Polyacetylene conductive polymers

Appears in 2 lectures.

Appearances across the corpus

SMS_F2013_06 · Structural Materials Selection, Fall 2013 · §4.p1

The class of materials at issue in the Wennick talk; now used for touch screens, never displaced copper.

People can use those phrases all the time, and they do that for the unaware. You should not be the unaware — you're MIT grads or soon will be. I was sitting in the old Shipman room, probably 20 or 25 years ago. A young professor, Gary Wenick, was in polymer science. This was at a time when people had just discovered things like polyacetylene, which were electrically conductive polymers. He was giving a talk to the visiting committee or somebody about his research. He said, these conductive polymers have a specific electrical conductivity — that means the electrical conductivity, which is the inverse of resistance, divided by the density — that is better than copper.

MSE_F2016_05 · Materials Selection, Fall 2016 · §7.p2

Another thing people do with new materials is they'll be very careful about how they phrase the properties. The example I like to give was Professor Gary Wnek, who was an assistant professor in this department. He left before tenure ever came. He was really a chemist but he worked on polymers. This was back 25, 30 years ago when electrically conductive polymers were a new thing. He was giving a talk in the Chipman Room about his research on electrically conductive polymers. At the time the polymer was polyacetylene. Ordinarily polymers are covalently bonded — there's no free electrons, and that's why they're excellent insulators. Polyacetylene has a bunch of double bonds, and so properly doped, it can have some free electrons and so is electrically conductive. He was pointing out that the specific electrical resistivity of polyacetylene was better than copper, and therefore big rotor generators and rotating machinery and motors would all be using polyacetylene or other conductive polymers in the future. I thought, wow, that's pretty impressive.