§1. Introduction and the refrigerator shelf case [00:00]
I'm going to be lecturing for Professor Eagar today. My name's Brian Holman. For my background: I worked for a consulting company the past five and a half years, and I just started my own consulting company recently. A lot of what I do deals with materials failures, and a lot of the issues sometimes involve material substitution. So that's going to be the topic of today's lecture.
The first example is a refrigerator. I was talking with Professor Eagar about this yesterday. When he was a child, refrigerators were made strictly out of metallic components. In our lifetimes we're starting to see they're almost more like computers — some refrigerators now have cameras and things built into them, a lot more electronics. So you've seen this change over time.
One of the main material substitution issues that happened years ago was when they switched from metal shelving to plastic shelving. What they initially did was say, all right, we're going to mold this out of plastic and stick it in, and it'll save us a ton of weight. One of the things here is that when you're working with a system, you can't just look at one property or one particular aspect of the system. You have to look at everything as a whole and how it interacts.
So what happened when they switched from metals to plastics — and there's a lot of case studies on this — was they were getting a lot of cracking in the plastic shelving. If you think about thermal expansion, thermal contraction, and the stresses when things are joined together and constrained: when it was all metal you didn't really have an issue, because the materials expanded and contracted at the same rate. However, when you make this out of dissimilar materials — metallic slides here and plastic shelving with a metallic outside to it — now you're adding all these other stresses to the system while it's in service.
Because you're constraining the plastic by the metal piece, you're getting stresses on the plastic while it cools and when you open the doors. So a lot of these plastic shelves were cracking because of the material substitution.
This was an issue where the designers didn't take into account the full picture. Yes, it's going to save weight, plastic is not as dense as metal, it's cheaper to produce — but when you put a component into service, you have to look at the whole array of functionality that it needs to provide. What was overlooked in this case was that when you have dissimilar materials joined together, you're going to create stress concentrations. The plastic is joined to the metal, and these things are expanding and contracting at different rates in service, and you get cracks over time.
Student: [Inaudible question about working at a refrigerator company.]
Did you have any issues while you were working there related to cracking of components or dissimilar materials?
§2. Conveying water and gas — historical material substitution [04:20]
We have other examples. This happens when you talk about gas lines, water mains, and actually conveying material from one area to another.
When you have competition between different materials — Professor Eagar discussed the economies of these different materials, steel versus aluminum, in terms of mass tonnage and how much manufactured components of each are made per year. But when you're choosing between a metal or plastic or glass, you have to think of the whole array: the environment the component is going to be in, the unit cost you want to produce it for, weight, brittleness, impact resistance. So you have a whole suite of mechanical properties to keep into account.
The example everyone knows is food containers. If you've ever seen a 1950s Coca-Cola bottle, it was made out of glass. That's because the technology for polymers wasn't around in the 1940s and 50s to make them out of polymeric materials. But as the technology matured, you can see there's a competition: the issues with glass were that it was heavy and it was brittle — drop it, it breaks into thousands of pieces. Change to a polymer, it's impermeable, it has more resistance, and it's a lot cheaper to make.
One thing you may notice with your water bottles over time: they're trying to optimize weight savings, and they've actually made the plastic thickness thinner. They've had failures happen during transportation and packaging because they've made them so thin. These things happen when you're substituting from one material to another, or from one design to another of the same material. You have to take these things into account: transportation, ease of use, recycling, composite costs, corrosion.
When you have your soda can — Dr. Eagar talked about how soda is basically phosphoric acid. So you have to make sure the soda wouldn't react with whatever material you place it in. You wouldn't use a carbon steel soda can. You use something with a little more resistance.
Material substitution also happens over time. One of the best examples is the conveying of water. If you look at the top left figure, clay pipes in 4000 BC. Why did they make them out of clay? Because that's what was available. You didn't have steel mills, you didn't have factories. So some of it is the product of the era you're in.
We talked about the aqueducts, the Roman Empire, how they changed into more concrete-type aggregate structures over time. Then we got into the period where they transferred from concrete to wood and cast iron. Today you're seeing these large cast iron pipes — or ductile iron pipes — in a lot of these major cities. They're 100-plus years old. One of the things that happens with cast iron over time is it can become embrittled, and you can get stress cracking and issues just by it being so old.
As infrastructure ages, now they want to go in and put in the latest and greatest materials. They want to switch to more polymeric-type materials as well. So there's a competition between what was in the ground and what you're putting in the ground. If you're going to switch from a ductile iron pipe to a polymeric pipe, you have to take into account the environment it's going to operate in. The soil could be acidic, depending on the location in the U.S., or there could be trace elements from factories in the soil itself.
That's the environmental factor, and you also have to take into account corrosion resistance. Polymers will have very good corrosion resistance generally. Then there are heat and temperature issues — how hot, what type of water, is it ambient? This is not just for transmission, this could be going into your house plumbing connections. So the conveying of water is a good example of how we went from different materials, starting in 4000 BC with clay pipe because that was the technology that was available, to a concrete aggregate type material, stones, to wood, and then later on cast iron, ductile iron, plastics.
In addition to conveying water, another example is conveying gas. The image up here is wood. Years ago they used to hollow out wood trunks, and gas would be transferred inside. Who can think of some issues with wood over time and having a combustible material flowing through it? But in the 1800s, when they were first getting things started, that was a main issue.
Now we have fractures, different types of gas pipes. You can have plain carbon steel — you've probably seen in the news, hundred-year-old pipes that break and cause a major inconvenience. So the issue is, once it's in the ground, are you going to maintain it, are you going to leave it in place? You don't want to have to dig this stuff up every five years to inspect it. As you substitute from one material to another, how are you going to inspect this over time to make sure it's still functionally and structurally sound?
§3. HDPE gas pipe and plumbing substitutions [12:13]
After we go through these few slides that Dr. Eagar put together, I'm going to show you some examples on how you can test the component and determine its mechanical properties. We have a whole bunch of examples here on pipe. This is for gas — a plastic HDPE, high density polyethylene pipe. They're now using these types of pipe in the ground in various locations rather than metallic pipes, either carbon steel or whatever. They've gone to these plastic pipes because, for one, they're easier to fabricate in the field.
I had a job a few years ago where they asked me to look at this style of HDPE pipe. It had fractured, and they wanted to know whether it was an issue with the pipe or something that happened during the production process. For that job, they had thousands of feet of this pipe out on a barge on the Hudson River, and they were actually fusing it and running it under the river in place. This is something you couldn't do out on a barge with metallic pipe. The flexibility is what allowed them to bore through the hole and tug this along behind. The reason they could do that is because the joint is a fusion-welded joint. They heat it up and press it together, and they fuse it. They continually feed this off the barge while they're pulling the pipe into the ground.
So for a contractor or somebody who's installing it, this is a lot easier than having to do piecemeal welding with a metallic component. If we're talking about pulling something under a river, how are you going to dredge a river? So you're starting to see more plastics because of the flexibility it provides when you're installing it. But there are some issues. Have there been any studies to see how this will be a hundred years from now? Generally this stuff is not — you can do an accelerated test, but you have to make some assumptions, and these haven't been in service. They've probably only been using these maybe 10, 15 years. So as with anything when you start to substitute a material, there will be unforeseen environmental conditions and field conditions, and we'll see how the material responds over time.
Another example. Professor Eagar gave me this yesterday. He's having a renovation done on his house. Have any of you ever done any soldering, either jewelry or things like that? Everyone has plumbing, and years ago all the plumbing was joined together by lead-tin solder. Over time there were environmental restraints on the lead. You've probably seen all over the news, all the people up in arms over the lead in school drinking water — that's a result of the pipes having lead joints. And they probably actually had lead in the composition of the pipes, they're so old.
The plumbing used to be lead-tin solder connection. Then they wanted to get away from the lead and the tin. The EPA or other government agencies said you can't use certain fluxes anymore. So they moved to different materials, but those materials had their own issues. They didn't form as good a joint, so you got more leaking, or they became brittle at higher temperatures. Professor Eagar gave me this and said it came from the remodel of his house. Now what they're doing is almost like a swage connection, where you don't even do a solder joint anymore. It's a swage where it locks into place. This would be for your plumbing connection going in your house to either your sink or things like that. So now they're trying to get away from even having to do any soldering.
One of the implications — we talked about externalities and costs — at least where Professor Eagar lives, in Belmont, if you want to solder, you have to get what's called a hot work permit by the city. With the hot work permit, if you're doing welding or things like that, there are sparks, so you have to get a special permit to do the work. The other thing you need to have is what's called a fire watch. So there are cost implications as well. You need to have somebody from the fire department, and you have to pay them, when you're soldering these joints — versus saying, I can go buy this at Home Depot or one of these major retailers, and all it is is a snap connection, and leave it in place. Cost really is the driver for a lot of the construction and joining activities.
§4. Corrugated stainless steel tubing and battery thermal runaway [18:28]
The next one is what's called corrugated stainless steel tubing, CSST. This was an issue because a lot of home contractors wanted to get away from black iron pipe. This is what used to be a threaded pipe — the gas connection to your house. The gas would come in through a black iron pipe. One of the reasons they wanted to get away from it is because the CSST is more flexible. Rather than having a threaded connection with elbows and tees, they could use this material which has some flex to it.
So there was a switch between materials. But what happened was, they started to see houses burning down. The reason some of these houses were burning down was that when they manufactured this material, the wall thickness and the sheath insulating it weren't sufficient: when houses were getting struck by lightning, or lightning was hitting the ground, the energy was enough to puncture the wall. So now you have a gas line, you have a source of combustion — the lightning strike arc — and you have a wall thickness thin enough to be punctured by the lightning strike.
What you're seeing here is actually taken from a site where they had a puncture in the line and a fire resulted. So when you substitute materials, you don't know whether a designer took everything into account. If I'm switching from this to this, the wall thickness is going to be critical, because you can't have a material in your house where there's a chance it could go up in flames if it gets a lightning strike. If you watch TV, some of the commercials over time — you have recalls, whether with automobiles or other things. A lot of times the recall is a result of a material substitution or design issue where you switched materials.
Student: With the high-priced iPhone 7 or the Note?
Yes. And not only that — I've worked on some cases where you have phones catching on fire, but a lot of people do the vape pens. They think it's a safer alternative to smoking. The vape pens have the same issue: they can spontaneously ignite. You get what's called thermal runaway on the battery.
Does anyone here work in batteries? With your battery, you want the energy density as high as possible. We talked about these Ashby charts, where it's two different properties and it's a trade-off. So you want to get the energy density up. Do you want to talk about some things you've seen in terms of fire protection or charging-discharging—
Student: [Inaudible] basically start charging a battery too hard [...] sort of a self-healing process where the metal just gets hotter [...] and at some point you have an ignition in there.
Yeah. So one of the things I read in the news was Samsung's response when they recalled, whatever, 1.2 million phones — to tell consumers don't charge it past sixty percent. That ties in to keeping the temperature down so it doesn't get so hot that you'll get combustion.
One of the other things I've seen is with glass — battery casings, and structural glass. I've worked on glass failures on a lot of structural glass, like panels on large skyscrapers. There are issues there in terms of glass breakage, because what you have with glass is called an IGU, insulated glass unit. Generally it's more than just one panel, it's multiple panels tied together. If you think of that as a composite, like a sandwich, you have a small gap space between the IGU glass layers.
What designers have done by trying to optimize is make that gap layer smaller and smaller. But what's happening — you've seen in some buildings — when the sun hits in the morning, you get thermal expansion and it gets hot in those layers. Because the design has tried to minimize the whole unit thickness and weight, you have such a small space that's getting hotter and the heat can't diffuse out, and you get thermal stress breakage.
I've been on sites where you've seen panels shattered. Now they tie them in with an extra so you don't have panels falling 80 stories down on people — it's a life-critical component on the curtain wall. But you have to think in terms of the whole system: temperature, the emissivity of the glass. You want to get environmental credits on these large skyscrapers — this can be millions of dollars by using a certain type of glass versus another. But if you then have panels breaking, in the long run is it worth it or not?
§5. Rail inspection and the forging burst case [25:29]
I wanted to spend the second half of class today talking about some projects I've worked on — not just material substitution but inspection and testing of structures. How many people take the T? I take the Red Line in every day. We talked about the size of the steel industry, and how trains aren't running on a maglev here. The miles of steel that train systems around the U.S. run on, it's enormous.
What happens when you have steel that you have trains running on daily, and you have to leave it in service 80-something years? Has anyone ever been inconvenienced by a train issue? When I take the T, I look at it from a maintenance perspective. I've worked on train derailments where you actually see the fractured rail afterwards. With trains you get a lot of fatigue issues with the rail, because the train truck is running over it. If you think of your train system: you have the rail, then the ballast underneath, which is your concrete and aggregate, allowing water to drain out. This is a structure where hundreds of thousands of pounds are being transported over the steel.
There is some flex to the steel. I've seen on some rail systems where you have cracks, and you can actually see the fatigue crack has grown because of all the cycles. So you have to be able to go in and inspect. The transit agencies have a system they call a Sperry car — a car with an ultrasonic sensor on it. At night when the trains aren't in service, it runs over and looks for indications in the rail to see if you have cracks or not.
[Holman passes a section of rail around the class.] The example I'm going to pass out is not from a commuter rail, so I don't want you to think somebody was driving on this. This was from a crane rail. It was out on a barge — it was a turntable, and a crane moved over it and did dredging operations. I got a call one day and they said, we need you to come out here, we can't run the crane, the rail broke. So we flame-cut the section of rail out that I needed, and when I came back to my lab and cut a clean section through it, I saw this.
Do you think this should have been here? What this is called is a forging burst, and it happened during the manufacture of the rail. A lot of times you have molten steel, you need a refractory when you're manufacturing it. Chances are some of the refractory fell off — some of the brick casing that keeps the heat in the steel when the steel is molten. Pieces of it fell off, and when the rail was getting extruded out, this area never melted because you had a refractory there whose melting temperature is above the process temperature.
One of the things that should have been done with this rail — that I don't know if was — before this rail gets put into service, you should do what's called UT, an ultrasonic inspection. The ultrasound is the same as if a woman goes to a doctor and she's pregnant — it deals with sound waves, the same as your sonogram. For ultrasonic inspection, you use a couplant material, and you check the consistency with sound waves. It goes through, and you would have gotten an indication that showed this was here. But this got put into service, so ultimately they had to replace that whole section.
§6. Tensile testing and wire rope failure [30:23]
Some other examples. You have huge pressure vessels and pipelines. Over time, if you want to see the integrity, how the steel is holding up, you can do mechanical testing. How many of you do mechanical testing in your research? Compression tests, tensile tests? This is a structural materials class. When you're dealing with steels and thick-section structural materials, your Young's modulus, ultimate tensile strength, elongation — these are all properties that for the most part are going to be most critical for structural applications.
[Holman holds up a round bar tensile blank.] When you're doing tests, you want to take samples and test. This is a blank for a round bar tensile test. This would go in a testing machine. It gets threaded into the grips, and you pull it. This will neck down over time, and it'll tell you what your tensile strength and yield strength are — to tell you if the raw materials, once fully fabricated, are as strong as they're supposed to be. For any skyscraper or any large structure, you want to test the metal to make sure the quality is what it should be.
One of the students the other day asked about wire rope. So the same as you can do a tensile test on this material and watch it neck down — I'm going to show you a video of a case I worked on a few years ago. It was off a cargo container ship. They have wire ropes for lifting huge amounts of weight onto the container ships. One of the wire ropes fractured, and they wanted to know if it was a material issue.
[Video does not play.] I'll have to show you this way. One thing you'll see here: this testing setup is three stories high. Maybe I'll just pass this around afterwards. The machine that was actually testing this was three stories high, and the rope section itself was probably about 12 feet. This rope was about an inch and a half, two inch thick diameter. The way they braid the metallic wire rope makes these things extremely strong. We tested this, and it broke at over three hundred thousand pounds — three hundred ksi when it broke.
I don't know why it's not playing — it's a movie video. There are YouTube videos out there that show wire rope tests at the manufacturers. This was the one I performed. The setup was vertical, three stories. At a lot of manufacturing facilities you have size constraints, so they set it up horizontally.
§7. Charpy impact testing and metallurgical mounts [35:25]
Another type of test we have to do — we talked about fracture toughness — is a Charpy impact test. [Holman locates a Charpy sample.] If you have a pressure vessel or any critical component, you have to make sure that if it gets a crack, it's not going to brittlely fracture. This was developed around 1901. You'll see how simple a test it is, because in 1900 you didn't have computers and couldn't do crazy simulations.
This is a test where you have a swing, you put your Charpy sample in the holder, and you can do this at different temperatures. You can put it in a bath, let it sit for ten minutes, take it out, and test it. You test at different temperatures because impact toughness is a function of temperature. You have to make sure you'll have impact toughness throughout the range of temperatures you're operating in. You set the sample in, swing the hammer, it breaks, and this is what the fracture surfaces look like.
There's a specification group, ASTM, the American Society of Testing and Materials. They come out with these standards. There's an ASTM standard for how you run this test, so when different labs run the tests, it's an apples-to-apples comparison and people aren't just reporting whatever results they get. If you're putting a structural material in service, you need to meet certain impact toughness, fracture toughness, and impact strengths. This is the test you'll do. This is a blank for it.
If you look on that, there's a notch. You notch it in the center so it breaks there. The direction — if we're talking about pipelines or other structural materials, which orientation you notch will have a big effect on what value you get on your Charpy test. That ties in to the rolling direction of the steel, if you're going along the grains versus against the grains.
[Holman holds up metallurgical mounts.] One other example — these are metallurgical mounts. When you have something that breaks, in general you want to look at the fracture surface. When you're dealing with big structures, you have to section out something you can handle. Normally when you're looking at a structural metal, or doing a metallurgical eval, you would mount it, polish the sample, and look at it under the microscope.
What you'll see here is some indentation. You can do micro-hardness tests versus macro-hardness, to see if the hardness is in line with what it should be. That ties in to your heat treating of the material, annealing, things like that. I actually use these to show what not to do when you're making the mount. You can see there's a huge cloudy area in here. You have to mix the stuff right, and let it set. These are cold mounts, which are epoxy-based. You put your material in flat, you mix this two-component goo, and let it sit for four hours, and you've got a clear mount. Or you can do a hot mount where you do it under temperature. So these are various mounts from samples.
§8. CT specimens and crack growth in aircraft [40:05]
The last one I want to show you is a CT sample. Sometimes you want to know how a crack will grow over time. Airplanes — they know they're going to have cracks in the wings, but one of the things they want to know is how that crack will grow. On the wings of airplanes, they're designed to withstand cracks. There's a critical crack size — but that's the old airplanes that had rivets and things like that, more aluminum frame. Now that you have composites, the issues of cracking on a composite are a lot different than aluminum, between a carbon-carbon. If you're looking at the Dreamliner versus an airplane from 30 years ago, there are going to be different issues in the design.
If you're dealing with aluminum airplane structure, what you would have done is — this is a CT test. This has the notch in it. You put it in, you cycle it, and you can actually track the growth of the crack with the cycles. That's something you want to know, because every time you go on a plane you have a pressurize-depressurize cycle. This goes into fracture mechanics and some other things that Professor Eagar or Dr. Bellmehra will talk about. When you're talking about fracture mechanics and crack growth, you need to understand the rate at which these things grow. A lot of times the design philosophy, in some of the industry, is "leak before burst." You want to design it so it's not a catastrophic failure, so that you can go in and maintain it before critical fracture occurs. So this would be a CT sample.
Student: [Inaudible question about computer simulation versus physical testing.]
A lot of times you'll do the actual mechanical testing hand-in-hand with a computer simulation. The ASTM standard, or API, or whichever standard your material has to conform to, will tell you minimum acceptable limits. The first thing is, you run the test — does it meet that? Then you would tie the values you get into a simulation if you're trying to predict either crack growth or properties over time, creep, things like that. So there's a whole suite of properties that need to —
One thing is, full-scale physical testing costs a lot more. The video of the wire rope — that's a huge structure. The largest one I've seen is at Lehigh University, and it's a five million pound load. They were doing full-scale bridge sections, testing them to failure. These are very expensive. It costs a lot of money to make a mock-up, to use the equipment. So yes, you want to do as much computer simulation as you can, but at some point you have to benchmark it against an actual value to make sure you're not putting a false assumption into your model.
A lot of times I get involved after the fact, after something's already broken, and it's a question of, was this material up to what it should have been while it was working? — to try to find root cause on why it broke. You can do similar tests on plastic. Plastics operate off of a Shore scale — a different hardness scale, with different values, but you can also do this for plastics. If we were looking at the bulletproof glass that Professor Eagar showed the other day, if you wanted to make sure those polycarbonate layers were what they should have been, you can do impact-type tests on that as well to see what values you get.
§9. Navy sandwich structures and closing Q&A [44:54]
The only other thing I'll end with today: Professor Eagar talked about the Navy and trying to reduce topside weight. [Holman holds up sandwich-structure samples.] These were a couple samples from back when I was doing my master's thesis. One of the things we were looking at was, could the Navy use sandwich-type structures or composite structures with different materials rather than just monolithic pieces of aluminum on the topside?
We looked at these different structures. As Professor Eagar said, you have to look at the whole array of properties. We were getting very good compressive stresses with these — they could withstand good compressive loads — but one of the problems when you're dealing with these is bending loads and shear, and also joining. These are foams. This is what's called a closed-cell aluminum foam; this is open cell.
What we were doing was a so-called dip brazing procedure: you put it together, dip it in a molten bath of sodium fluoride, take it out, clean it off, and then it's all joined together. But it's extremely cumbersome. You have to think — if the U.S. military had an issue where they had to maintain this, how are you going to repair these things in the field? These are great novel, boutique-type materials, but you have to think about maintenance, repair, replacement.
Does anyone have any questions?
Student: [Inaudible question about whether ultrasonic testing of the rail takes samples.]
For the rail, it doesn't take samples. It shoots sound waves while the inspection car is rolling on the track. With ultrasonic sound waves, you have decibel drop. When you're looking at the data, if your reflectance of the sound wave hits a defect, you'll have a drop. That would be your indicator to go in and do a more precise inspection.
You can always do multiple inspection techniques. Some aren't applicable to every material. You have what's called magnetic particle tests, but you can only do those on a material that is magnetic — so not on a polymer. You have eddy current testing — a lot of times on heat exchangers you have these really long 20-foot sections of tubes for cooling, you can do eddy current because it's nice and quick. The same issues you have with material selection, you have with material inspection. What's the depth of penetration you need to see the defect? Is it a surface defect, a volumetric defect? There are multiple inspection techniques in the field to try to make sure you can see if there's a problem or not.
One more question.
Student: [Inaudible question about applications of aluminum foam.]
They say some of that might have been used on a space frame because it's so light — as a fall on the space shuttle, I think, was one of the uses they called out. I don't know if they're actually doing it though. Dr. Bellmehra will be giving you your lecture tomorrow. Thanks a lot.