker injuries §4.p2

    Tom's 1975 employment data point (45% labor, 45% materials, 10% profit, vs. 1980s 55% labor and 10% loss). Foreman pay comparison. Suicide-in-the-bath anecdote. Bethlehem PA hospital "for maimed steel workers." Bethlehem Steel near-bankruptcy in early 1960s. Burns Harbor as last US private integrated steel mill.

  • Bethlehem Steel Burns Harbor §8.p3

    Last private integrated steel mill ever built in the US, 1965, cost Bethlehem $5 billion (their entire year's gross product). Used to make the "no private company can finance an integrated steel mill anymore" point. Setup for Clayton Christensen / mini-mill discussion.

  • U.S. Steel's last open hearth furnace §4.p6

    450-ton open hearth installed in the 1970s when everyone else had moved to BOFs. Probably world's largest steel furnace ever made. Symbol of US Steel conservatism.

  • Saugus Ironworks §3.p9

    Established 1620s in response to English wood shortage. Failed within 10-20 years. Iron industry migrated to Chesapeake Bay (Northeast Forge 1735, principal forge 1724) for water power.

  • Japan Manufacturing Study (Tom's 1984-85 sabbatical) §3.p2

    Year on sabbatical with U.S. Office of Naval Research, visiting research labs and manufacturing facilities. Concluded Japanese productivity was not superior to US — competitiveness driven by exchange rate (250 yen/dollar). Anecdotes: $36,000 Tokyo rent, $15 Cheerios, C-5A Coca-Cola pallets, $2 hot dogs, embassy commissary access.

  • MIT Commission on Industrial Productivity §3.p1

    Started ~1985 in School of Engineering conference room; published 1989 as *Made in America*. Led by Dertouzos (computer science), Lester, and Solow (Nobel economist). Tom served on the steel-industry subcommittee.

  • Continuous casting adoption (US vs. world) §7.p1

    65% yield (ingot) → 97% yield (continuous casting) was a transformative productivity gain. Foreign governments backed the risk; American boards of directors would not. Setup for the Airbus/Boeing subsidy parallel.

  • Bismuth-tin solder steel contamination §7.p7

    Lead-free solder researchers proposing bismuth-tin alloy; Tom's objection at conferences that putting bismuth into automobiles would destroy steel recyclability (bismuth segregates to grain boundaries, embrittles). "Dead on arrival" — the solder metallurgists didn't know steel-making.

  • Airbag explosive in steel mill shredding §7.p7

    Brief example of why you can't simply shred automobiles for scrap. Workers have been injured by airbag explosives going off during shredding. ## Cases referenced briefly

  • Spruce Goose (Hughes H-4 Hercules) §2.p2

    Wood-construction biggest-aircraft example. Used to make the "you use the materials you have" point.

  • Ashby's age-of-materials plot §1.p2

    Tom revises his own attribution date (1992, not 1980), and notes Ashby quietly corrected the original "metallurgy is dead" framing in the fourth edition.

  • MIT Chipman / Elliott / King steel chemistry lineage §6.p4

    John Chipman (Georgia Tech physical chemist) applied high-temperature physical chemistry to slag-metal partitioning; transformed steel chemistry from "crapshoot" (10-30% bad heats) to one bad heat in a hundred. Over half this department's chaired professorships derive from steel-industry funding tied to Chipman.

  • Elliott and Gleiser in Mao-era China §6.p5

    Elliott's textbook enshrined in glass case at Chinese university because Mao restricted European imports. Brief anecdote within the Chipman cluster.

  • MIT-developed venturi vacuum degassing §5.p7

    Developed at MIT mechanical engineering in the 1940s. Brief in-passing reference within the BOF→tundish process flow.

  • Bethlehem Steel suicide-in-bath §5.p6

    Retired worker jumped into a BOF bath; body floated, visible as gold on the surface. One ingot buried in the cemetery. Phosphorus contamination from human body slightly degraded the heat. Brief anecdote, but recurs in Eagar's lectures.

  • Carnegie open-hearth scale-up §4.p1

    Andrew Carnegie's economies-of-scale strategy built initially on Bessemer, then on open hearth. Used as the setup for U.S. Steel's eventual conservatism trap.

  • Boeing-Airbus government subsidy parallel §7.p1

    Used to illustrate that foreign-government backing of integrated steel mills is part of a broader pattern. Boeing's defense contracts (~50%) are an indirect US subsidy; Airbus is directly subsidized; both governments deny their own.

  • Clayton Christensen innovator's dilemma research §8.p2

    Tom's daughter Rebecca worked one summer for Christensen at HBS; Tom is cited in *The Innovator's Dilemma* on integrated-steel-mill cost. Tom's 1995 sketch in the Saginaw airport: integrated mill ~$15 billion, mini mill ~$100 million, micro mill smaller still. ## Figures referenced

Layer 2 — cleanup edit
p1 00:43

And hopefully that's the end of the lectures in next week. So we'll see what happens. Uh okay so my little thing where I kind of say well, kind of a throwaway in the first five minutes. So, good old Ashby. I mentioned, and Michael Ashby is a real leader in materials selection and design, and he's a great material scientist okay, and I'm not going to try to knock him for that. I'm not going for something else. But I gotta find here.

p2 01:26

So Ashby, I showed you probably on the first day of class, second day of class, this Ashby plot. Uh materials used for the ages, I certainly showed it several times. And it turns out I was wrong. I went back to some of his books. I thought this was one of his 1980 books. It was actually the Material Selection and Mechanical Design, and he actually came up with this plot, first I could find it was 1992. He does have books going back to 1980 but didn't have that plot. So here's the plot and that's where my slide came from. Whoop, what'd I do?

p3 02:10

You know it did this to me earlier, before everybody got here. I think there's something wrong with this cable. Let's try. [Long pause while Tom works on the projector.] Well that's not working. Not the cable. Oh let's reboot that. Well, okay I hit a button somewhere and then I hit it again and it works anyway.

p4 04:48

So anyway, Ashby came up with this plot um in 1992 and what he said, well anyway so this is the first edition of this Material Selection of Mechanical Design, and then the fourth edition, that was 1992, the fourth edition is 19 is 2012, 2011. So I sort of, when I presented this I said well, you know, he was extrapolating around 1980 or 1990 and saying oh, the amount of metals is decreasing and it's going to continue to decrease, and the amount of other structural materials is going to increase over time. And so I just happened to buy this a week ago and I was flipping through it, and what he says in the fourth edition is he sort of corrects that okay.

p5 05:54

And he says in the caption of this thing, now he's gotten color, I'm going to have to get in color, he says, "The evolution of engineering materials with time, relative importance," which he's plotting on the vertical axis there okay, of the materials, which is what he had before, "is based on information contained in the references" okay "from 1960 onward," so from here onward, "data for teaching hours allocated to each material family at the United Kingdom and US universities" okay. So this is basically, and it's true, you know when I was a student in 1970 it was a metallurgy correction curriculum, it was metallurgy and material science, and it didn't become material science and engineering until 1974, or 73 or something anyway, um, in this department. And so it was primarily metallurgy and that's correct. Except that's not what he said in 1992.

p6 07:02

That plot was supposedly, here's the plot okay. And he says, "The evolution of engineering materials, this evolution increasing pace, are illustrated in Figure 1-1, the materials of pre-history" blah okay, up here. "There had of course been develops in other classes of material, Portland cement, refractories," and he's talking about the fact that everybody taught metallurgy back in the 1960s. "The rate of development of new metallic alloys is now slow, demand for steel and cast iron has actually fallen." That's wrong. It has never fallen. Oh maybe from what in one year, but if you draw a trend line over a decade it's been increasing okay, and it continues to increase.

p7 07:56

Okay, "the polymer and composite industries on the other hand are growing rapidly." Yeah because they were so small. It's not hard to grow rapidly when you're small, it's very difficult to grow rapidly when you're big okay. It's what your baseline is. "And projections of growth, production of new high performance ceramics suggest rapid expansion here also." Well this is right after the ceramics fever — oh, they're going to make jet engines out of ceramics and all this other stuff. Hey you're supposed to be the material property guy, you're supposed to know what about strength and toughness okay, you got the plots in your book. Well in fact, he was on the same type of bandwagon as everyone else in 1990 saying oh, metallurgy is dead okay. My, the last department head in this department was a polymer guy, he actually said metallurgy was dead, which I didn't particularly appreciate. But nonetheless, other materials are important and I'm going to talk about some of those. Does anybody have any questions? Sorry about the minute, several minutes I killed trying to get this thing operating. No questions on this?

p8 09:06

Well this one's not looking very good. I got to get these things out of these things. I had a, long time ago I gave a talk on material selection at some conference. If you look at different materials, it's going to be a better way to get this. Let me try it with the light. Okay, well that's not so bad with the light, okay. Material and the strength to death [density] density ratio. Well it turns out aluminum is better than steel for typical strengths and densities. Composites are right in there, equal to steel. Very fancy composites can actually be significantly above, but they were talking about materials that cost ten thousand dollars a pound. Plastics are relatively low even though they're the lightest weight of all these, as is wood.

p9 09:55

But it turns out if I'm going to build something like an aircraft, you look at the strength to density which is the specific weight of the material, we make aircraft out of all these things. I mean, the one of the biggest aircraft ever built, what they call Howard Hughes's, the Guppy or whatever, the — Spruce Goose, yeah. The Spruce was made out of wood okay. So in the 1940s when you wanted to make the biggest aircraft in the world, you didn't make it out of aluminum, you made it out of spruce okay. Then we built one of them but anyway, but it worked okay.

p10 10:34

So there is again there's competition for materials. Now another thing from that same talk that I gave, a selection of structural materials, well the number one thing I've been telling you is cost okay. Strength and fracture resistance, there's your strength toughness, and that's what I've been saying is after cost that's what we're worried about. And we really didn't worry about fracture resistance until the last 25 to 50 years and some industries haven't even caught up yet. Availability, okay. One of the strengths of steel is there's a lot of iron out there okay, and it's not hard to come by. That's the strength of aluminum, it's just that aluminum takes a lot of energy, but they're both available and that's why they're the two most common metals.

p11 11:19

Wood, really good quality wood, we're running into the same type of problem they had back in the 1500s in England. Their really good big trees and high quality trees have sort of been, we've deforested them and we don't have them like we used to. And so people are using composites and making things look like fake wood and stuff. Fabricability. Hey, if you can't machine it or cut it, uh you can't weld it uh very easily, it's one of the problems with ceramics. I showed you the ad for the watch, the little bezel. Well you know ceramic is very difficult to machine. Yeah well that's why you gotta buy a forty thousand dollar watch to have them make it out of ceramic, right.

p12 12:01

Recyclability. Now, that's an interesting topic in and of itself in that, I told you the most used metal is steel, had a billion tons a year, and steel is about 80 to 90 percent recycled okay. Everybody thinks of recycling of aluminum, you know people go around and pick up beer cans and soda cans and recycle them. Aluminum is like 50, 60 recycled. It's not recycled as much as steel. And there's a number of reasons. It turns out the aluminum alloys are so different in their classes that you try to mix them all together and you end up with a mishmash that you can't use for much of anything. And so people are working on new ways to separate the alloy content out of the aluminum alloys.

p13 12:57

But steel is the most recycled. But there's two materials that are much higher than steel in usage. Did anybody remember what they were? They're not metals. Stone, and cement, and well wood is there too. Now you don't resize, I mean you go to the hobby shop and can, uh Ken Stone recycles wood okay. He made some things for me and it all came from recycled wood okay. He used to use the old MIT that we had desks like this, and they were solid cast iron legs, and it was, um, it was bird's eye maple, I mean it's beautiful maple, two inches thick solid okay. Yeah we got rid of them rather than refinish them. It's beautiful wood. So Ken's got some, I mean he recycles that. And he, anyway, so he recycles wood. But mostly wood is kind of consumed. It's a renewable resource.

p14 13:54

But recyclability, the one that we make of one and a half billion tons a year of that we don't recycle is cement. And you can't keep putting one and a half billion tons a year of big old rocks, because once you break it up and you have an earthquake or you go destroy the building and send it to a landfill, you can't keep landfilling one and a half billion tons a year. You want a problem to work on, figure out how to recycle cement. There's a huge industry out there, and at some point in the next 10 or 15 years people are going to realize you can't keep landfilling all the cement okay. We've had a tremendous growth in the use of cement, you know, it used to be a half a billion tons, and one and a half billion tons and continuing to grow, particularly in the third world. You can't just keep building up piles of old rubble.

p15 14:46

Repairability. This is one of the Achilles heels of all your fancy composites okay. How do you repair them okay? You went to all this trouble and processing and extra expense to make this fancy material, and you have a hard time. There are also others. I mean this is just what I put up at that time. I actually have a list of 10 or 12 different things and you can think about some of these things and in terms of specific examples.

p16 15:16

However, even Roger Rudyard [Rudyard] Kipling knew that — gold, oops, better drop it down in size. Rudyard Kipling: "Gold is for the mistress, silver for the maid, copper for the craftsman cutting at his trade. Good, said the baron sitting in his hall, but iron, cold iron, is master of them all." So this is what I've been telling you, is not something new, it's been known for a long time okay.

p17 15:44

I want to start kind of a new topic now but before I do that, our theme before was there are practical limits on toughness and density. I told you, hey for penetrators or for little, you know, eyelids for people who have been disfigured, density is important. Toughness is important and I could teach a whole class on the problems of toughness where we had a brittle fracture in something. This is something that I wrote up before on nails. We already went through nails, I'm not going to go through nails again, in the growth of importance of steel and nails and stuff. Ashby points out that the ages of the human race are defined in terms of the materials that they use. There's the Stone Age, the Bronze Age, the Iron Age, and now some people say we're in the Silicon Age so far as that goes.

p18 16:42

And, you know, we use the materials that were available. The Romans used stone and concrete and built ships of wood. The civil engineers here have a concrete canoe contest every year where they try to make a concrete canoe out of chicken wire and concrete okay. You don't usually think of concrete as a material for ships, but hey, you don't have to use it for very long. And I've talked to you about the materials that we use.

p19 17:11

It turns out that the topic I want to switch into, which is not necessarily a material selection but I kind of lecture like I feel like, and that's productivity. And I thought I'd tell you a little bit about Made in America: Regaining the Productive Edge okay. Michael Dertouzos, who, Michael was a professor, he was running the computer science lab at MIT. Richard Lester, is he now head of the nuclear engineering department, anyway he's been an administrator around here for 20 years. And Bob Solow is an economics Nobel Prize winner. And so this is the MIT Commission on Industrial Productivity. Now I actually as a younger faculty member got involved in this. It started about 1985 at a meeting in the School of Engineering conference room. This was published in 1989.

p20 18:10

And at the time in the mid 80s the Japanese were knocking our socks off in manufacturing, and it's, everybody thought that the problem was regaining the productive edge. Well in 1984 and 85 I went over to Japan, and I watched, I was over there for a year on sabbatical working for the office of neighbor [Naval] U.S. Office of Naval Research. And it turns out I looked at things, I was visiting research labs and manufacturing facilities all over Japan for a whole year, and I said, this is not better than what we have in the United States. It might have been making better quality, but at the time there was a significant competitiveness issue. And that was that it was 250 yen to the dollar after World War 2. It had been like 350 yen to the dollar or something. Today anybody know what the exchange rate is? It's about 100 yen or 90 yen to the dollar okay.

p21 19:13

Well back in 1985 when I was there, 250 yen to the dollar, I mean 10,000 yen note was a $40 bill okay. And yeah my housing was pretty expensive, I, the U.S. government paid $36,000 for me to rent a house in Tokyo for my family. And food was expensive, particularly if you wanted to eat like an American. If you want to eat like an American in Tokyo, really expensive, I mean back then 1985 a box of Cheerios could cost you fifteen dollars okay. That'd be like 35 or 40 today. Hey, because they had to import it from the United States. If you want to eat like a Japanese you could eat pretty cheap, and if you want to eat like Chinese you could eat really cheap in Japan.

p22 20:00

I had a certain advantage, I was a U.S. government employee for that year, and I could go out to the post exchange and I could buy things at the military exchange. And they would have C-5As coming over from Seattle on the weekend. You go out to Yokota Air Force Base and there'll be 10 of them there, and this is the National Guard basically taking a quarter million dollar flight from Seattle to Tokyo to get their training time in okay. And what were they offloading? Big pallets of Coca-Cola. So I could buy a case of Coke in Tokyo cheaper than I could in Boston, okay, and they've been flown across by the military okay. So there's all kinds of competitiveness things there.

p23 20:47

And I remember when I was first there, the first week I was there, I showed up at church and they said can you go, I was the only person who was a government employee at the time, can you go down the embassy and buy us hot dogs because they were going to have a social and they wanted like 300 hot dogs. And a hot dog in Japan would cost you like two bucks apiece, just for the hot dog without the bun. I got it on the commissary and buy it for 50 cents a pound okay for hot dogs. So I had to go down the commissary and buy all these frozen hot dogs that week. But there's anyway, there's some disparities. One thing I learned, if you're ever going to live abroad, live under the U.S. State Department rules. Those people know how to live abroad okay, obviously. They take care of themselves.

p24 21:32

Anyway, so we thought that the Japanese were these master manufacturers, and it never quite made sense to me in the mid 80s from what I'd seen over there. They had lots of inefficiencies built into their system. Finally in the early 90s I read something in The Economist that pointed out the United States was the most productive nation in the world in terms of person hours per whatever you want to use as the metric, whether it's tons of steel or whether it's pounds of aluminum or computer chips or whatever. We actually had the competitive advantage in almost everything including agriculture at that time. Now in some parts of the world, I think Thailand now is the most productive rice grower because they got the right climate and the soil and and whatnot. But we are the most productive nation in the world and have been for the last century okay. We passed the British, so far as that goes.

p25 22:30

However, the important thing here is to read the very beginning of this book. It says, "To live well, a nation must produce well." So this is a book that was written by actually a committee but it was led by these three people, and I served on one of the committees that actually looked at the steel industry, and there's a section in there on the steel industry, so far as that goes. Another quote which I thought I'd written down but anyway, there's a guy Paul Krugman, and I think I've asked you, oh here it is. If anybody knows who Paul Krugman is — before. He's an economist. He did all of his really good work here at MIT. He wrote some very good books that were understandable and correct principles. He then went to Stanford, which is when he won the Nobel Prize, and now I think he's back at Columbia or somewhere, anyway he's still around, he's still doing things. But he's an MIT product.

p26 23:37

And so here's Made in America: "To live well, a nation must produce well." Paul Krugman used to say "productivity isn't everything but in the long run it's nearly everything." And that's where I talked about nails and you know it used to be, I actually have the plot here which I showed you way ahead of time, of a little graph I made the year before on productivity of steel okay. So here's productivity of steel, a graph that I put together last year for this course, just scratched it out one morning. And so we got hours per ton on a log scale versus time on a linear scale.

p27 24:26

It was very labor-intensive back in the old days, and then the Bessemer process came along, we learned to melt steel. Before, we basically either started with cast iron, or if we made wrought iron we basically diffusion reduced it from the ore and ended up with a sponge which we then had to forge by hand into wrought iron okay. So, which was steel basically, uh a lower carbon cast iron. And then Carnegie came along with economies of scale and built huge steel plants based on initially the Bessemer [Bessemer] process but others later, the open hearth. And then we came up in the 60s with the basic oxygen furnace, continuous casting, mini mills which were smaller, a way to use a lot of scrap.

p28 25:14

And here we went from labor intensive in 1975, when I worked for Bethlehem Steel was 50 labor, materials — actually was 45, and they actually made a 10 profit. In the 1980s it was 55 and they made a 10 loss. That's another story. Raw materials energy intensive today okay. That's what it takes to make steel. Doesn't take much labor, we're down to 20 minutes a ton okay, per person ton or whatever.

p29 25:48

Well why do we have that? Let's talk just a little bit about what happened in some of the details of the steel industry. People asked me about that before, and I went through a little bit of it but I didn't give you the whole story. I did find — I told you the story of Saugus Ironworks and the problem they're running out of wood in England, and so in the 1620s they basically started an ironworks here, the first one in the United States because we had a lot of forest. And they, we needed, they needed the energy which came from wood.

p30 26:22

Well this is something out of the Metals Handbook on casting. Development of foundry technology in the United States is the chapter, and here's a little plot of the Chesapeake Bay in the 1700s. And it shows you Northeast Forge in 1735, and principal forge, furnace and forge in 1724. In the 1700s there were all kinds of forges around the Chesapeake Bay okay. This became the center of the iron industry in the 1700s, which was the beginning of the metals industry in the United States. Saugus failed in the first 10 or 20 years and went out of business, but eventually they did because of the wood. And in this case because all the water power down in Virginia, if you know anything about the rivers, the Rappahannock and stuff, and you could eat clams for lunch okay. Actually clams, not clams but oysters. Uh they used to feed oysters to the slaves and to the lower paid laborers because they were so plentiful. It was, rich people didn't eat oysters okay, that was poor people's food okay. Nowadays you go try to purchase, snorts I had an oyster yesterday in San Francisco cost me three bucks a piece, anyway.

p31 27:48

And then we talked about the nails. Well let's talk about what happened in some of these uh processes. So the Bessemer converter came along, and what happened is you couldn't melt steel with a regular fire. You can stick a poker of steel or even cast iron in a hydrocarbon fire burning in air, and we make furnace tools okay, we make the hearth and stuff out of cast iron okay, it doesn't melt. But Bessemer came along, and basically what he did is he built a converter where you had the liquid iron here and you'd blow the air in, but the exhausting air would come out and it would sort of preheat the air coming in. So it was a very poor crude way to preheat the incoming oxygen. If you preheat your one of your oxygen or your fuel you get a higher temperature flame. And he was able to, with a particular type of furnace design, he was able to blow air in and get this kind of open forced open exchange heat exchange here, and end up being able to melt steel.

p32 28:56

That wasn't very efficient, but uh they came along, and this is what Andrew Carnegie used, was the base basic open hearth, uh or the open hearts hearth furnace, where you just had a big furnace and you had a layer of liquid iron about three feet thick. You start figuring out the density of that iron. We used open hearths from the 1880s to the 1970s. When everyone else was going to the basic oxygen furnace, U.S. Steel being the conservative people they were, in the 1970s put in the world's last open hearth furnace at 450 tons, probably the world's largest steel furnace ever made. They were just going bigger and bigger in scale.

p33 29:39

Well, it turns out to do this and to preheat the air in a big furnace like this, first of all it has to be a fairly shallow bath because you're still getting the reaction of burning the carbon out of the cast iron which comes from your blast furnace. You blow the air in here and the oxygen burns away the carbon, leaves behind an iron liquid that has less carbon in it. And you control it, the time of burning, get the carbon down to what you want, and then you can lift up this whole, it's about a thousand ton furnace if it's 450 tons of iron with refractory and the walls and everything else. You actually, some of these things would actually tip up, pretty massive things. Some of them you would just tap out of a little hole. You basically build ceramic and then put a little piece of dynamite in there, blow out the hole, all this liquid iron comes rushing out, pretty hard to stop. You basically have to have something to catch it, and if you don't you have a mess.

p34 30:37

I remember one of my classmates one summer worked for Copperweld Steel. And so Harvey comes back and he tells the story that summer that the uh the foreman in the melt shop was an hourly employee, this type of guy who maybe graduated from high school but he was making a lot of money. When I worked at Bethlehem Steel, the foreman in the melt shop was an hourly worker who was probably making forty, fifty thousand dollars a year. I was making about twenty thousand dollars a year as an engineer. So the foreman in the melt shop, he had to turn out about 300 tons of steel every hour, and he was responsible for it. He didn't know a whole lot about it but he was responsible for it, and he had about 30 years working in the steel industry, and he made more than almost — he didn't make as much as the plant manager but he made more most of the college professionals.

p35 31:31

Anyway, so the guy's sitting there in the control room, and the engineer comes in, he looks up at the gauges and he says oh you haven't tapped the heat, I want you to go ahead and tap the heat. Which means out of this type of conveyor, this type of basic oxygen furnace down here, he means this whole thing is about a 500 ton vessel and a couple of hundred tons of steel, and it's on a trunnion, great big bearings, and you basically tip it over and pour it into a big ingot, it's on a big railroad track, and then you carry it away to cast it in the molds and stuff. Well anyway, he comes in this, in the 1970s, he says, he looks up he says oh you haven't cast the heat, I want you to go ahead and cast it. And the guy says "but —" he says I don't care, I told you to cast it and do it, and he walks out. But, hey, he's an hourly employee, he makes more than that guy. So he does what he's told, he taps it. Problem was there was no railroad car there yet, that's why he hadn't tapped it. So he taps it right on the floor of the casting shop. Now the floor of the casting shop is usually just dirt, but it takes about a week to clear that up, and five or ten million dollars okay, because you sort of now welded all your steel parts in your cast shop with this big puddle of 200 tons of molten steel which solidifies. You have to wait for it to solidify and then you have to go in there with oxygen lances and cut it up. Both of them lost their job okay. But the moral of the story is, have enough respect for that hourly employee and listen to what he means when he says "but" okay. Uh, he may not be completely stupid.

p36 33:11

Anyway, the problem with the old open hearths is you had to preheat the air. So you had this, a basic open hearth which could be a quarter the size of a football field, and then you'd have these two big buildings of two or three stories of brickwork, and it's brickwork and a big lattice. And initially you'd fire this thing up about once every two or three years and run it for two or three years before you shut it down and replace the refractory. But you had to heat up the brickwork and stuff. The exhaust gases would go through this brickwork preheating the bricks. Now this brickwork might be half the size of a football field or the size of a football field all inside a chamber, and then the gases would go up the stack. But you're going to preheat these bricks in the meantime. From about 12 hours before you had preheated these bricks and the air comes in, and that's how you preheat the air going in, and then you switch over every 12 hours. And you're just using the thermal mass of these bricks to contain the heat okay. So you're taking your waste heat going out to heat up bricks, and then you switch it over and you have your air coming in and those hot bricks are now heating up the thing. Fairly inefficient process, took about a day to produce 300 tons of steel.

p37 34:34

And in the early 70s, even though in the late 1950s some Austrians had developed a process where they took pure oxygen and blew it through a lance onto the steel and in 30 minutes they could burn all the carbon out with pure oxygen that took a full day. So there's about a factor of 50 in productivity. This shop has an area that's one quarter the footprint of this shop. So everybody in the world, the Japanese, and except U.S. Steel and Bethlehem Steel and others, they weren't, you know they were about 10 or 15 years behind because they were used to doing things the traditional way. Um anyway, so you know, and this thing actually is only filled about ten feet deep and it's about three stories tall.

p38 35:20

And when you actually blow the oxygen in there, supersonic velocity, sonic actually, it is — well it's not supersonic but sonic velocity. It's liquid oxygen. An oxygen company will build a plant right next to the steel mill to survive supply the liquid oxygen. So they do a refrigeration plant, whether it's Lindy [Linde] or Air Products. You'd have a company that would build a plant right next to your steel mill to be able to supply the liquid oxygen. And this whole thing turns into a froth that's about two or three stories tall of just molten steel and oxygen just reacting and burning rapidly. It's pretty dramatic to see it from a distance.

p39 36:04

When I was at Bethlehem Steel, one guy retired and then he decided to commit suicide, so he came back and jumped into the bath. You float very well on steel by the way. They could see the body spreading gold on top of the bath. And in a case like that what they do is they bury one ingot in the cemetery okay. The only problem with the steel is in the phosphorus increases, because we have a lot of phosphorus in us. Phosphorus is an impurity in steel, but anyway, so that had to degrade the steel a little bit.

p40 36:33

So you have a BOF converter, and then you take it and you may do argon bubbling to get even lower carbon. You could do uh degassing, where you actually pull a vacuum using this venturi technique that was developed here at mechanical and mechanical engineering at MIT in the 1940s. You can degas the steel, and then you pour it into a ladle, and from there that's transported by the cranes and it goes into a tundish, which is stationary, which is just a holding vessel, and they control the rate of casting the steel in this little vibrating copper mold which might be about 10 feet high, water cooled copper. And the steel is coming out red hot and you actually can bend it with rolls, turn it horizontal and cut it off into big slabs about 10 inches thick.

p41 37:23

Student: [inaudible question about oxygen reaction]

p42 37:26

Yeah, oxygen, is it the fact that you're jutting [shooting] the oxygen in there and there's so much application and you've got so much surface area between the gas and the liquid that you're just getting a very rapid reaction? First of all there's no nitrogen around to mess things up, and you're just, the nitrogen, the oxygen combines, the carbon monoxide. And one of the reasons it's nice and dramatic is you get a carbon monoxide gas jet coming out of here that's about 10 or 20 feet tall okay. You don't stand right next to it, you kind of stand about 30 or 40 feet away. But it's pretty dramatic, and you can feel the radiant heat at 3000 degrees Fahrenheit okay coming from this. But it's, you're basically getting a froth and you're getting huge amounts of surface area between your liquid and your solid, and just burning that carbon out of there, and it just anyway, it's a little explosion, controlled explosion uh going on in there. It's a huge deflagration.

p43 38:22

Student: [inaudible question about burning iron]

p44 38:28

Uh no, it doesn't, until you get down to very low carbon. The thermodynamics are such that you can get down to about .05, about 500 parts per million carbon, before you will start to oxidize the iron. Now the people who worked all that out, there's a guy named John Chipman here at MIT who is head of the materials department, and John Chipman and after him John Elliott who was one of the students, and Tom King who was the department head after John Chipman and was the department head when I was a freshman or undergraduate, all the world's steel making technology, um, the chemistry of it was developed here at MIT okay, by John Chipman.

p45 39:07

I remember John Elliott said that when Nixon opened up China, and John Elliott in the late 70s was one of the first scientists to go over to China from the United States, and he visited one of the universities there and they had a book written called Elliott and Glyser [Gleiser]. John Elliott and Molly Glyser [Gleiser] had written this book on thermochemistry for steel making. They had it enshrined in a glass case at the library, because the Chinese didn't have, you know, Mao Tse-tung didn't allow them to purchase a lot of, you know, European things. Harold Larson's got a case of those things down in the basement, those volumes. He was a student with John Elliott at the time.

p46 39:49

But in the re-, we have a Chipman [Chipman] room and most of the chair, perfect over half the chaired professorships in this department come out of the steel industry, in part because of John Chipman. Back in the 1920s and 1930s and 1940s it was sort of a crapshoot to get the right chemistry for the steel. You kind of melt it and put in the basic oxygen for a basic open hearth furnace and hope through a kind of trial and error experiments that you get the right chemistry. But you could end up with 300 tons of the wrong chemistry steel which you got to downgrade or even re-melt. Well John Chapman [Chipman] came along, and using the principles of physical chemistry — he was a physical chemist from Georgia Tech, and he came up here and applied those same principles of physical chemistry to high temperature physical chemistry, not aqueous chemistry which is what the chemists were doing in water baths. He basically applied the same principles just high temperature glass slag baths and steel and stuff, and figuring out how the elements partition between the slag phase and the metal phase. And so now we can hit those chemistries right on. You know, you get one bad chemistry out of a hundred heats today, whereas in the old days you probably get 10, 20, 30 bad heats.

p47 41:05

So that's one of the things about productivity okay. If you go in the Chipman room you'll see, you know, Benjamin Fairless Works award okay. World's largest steel mill at the time was the Fairless Works of U.S. Steel. Anyway so they take that, and then there's lots of metallurgy that goes into — this is the tundish where this stuff is flowing around and it's coming down and it's going, these are the water cooled copper molds. You got solid flux liquid, you got a vibrating copper wall, it's contracting, and you actually have the molten zone is here. You're actually using hot solidified steel that's being supported by rolls, and sometimes you'll have a breakout. This little continuous caster you see here is about 10 or 12 stories tall. It's a pretty good build size building. You want to build a continuous caster like this today, probably about 2 billion okay.

p48 41:57

But if you have a breakout you're gonna drop your whole tundish right onto the floor, just like they did at Copperweld. But the guy did it sort of intentionally because he was irritated with the jerk engineer okay. And there's all kinds of microchemistry that's going along in here, where you get solidification and dendrites and you get uh pushing of the inclusions and anyway, there's tremendous amount of technology that's been developed in the last 50, 60 years. But most of it was developed between the 1940s and 1980s. There really hasn't, once they lost their productivity in the steel industry they started closing the research labs. And steel research did go down, there weren't any jobs. Now they're coming back, and they want to hire students, but there's no students, everybody's working on semiconductors.

p49 42:53

Student: [inaudible question, likely about the vibrating copper mold]

p50 43:00

Because you don't want it to stick to the walls, because you're trying to get it to move through there, and so you vibrate it. Uh, you have to, you don't want it, and basically you don't want to weld to the copper wall, and you want to reduce the wear on the copper. That copper's got to last for about three or four years before the shutdown. I mean the Japanese have run continuous casters for well over a year without shutting them down okay. So you run 24/7 for over a year. And you gotta, these things have to be fairly robust okay, and so vibration is one of the things that —

p51 43:33

Student: [inaudible follow-up about space inside the caster]

p52 43:36

Is there a lot of space? Oh, no there's, well no not doing — well hopefully, you've got these water cooled copper molds. This could be 10 or 20 feet high, and you're going to have built up a skin on here that's going to be half an inch or two inches thick depending on your casting speed okay. The actual only contact is just up in here. Hopefully it's cooling away and you just got radiational cooling here from the cold water cooled copper that's helping grow that skin. And one of the reasons you can bend this thing so easily is because part of that, the first part, it's basically got a liquid core. And if you're not careful about the radius of curvature and the speed of casting, you can have a breakout, and all that liquid steel falls down through everything else, and that's probably a hundred million dollar loss okay. So they got a lot of control algorithms and everything else. They got a lot of incentive to run it as fast as possible but not too fast okay. A lot of technology, a lot of experience there. Breakouts are not very common. They're probably not more than, not more in one breakout in the world every year or two today.

p53 44:51

When they first started doing it in the 1960s, a lot of people saw, no, that process will never work okay. Well some people said hey, going from 65 percent yield, and you know pounds of steel produced per 100 pounds you know cast, to 97 percent is a big enough increase in profitability that they were willing to bite the bullet and do it. American steel companies, no, they were too conservative. Board of directors were not willing to take a risk. It was people who were willing to take a risk, but some of those people were in foreign countries where the government was backing up their risk okay. So it wasn't exactly, it's sort of like the whole Airbus Boeing type of controversy today, of how much is the government supporting both of them.

p54 45:39

You know in the United States, well we don't support Boeing. Bo— you know how much money Boeing gets in defense contracts every year? And you don't think that they're doing some of that as a way to support things? What about the new Air Force tanker program, which basically went to a consortium that included Airbus on the first bid, but then all the congress, all the Boeing people go in there and start yelling to their congressmen, they just forced the Air Force to reopen the bid. And guess who won that time? Boeing okay. Now Airbus is pretty much directly okay uh subsidized, and they're always having fights with each other about how you're illegally subsidizing your aircraft industry. It's tremendous export industry. What's Boeing today, 40, 50 billion dollars a year worth of exports, and fairly profitable in general?

p55 46:35

Student: [inaudible question, likely about whether Boeing is always subsidized]

p56 46:35

All the time. Yes, basically, I mean yeah, half of Boeing is government contracts okay. So you know, yeah we don't really subsidize in the same way. We just subsidize in a different way. But our subsidy is okay, we say. The Europeans say no it's not. So anyway, these are some of the externalities right. So it happens in lots of industries, and then you know it was a real problem for the American steel industry in the 1980s, because everyone had convinced congress that the Japanese were not dumping steel, and then the Romanians, and then the Koreans in the United States, and now the Chinese okay. They've been fighting this for 40 years.

p57 47:25

It turns out that yes, the American steel industries were losing a tremendous amount of money in the 1980s, but the reason, I showed you these plots before, the productivity had doubled, the consumption was constant, the employment went down. Well that was because productivity, they went to BOFs from open hearths, they went to continuous casting, they did a number of other things okay. They built mini mills, and mini mills could use 100 scrap.

p58 47:54

In the old days, before the mini mills, let me turn it upside down, uh, they could, they had to use 70 virgin iron ore to make the steel from the cast iron, and only 30 percent scrap in that BOF. Well an electric furnace can make the steel um out of 100 scrap. And you can use John Chipman's principles to purify the scrap to get the chemistry you want. It's a lot harder in aluminum because, it is your question about how much can you burn out all this carbon before you start burning away iron. Well if you start burning away iron, you're going all the way back to iron ore, and that's not what you want to do right, it's a lot of wasted energy to go full circle. Well in aluminum, you'll burn up the aluminum before you burn out the car-, the copper and these other things. In steel, you can basically burn out a lot of these things. Certain things you can't burn out, bismuth out of steel. You get bismuth impurity in steel and it goes to the grain boundaries and produces a brittle product.

p59 49:00

And you know, and everybody 15 years ago people were trying to get lead out of solder, and they're still trying to get lead out of solder. And I go to these conferences and they say oh well we've developed this bismuth alloy. I said that's great, so you're going to start putting a number of pounds of bismuth in every automobile, which means we will no longer be able to recycle steel automobiles. That was dead on arrival, but these metallurgists that were working on solder, they didn't know anything about steel making, and they didn't realize that nobody was gonna put bismuth alloys into the soldering on an automobile, because you can't, that you're gonna now have to go out there and separate the scrap okay. You can't just shred up the automobile and dump it into the furnace, you gotta have to separate it out. Now we have, we separate out some things, we take out the airbag explosive because that has killed people in some of the steel mills when they're shredding, you know, shredding it and all of a sudden, got this explosive and you got this piece of shrapnel goes right through someone's arm or something. Um so they do go in and do some things, but you can't start ripping all the wires out of that thing, you couldn't afford to recycle the steel.

p60 50:10

Well what happened in the 1970s is people like Gordon Forward and Ken Iverson realized you could buy scrap steel at 100 a ton on the open market. In the world there are millions of tons out there okay. Cast iron cost two hundred dollars a ton. So you had a fifty percent advantage. You had a hundred dollar a ton advantage on something that sold for four hundred uh dollars a ton. You had a twenty five percent cost advantage to use 100 scrap. Except the quality of the scrap was not very good because it had all these alloying elements, and about the only thing they could make was reinforcing bar concrete, you know, steel concrete reinforcing bar. Just has to have 60,000 uh strength and be the right diameter, and that's about all. We don't have to have toughness requirements because let's face it the concrete has no toughness, so you put the steel in, it's tougher than it was okay.

p61 51:07

So, you could make rebar, but rebar was the garden variety low quality stuff. And when that is, Bethlehem Steel, the manager, "we don't care about mini mills." Well this is what Clayton Christensen made his name for at Harvard Business School, on the innovator's dilemma okay. Here you have these little mini mills, and one of his sections, one of his three examples, is steel mills, steel technology. My daughter worked on researching things for him one summer, and I'm a reference in there on what it cost to build a steel mill. Rebecca came home and said, "Dad, Clayton wants me to find out what it cost to build a steel mill and I can't find it anywhere." Well this was like 1995 and no one had built a steel mill since Bethlehem Steel in 1965. It had only been countries that had built it, and so it was all mixed in with the country, you know, the government finance and everything else.

p62 52:00

Well it turns out about a year before, I'd been sitting in a Saginaw Michigan airport with one of my graduate students, and we'd sketched out, I just sketched out on a piece of paper the approximate cost of an integrated steel mill, a mini mill, and a micro mill okay. In a mini mill you could build for like 100 million dollars. A integrated steel mill was 15 billion was my estimate. It cost Bethlehem Steel in 1965 5 billion dollars. That was their whole year's gross product okay, and they almost went bankrupt. But by the time they hired me, it was the most profitable year ever, that's why they could afford to hire me right. But they almost went bankrupt in the previous six or seven years.

p63 52:46

No one could take on a five billion dollar investment back in the 1960s. That's like Intel taking on a 15 billion dollar investment today, or Boeing a 15 or 20 billion dollar investment. These companies are betting the farm on these, you know, building a new 787 Dreamliner or a new computer fab and things. Other countries, it's the whole country, and there's never been an integrated steel mill built since Bethlehem Steel Burns Harbor by a company. Been plenty of integrated steel plants built but by countries doing the financial backing. No private investment eating a 15 or today probably a 30, 20 or 30 billion investment for an integrated steel plant.

p64 53:30

Anyway we're going to run out of time, but so what they did at Chaparral Steel — Gordon Forward is a graduate of this department, he's a Canadian, he's retired in British Columbia now. But these guys, they sent their own employees out with sales. Every now and then, if you were a employee at Chaparral you had to go spend one week a year with the salesman in the field to find out what the customer wanted. Hey, what a unique thing. And they found out that the smallest diameter rebar, three-eighths of an inch, got like a 20 or 30 premium because you could only go so fast through the rolling mill. So here is what they did. They first they came back said we're gonna roll faster, we're, to we're going to sell more 3/8 inch, we're going to take over the 3/8 inch rebar market because there's more profit there. So they tried to go faster.

p65 54:17

Well, this stuff is going through there 60 miles an hour okay, and if you go faster you get instabilities, and all of a sudden you've got hot band steel that breaks and goes whipping around. If someone's there, cut your arm right off. My second child, my oldest daughter Rebecca, was born in the hospital in Bethlehem Pennsylvania, beautiful hospital because they sent maine [maimed] steel workers down there every day okay. Just cut your arms right off okay.

p66 54:45

Anyway, so they tried to speed it up for a while, and finally they said no, we're doing it the wrong way. We shouldn't try to speed it up, we should try to slow it down. And what they did, they slowed it down, and here it's coming into the rolling stand as one bar and it's coming out as two bars. They split it in two. They had to go slower to do it, but they got twice the productivity out right, at a slower rate, which is like a 50, well, hey, they did that once, they decided they could do that again. And here you see, oops you don't see anything. You see two bars coming in, and you look down here and you see four bars coming out. They did it twice. And so they're running this mill slower, but they're getting four times as much product through. So they took over the 3/8 inch rebar market. Yep.

p67 55:38

In fact, I'll tell you about that tomorrow. The quality actually went up okay, and that was another benefit. But that, they really did, they proved that in I-beams, and that's the rest of that story okay. Less than a year. You can read about it actually, not in this book, but there's another book that I actually was involved in reviewing Chaparral Steel's product development stuff with the guy Steve Wheelwright, Harvard Business School. So you can read about it if you're really interested. It was written up.