§1. Schedule and catch-up cases [00:02]
There's no class on Tuesday — it's an MIT holiday — and I have to fly back to Southern California. I just got back on the red eye, I have to go back. I'll be back on Wednesday on the red eye, but Dr. Belmar will lecture on Wednesday. Everybody's watching different videos, so you can watch your videos or skip things however you want. I should be around to lecture Thursday and Friday.
I wanted to catch up on a couple of things. I have to apologize — I was using my old lecture notes, and I found my newer lecture notes this morning. I talked about the Alexander Kielland disaster. This is the Alexander Kielland offshore platform. It's 50 meters across — half a football field — and 81 meters in the other direction, almost 90 percent of a football field. If you looked at the legs a little closer, this was the hydrophone. You have big columns of legs, then cross braces, and they put this piece on. It was 325 millimeters, about 10 inches in diameter. So that's 10 inches in diameter, and it looks like a little thing on this structure, so you can tell these things are pretty good size. At the time it was one of the largest offshore oil rigs — this was probably early '70s. It's not the largest anymore.
For the critical structures — what they thought were the critical structures — they had all kinds of quality control in place to make sure they didn't screw up the welding, that they used the right electrodes and the right procedure. But this hydrophone was just an attachment, and the maintenance department was charged with doing this in the French shipyard. They went and got a piece of pipe. This piece of pipe was like 1060 steel, very high carbon, which is difficult to weld. They welded it, and afterwards they had fatigue cracks. This is the hydrophone and this is the bigger pipe it was welded onto. The crack ran almost all the way around before it finally let go. You lose that cross brace between the legs, then you lose one of the five legs. This was a tremendous storm, the whole thing goes down, and 220 people I think lost their lives.
The Norwegian commission that looked at it spent most of their time talking not about the failure but about the lack of safety equipment. They did have a few boats — boats that have covers on them, like getting in a clamshell, and it doesn't matter if it flips over because it's watertight, and you ride out the storm no matter how big it is. But they didn't have enough of them. This platform had been designed as a drilling platform, but they'd converted it to a hotel, and they didn't increase the number of life rafts. There's another one of my lectures where I go through one in Brazil that was very similar a few years later, with some of the same safety problems.
Another one is the Comet aircraft, in the middle of the 1950s. Anybody hear about the Comet?
Student: Yeah, low cycle fatigue.
It was low cycle fatigue, but the problem was, they were falling apart in the middle of the Atlantic, and no one could get the evidence to find out what was causing it. They just break up in the middle of the Atlantic Ocean, and there's no evidence. Finally Alan Wells, who was head of the British Welding Institute and a fracture mechanics guy, looked at it and realized the windows were square.
Student: They had a big water-filled tank, they pressurized and depressurized it for months, and they actually grew the fatigue cracks from there in one day.
Yeah. It's not all that different than Aloha Airlines, except Aloha was 37,000 cycles, because you were in Hawaii and it was all 15, 20, 30-minute flights from island to island. The plane had 40,000 hours, where a typical Boeing aircraft would go 100,000 hours. But in terms of ground-air-ground cycles — takeoffs and landings — it was 250,000 hours equivalent compared to everything else in terms of low cycle fatigue.
So with the Comet, it was a stress concentration at the corners. If you fly an airplane now and look out, you'll never look at the window the same, because they have rounded corners. They learned about stress concentrations, even though stress concentrations had been known going back to 1880, the first calculation of the stress concentration of a hole in a semi-infinite plate. Anybody know the stress concentration around a hole in a semi-infinite plate, if you pull it in tension? This was solved by some guy in 1883. If this is sigma, at the tip of that hole — just a circular hole — it's 3 sigma. So you get a three-fold stress concentration from a round hole in a semi-infinite plate. Actually it's an infinite plate, not just semi-infinite.
§2. Boston gas pipes and the geography of Back Bay [07:13]
When I talk about improving the reliability of joints — I had a case, and Boston Gas doesn't even exist anymore, they're NSTAR or National Grid now. If you go down to their training facility in the South part of Boston — not South Boston, the South part of Boston. South Boston is just east of Boston. The South End is east, the southeast is west of Boston, the North End is east — they go through all these directions and they're all mixed up.
Boston was out on a peninsula and the Back Bay didn't exist. Well, it existed as a bay full of water, with little isthmuses of land. You know why Beacon Street is called Beacon Street? Because you had a right to graze your cows — even today you can take your cow to Boston Common and graze it, it's in the law from 400 years ago. Beacon Street was a causeway across Back Bay so the farmers in Allston could take their cows to graze. It was a very narrow causeway, and you had to have a beacon on your cow when you brought him back at night so you wouldn't knock someone else off the causeway into the bay. That's why it's called Beacon Street.
Here are some pictures of things they dig up out of the Boston street. These are old gas pipes that were abandoned in the ground. This is just a cast iron sleeve with two pipes, and the whole thing is filled with oakum. This is a bell-and-spigot joint, also filled with oakum — they just stuff some old rope and tar in there.
Student: What about lead-sealed joints?
That didn't come along until around 1900, 1910. I've worked on water pipes that are lead-sealed that failed 90 years later. These were 1880s-type stuff. I wish I had taken a picture when I was down there — they had one that was even older, a wooden pipe. They'd just take a log. The original street lights — in order to pipe the gas down the street, they would take a log, gun-drill it, and put a hole in it. It might be a 6-inch diameter log with a 2-inch hole in it. You just hope it wouldn't rot away. They finally went to cast iron, and the cast iron lasts for a long time. Not that it doesn't leak at the joints, but that's another story.
You know what gun drilling is? If you try to drill a really deep hole, the drill will walk on you and go off to the side. Gun drilling — if you need to make a long hole in a gun barrel — you rotate both, so you average out any asymmetries in the force, the cutting action, the sharpness of the teeth. You can drill a very straight hole with a gun drill. So why on a lathe don't the tail stocks rotate?
Student: On a gun-drill lathe they do.
Right, that's the only difference between a regular lathe and a gun-drill lathe — the tail stock rotates on a gun-drill lathe. Not a lot of gun drills around anymore, but we do extrusions and other things.
§3. Stiffness and the sapphire surgical instrument [11:45]
Does anybody have any questions? I wish I had saved it — I remember reading it in some magazine — but the nano guys with the nanofibers, there was one group claiming they had strengths of 10 million PSI. That would be a bond energy of about 10 electron volts, if you remember my little scale. What two elements have a bond energy of 10 electron volts? None. There are physical limits, and that is an absolutely absurd statement. But some scientists will say, oh well, we're working on nanofibers, we predicted they have a strength of 10 million PSI. I haven't seen your prediction, folks, but your prediction defies all of known chemical thermodynamics.
One of you was working on micro-catheters? I should have brought my micro-catheter stainless steel piece. Does anyone have a parent or grandparent that has a stent in their heart? How do they get it in? They take one of the arteries in your leg, and they go in with this long stainless steel Teflon-coated tube or wire, and they're taking flash x-rays so they can see. They put a little bit of barium on the tip so they can see exactly where it is in your arteries. They're taking x-ray movies while they're doing this. This has been a great boon for the radiology doctors putting stents in. It used to be the surgeon did open-heart surgery. Now these guys do this much less invasive stuff. The first one they put in is a guide wire, and then they use that like a little trolley wire to bring other things in, and they eventually put the stent in.
Where was I going with that? Oh — stiffness. One of the problems with these, and also with arthroscopic knee surgery, is you're going in with very slender tools. When something gets slender, it wants to bend. The stiffness goes as the cube of the diameter, you remember that, right? In beam theory, a simple beam — he's a structural guy, you should have known it. It goes as the cube. So you cut it down, you make it slender by a factor of two, you just lost a factor of eight in stiffness. You want a nice flexible guide wire, but when you're doing arthroscopic surgery and trying to cut out the cartilage in someone's knee, you need something stiff.
Steel has a stiffness of 30 million, tungsten has a stiffness of about 60 million, molybdenum's about 50 million I think, sapphire is about 60 million. But 60 million is about the top — iridium might be 70 million, but it's pricier than platinum. There's only about a factor of two. A medical company came to me once and said, how do we get a stiffer part? I said, why don't you use sapphire? I still want to do this — you can buy single-crystal sapphire and it won't wear out very much, it's very strong, it'll hold its edge. You're going in there with this little thing that scrapes away the cartilage, and you want it to be thin so you don't have to make a very big slit in the person's knee, and you want it to be stiff so it's strong enough to do this nibbling. You can get a factor of two in stiffness if you went to sapphire. And do you know what happens if you add just a little bit of chromium to sapphire? It becomes ruby. Can you imagine selling surgeons sapphire and ruby instruments? They're color-coded, which is a wonderful thing — they like color-coded instruments. I never could convince them to use sapphire for making instruments.
§4. Friction welding and the blisk problem [16:43]
There are two fundamental reasons why something won't bond. I talked about friction welding as a sort of form of cold welding. It's not really cold welding. I found my notes, just out of the welding handbook. There is a video that should be online — I don't know if it's on my website, but there's supposed to be five or six videos, and one of them is a commercial video on friction welding. You actually get to see a friction welding machine run. This is the tooling, a simple circular friction weld, and it heats up really quickly as you spin it together. It's basically just a fancy lathe.
Here's the force-displacement. The welding starts — one is rotating, one is not — and there's the completed weld. You have all this flash. [Tom produces a friction-weld sample.] If you haven't seen it before, you can look at it. There's the flash. You have speed, force, and upset all plotted on different graphs. You accelerate to some friction speed, you start pushing the two things together with some force, that increases, and finally you jump the force to forge it together. You're making a hot forge weld, but in a sense it starts out as a cold weld, and you're using friction to get enough heat to melt down these asperities, because you have to break down the asperities and extrude out the contamination.
Student: What kind of tolerance do you need on the flatness of that surface — if it's off by a little it can kick?
A lot of people put a taper on it. They actually make one conically shaped, and I'll show you the reason.
Student: What if the end is cut off at an angle?
You have a machined end on these. You don't just do a sheared end — a sheared end would be terrible, very inconsistent results, because you're only heating up one area. But just trying to put two flat surfaces together doesn't work that well. Most people put a very shallow conical machined surface on it. You can see here — this is a bunch of them — right in the center I have no shear. As R goes to zero, the speed goes to zero, and you can actually see the heat patterns. You're not really getting a good joint right there unless you start with this cone. Then you have to vary your forging force. A good machine will do all of that. Some of these machines can cost millions of dollars. They make very good parts very quickly, or they make scrap very quickly.
This is out of the welding handbook and shows what you're doing. You've got a very rough surface, sort of like my little foam things, and you're touching them together, getting better contact. If you just do a straight normal force, you'll never get more than about one-third bonded area. You have to have shear. You have to plow these mountain peaks away. If you just squeeze down, by the time the base material starts to yield, you still have about two-thirds voids. Just a normal squeezing doesn't work. We'll get into that in more detail.
I wanted to mention three other types of friction welding. One is linear friction welding. This is circular friction welding — it's nice and easy to build a machine that goes in circles, but they would love to do linear friction welding. If you want to do some friction welding, you can do it with your hands — you feel your hand warming up. They would love to be able to make turbine discs for jet engines, where they weld the turbine blade to the substrate. Here's a regular turbine blade. The jointing is a mechanical joint, and they call this the tree — turn it upside down, it looks like a tree. This is ground very precisely. This is the most expensive part of the turbine, I think — $10 million grinding machine to grind these flats. You mount the whole thing in Wood's metal, a low-melting metal, to fixture it, because you can't clamp this precisely enough to get the tolerances they want. It has to fit into the mechanical sleeve on the turbine disc within a few tenths of a thousandth of an inch, otherwise at the speed it's going you'll get vibration and fretting wear. You have to be careful what temperature you assemble these at — a few degrees of temperature, you basically have to assemble these in a controlled temperature environment.
Over half the weight of this thing is the mechanical attachment. If you look at the turbine disc, most of the bad weight is out on the outer edges, the big heavy section. It looks like a railroad wheel, with the outer edge being large. If the value of a pound saved in an aircraft structure is $200, the value of a pound saved on the engine is $2,000 a pound, because that turbine engine is going very fast. One of my rules of thumb is, the faster something moves, the more valuable the weight savings. It's force times velocity, or mass times velocity, to get the energy required to move it. So the Air Force spent tens of millions of dollars trying to make bladed discs, which are called blisks.
This was back in the '80s and '90s, blisk technology. You can Google it. It's a bladed disc. With arc welding, it's hard to get in there — you've got a hundred blades around a rim this big, and it's hard to get in to weld. They tried electron beam, laser, arc welding, linear friction welding. The great thing about linear friction is, if everything's working well, it works great. You have to have a fairly expensive machine to oscillate back and forth, even more expensive than a simple circular machine. But if you make one bad weld out of 100, you now have a piece of scrap. The economics never worked out. If you can figure out how to get Six Sigma quality welds on linear friction welding, you could make a lot of savings for the airline industry and engine technology. But they never solved it.
There's only one engine I know of in commercial production that uses a blisk, and it's a cast blisk. I wish I could get one — it's about this big around. It's made by Rolls-Royce, it's the M250 engine, used on helicopters and small aircraft. It's probably the highest-production jet aircraft engine in the world. But it's a small helicopter or a small plane like a Lear jet. I don't know if it's on a Lear, but that's one example of blisk, and it's a cast part.
§5. What is a weld? [25:46]
Why else is friction welding important — or cold welding? You say, why is he spending two lectures on cold welding? It's not just cold welding, we're talking about surface roughness and surface contamination. With cold welding, I don't have to worry about the heat. I probably should have gone through this with you at some point — what is a weld? The American Welding Society has a definition. I gave a whole keynote lecture at a welding conference on this definition. If they ask you to give a talk and you don't have anything to say, make something up.
The paper I wrote was called "In Search of the Perfect Weld." I started by taking the AWS definition from their glossary: a weld is "a localized coalescence of metals or non-metals produced by either heating the materials to the welding temperature with or without the application of pressure, or by the application of pressure alone, and with or without the use of filler metal." If you analyze that, what you get is: a weld is something that can be metal or non-metal, can have temperature or not, can have pressure or not, and can have filler metal or not. Isn't that a great definition?
You have to understand the psychology of this. The guy who wrote most of the AWS definitions was Hallock Campbell, who's passed away now. Hallock was a Harvard grad, and he was a real stickler for words. Back in 1985, I was on sabbatical in Japan, and I had written a paper in the Welding Journal where I used the word "parameter" in the title. I get this letter in Japan from Hallock telling me I'd used the word "parameter" incorrectly. I read his thing, and I went to the office I was in, which had an unabridged Merriam-Webster dictionary about this thick. I looked up "parameter," and there it had four or five meanings, and it gave examples, including one from Percy Bridgman. Anybody know who Percy Bridgman was? A professor at Harvard who won the Nobel Prize. He used the tetrahedral anvil press to develop huge pressures for geological studies of minerals and phase transformations. He won the Nobel Prize for his studies at ultra-high pressure — gigapascals, millions of PSI. That's how people make artificial diamonds now, using Bridgman's tetrahedral anvil press. Bridgman was a professor at Harvard in the '30s and maybe into the '40s, and Hallock Campbell probably was one of his students. I wrote back to Hallock with a copy of the definition from the book, and said, this is how I used it and this is how P.W. Bridgman used it. He handwrote on the back and sent it back: "Percy, how could you?"
So this is a Hallock Campbell type of definition of a weld. I used it as the opening of my talk. They wanted me to give a keynote, I'd given keynote talks before, and I was running out of topics, so I decided to talk about "In Search of the Perfect Weld." First you have to define the word "weld," and I looked it up and saw it's a silly definition. I built the talk around — the problem with his definition is, he was trying to define a weld in terms of how you do it, not what you're trying to accomplish.
I came up with a different definition in my talk, which so far as I know the American Welding Society has not bothered to adopt. A weld is the joining of two similar materials for which the properties of the weld are substantially similar to the properties of the base materials. Because in solder and brazing you have weaker material in between; adhesive bonding, your joint is weaker. A weld, you have substantially similar strength. We talk about diffusion bonding — sometimes we call it diffusion welding — this is a diffusion bond in platinum for a turbine blade for the F22, I showed it to you once before. This is actually a near-perfect weld, in that the properties across that joint are identical to the base material if you do it properly. So I define a weld in terms of properties, not process. Even though I knew nothing about it, I could cobble something together.
§6. Cold welding for wire drawing — H.C. Starck and the MIT vacuum lineage [31:42]
We do use cold welding in a few cases. One is to make wire bonds. If I'm trying to draw wire — if you go over to Newton, Massachusetts, there's a company H.C. Starck that is one of the world's largest producers of tantalum. H.C. Starck is part of Bayer Chemical in Germany, one of the world's largest chemical companies, rivals DuPont in size. This factory in the middle of Newton, in the residential area, was started after World War II, probably because of the MIT mechanical engineering department. The mechanical engineering department developed a way to generate very good vacuum on an industrial scale. As a result, Norton Research Company started looking at being able to melt refractory materials. I don't know if this work came out of the Manhattan Project or not — it might have, because they were trying to melt things like uranium, which is very reactive, you need to melt it in a vacuum.
They started working on refractory materials. Watertown Arsenal, which is now Watertown Mall, developed titanium alloys. The workhorse titanium alloy is Ti-6Al-4V — about 1950 they developed titanium alloys, all because of this technology to generate vacuum on an industrial scale, when you're melting metals that are giving off all kinds of gas. You had a big enough vacuum pump to suck this stuff off. Norton Research started right down here at the end of campus, and the building is between the Wang Center and the river. That was the Norton Research building. Now it's part of the Sloan School.
Student: That Norton —?
No, different Norton. There were two Norton brothers who were faculty members in this department, but it's not either one of them. I don't know which Norton that is, but it's a different Norton. My thesis adviser in the 1950s did his doctoral thesis on single-crystal tungsten, the deformation of single-crystal tungsten, because we all of a sudden had vacuums that we could grow single-crystal tungsten and niobium and all the refractory metals, and titanium light metals. Tantalum is one of those metals. So H.C. Starck over here in Newton — this is going back 70, 80 years — but one little development out of mechanical engineering at MIT has spawned off a number of different companies.
There's another company started in Concord, which has pretty much gone belly up now, called Nuclear Metals. They used to extrude depleted uranium for all the bullets in the world. After the first Gulf War, Kuwait got contaminated with depleted uranium, and they weren't real happy. The Army has been spending lots of money trying to come up with tungsten alloys to replace depleted uranium as bullets. Nuclear Metals make tantalum wire, all kinds of tantalum products. I got this from them — basically they just take a die, and if you look closely you can actually see some of the die marks where it grabs this and keeps pushing it together as a cold weld. They kept pushing it together about 10 times to exclude the contamination. It's just cold-forged. Tantalum can be deformed probably 99 percent without cracking, even though it's a refractory metal. It's very ductile. Tantalum and niobium are both extremely ductile.
[Tom locates a figure from the welding handbook.] Here's the tooling that's used. You grab a wire and clamp it in a vise, and they actually push them at an angle and squeeze them together and forge it over and over. Then you shear off the flash, and you just draw the wire. They have a continuous drawing operation that can run for weeks without stopping. You're drawing wire continually, but you have to make these welds in between. You don't have to stop, because they have a little accumulator that runs a coil, and the coil keeps feeding while this thing is making the weld, and hopefully you get the weld made before you run out of coil in your accumulator. A number of metal-working processes use accumulators to do a batch-type operation following into a continuous flow.
§7. Thermocompression wire bonds — the highest-volume weld in the world [37:44]
The last type of cold welding I want to talk about is actually probably the most common welding in the world, at least in terms of number of units. Anybody have any idea? I estimated once, 20 years or so ago, they make 50 trillion of these welds a year.
Student: [guess]
That's not a cold weld. This is wire bonding in microelectronics. If I have my little tab-bonded tape — this is the Intel thing I passed around before — there are 400 input and output lines on it, 100 on each of the four sides. This one's soldered. But after they've soldered the chip to this little composite polyimide-copper tape, to join it to the rest of the package, they come in with a one-thousandth-of-an-inch diameter gold wire, and they squeeze that wire onto the surface and push it to the side. They often add a little bit of heat, like 200 or 300 degrees, and it's called thermocompression welding.
Here's a picture from the welding handbook. This is one they started to break apart. The tooling looks like a sewing machine, except you're using a thin gold wire rather than a thread. You feed the wire through, the head comes down, squeezes the gold into the surface, and spreads it out. Here's the 1-mil diameter wire. See this non-bonded region in the center? That's called the dead zone. That's where you have a straight normal force and no shear. The real bond is out here in the wings. All we're looking for is to carry nanoamps or microamps.
There's a company called Kulicke and Soffa in northwestern Pennsylvania that has about 90 percent of the world's market for making these machines. You can buy one for $50,000 or $100,000. It's like a sewing machine feeding a gold wire. It automatically indexes the part, and it makes about seven bonds a second, really kicking along. They might be up to 10. You run into the same stiffness and vibration problems limiting how fast you can go. You can try to run it faster, but the mechanical inertia of all these parts moving up and down — you have to make the sewing-machine heads lightweight because of the inertia.
Here's a book on wire bonding and microelectronics. Here's a gold wire bond, an ultrasonic wedge bond. We talked about ultrasonics — you can improve this problem if you do it with ultrasonics. You can't make seven a second if you're doing ultrasonics at the same time. You might make one a second, or two a second.
Student: Could you parallel-process it, do four next to each other?
Not so much because of the size of the heads. When we get into designing microelectronics — how do you get more input and output bonds — you're limited to about four mils between each bond pad center-to-center because of the size of the head, the sewing-machine head. You go any smaller, you get the same stiffness problem we talked about with the tools that go into your knee. The thing doesn't have enough stiffness, it'll bend. You lose your geometric stiffness. They do things like sapphire tips, because there's a lot of wear when you're doing seven a second. Even though it's gold, there's a lot of technology, because this is the bread and butter of Intel and others.
§8. Scrap economics, turbine blade theft, and Pentium redundancy [42:25]
You might have to make 400 bonds, but if you make one bad one, you've got scrap. You can take a $500 chip — remember I said one of the problems of joining is, if you don't do it well, it comes at the end of the manufacturing process where the cost of scrap is high. You can make a $500 chip that has to have 400 good bonds, and if it has 399 good bonds, it's a $0 chip. Actually it's not zero — they take the bad chips, put an ink spot on them, and sell them as keychains.
Student: I heard that when a Pentium 4 has part of it go bad, it becomes a Pentium 3.
That's what they've started to do. This was a Pentium 1, the 1995 version. The reason I had these — when I first became department head in '95 or '96, they used to bring groups of high school students through MIT, like 500 of them from around New England, top science students in their high schools, and try to give them a Saturday at MIT. They chose materials when I was department head, so we had to put on a dog-and-pony show for these high school science stars. I got Pratt & Whitney to give me — maybe it wasn't 500, maybe 200 students — enough turbine blades that I gave every one of them a turbine blade. These were worn-out turbine blades. A little problem, because you have to be careful about turbine blades. If this blade is worth $6,000 — now this one's cut in two, but even this one's got a corner cut off, and that tells a mechanic, don't put it into an engine, there's something wrong with it. [Tom shows a marked blade.] This one's got a notch right here — don't put it in an engine, it did not pass quality control. When these things are worth four or five or $6,000 apiece, there's a great incentive for people to steal bad ones and put them in engines, which could cause the engine to blow up. That's a quality control concern. That's not a problem with a Pentium chip.
Getting back to your question, starting around Pentium 2 — I was at Intel when they were designing the Pentium 3, probably around 2000. We'll get into this — the Pentium 3 was a chip this size plus another chip right next to it at about half its size. With Pentium 4 they were able to put everything back into one chip as they miniaturized it. As they got to that density, they started making things redundant, so that when you made the chip, if this area didn't work, you could reprogram it so you had some redundancy on the chip. Otherwise you're trying to make 10 million transistors and every one of them has to be good, and one being bad means you haven't got a good chip. This isn't a bonding problem, this is just a processing problem. Now they're up above half a billion transistors on a thing. About 10 years ago the big thing was to design redundancy in, so you can have something that — it's like, I've got two kidneys, right? If one dies, I can still live. They design chips like that.
§9. Explosive bonding [46:38]
There are other types of cold welding I'd forgotten I had. One is explosive bonding. This was discovered during World War II — bombs would go off on ships, or blow a tank apart, and they would find two sheets of material bonded together perfectly by the explosion. They did a bunch of research after World War II. DuPont did a lot of it, because DuPont started in the Revolutionary War making gunpowder, and they are still a big — most of the explosive plants in the United States are in the Pennsylvania-Delaware area, because that's the home of DuPont, where explosives manufacturing got its start in the late 18th century.
They found that at the right angle — let's say you want to take a plate of tantalum. Tantalum has a value approximately the same as silver. Tantalum is only one of two materials that can tolerate concentrated sulfuric acid without corrosion. Every ounce of gasoline in the world is made in a vat of tantalum, because they use concentrated sulfuric acid to get rid of the water in the gas from cracking. When you break down the heavy hydrocarbons to make octane, you end up generating a bunch of water, and the sulfuric acid will suck the water out. They call sulfuric acid a catalyst, but you have to use tantalum tanks. You can't build a great big pressure vessel out of tantalum 3 or 4 inches thick — no one could afford gasoline. So they take a great big steel tank, and they clad it with about a quarter inch of tantalum, and they do it by explosive bonding.
They put a layer — they have the steel plate, maybe 4 inches thick, and they go to a place called Explosive Fabricators outside of Boulder, Colorado. They have their own little valley between the mountains where there aren't a lot of neighbors, so they can set off explosions without people complaining. The top sheet of tantalum has a layer of explosive on it, and you set off the explosive. You put it at a slight angle — the tantalum plate to the steel plate, just laying on the ground — at a slight angle, you set off the explosive, and the explosive burns in one direction. You're forging these things together. That's called explosive bonding, and I'll tell you more about the technology next time.